Catalysis/initiation System and Polymerization Methods of Atom Transfer Radical Polymerization

Yan BAO; Xiao-zhao YAO; Jian-zhong MA

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Catalysis/initiation System and Polymerization Methods of Atom Transfer Radical Polymerization

更新时间：2022-09-18

- Catalysis/initiation System and Polymerization Methods of Atom Transfer Radical Polymerization
- Polymer Bulletin Vol. 25, Issue 8, Pages: 64-73(2012)
- 作者机构：
  
  1.陕西科技大学资源与环境学院，西安　710021
  2.教育部轻化工助剂重点实验室，西安　710021
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2012-08，
  
  Received：21 January 2012，
  
  Revised：06 March 2012，
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Yan BAO, Xiao-zhao YAO, Jian-zhong MA. Catalysis/initiation System and Polymerization Methods of Atom Transfer Radical Polymerization. [J]. Polymer Bulletin 25(8):64-73(2012)
DOI：

Yan BAO, Xiao-zhao YAO, Jian-zhong MA. Catalysis/initiation System and Polymerization Methods of Atom Transfer Radical Polymerization. [J]. Polymer Bulletin 25(8):64-73(2012) DOI：

摘要

原子转移自由基聚合(ATRP)作为一种有效的"活性"/可控聚合可对聚合物进行分子设计

制备结构和相对分子质量可控的各类聚合物

具有潜在而广泛的研究价值。本文综述了ATRP的研究进展

特别是对传统ATRP催化引发体系、RATRP催化引发体系、AGET ATRP催化引发体系、SR&NI ATRP催化引发体系、ICAR ATRP催化引发体系、ARGET ATRP催化引发体系、杂化或双金属催化体系等的催化引发机理进行了详细的介绍。并综述了ATRP聚合中各种实施方法如本体聚合法、溶液聚合法、悬浮聚合法、乳液聚合法等的研究现状。

Abstract

Atom transfer radical polymerization (ATRP) is an effective controlled/living polymerization method. It can be used to design polymer structure and control molecular weight. Thus it is of great potential research value. This paper reviews the research progress of ATRP

especially for catalysis/initiation mechanism of traditional ATRP catalysis/initiation system

RATRP catalysis/initiation system

AGET ATRP catalysis/initiation system

SR&NI ATRP catalysis/initiation system

ICAR ATRP catalysis/initiation system

ARGET ATRP catalysis/initiation system

hybrid and bimetallic catalyst system. Moreover

the current situation of ATRP application methods

such as bulk polymerization

solution polymerization

suspension polymerization

emulsion polymerization etc.

was summarized.

关键词

原子转移自由基聚合催化引发聚合方法

Keywords

Atom transfer radical polymerizationCatalysisInitiationPolymerization method

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