Thermal Stability Study for Allyl Methyl Phenol Ether/Bismaleimide/Diallyl Bisphenol A Ternary Blend

Miao YU; Zhen FAN; Liu ZHUN; Jing-min LIU; Ning-ning FU; Ning ZHANG; Guo ZHANG

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Thermal Stability Study for Allyl Methyl Phenol Ether/Bismaleimide/Diallyl Bisphenol A Ternary Blend

更新时间：2022-09-18

- Thermal Stability Study for Allyl Methyl Phenol Ether/Bismaleimide/Diallyl Bisphenol A Ternary Blend
- Polymer Bulletin Vol. 26, Issue 5, Pages: 71-75(2013)
- 作者机构：
  
  1.黄淮学院　化学化工系，驻马店　463000
  2.河南天方药业股份有限公司，驻马店　463000
  3.湖北省化学研究院，武汉　430074
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2013-05，
  
  Received：02 August 2012，
  
  Revised：29 January 2013，
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Miao YU, Zhen FAN, Liu ZHUN, Jing-min LIU, Ning-ning FU, Ning ZHANG, Guo ZHANG. Thermal Stability Study for Allyl Methyl Phenol Ether/Bismaleimide/Diallyl Bisphenol A Ternary Blend. [J]. Polymer Bulletin 26(5):71-75(2013)
DOI：

Miao YU, Zhen FAN, Liu ZHUN, Jing-min LIU, Ning-ning FU, Ning ZHANG, Guo ZHANG. Thermal Stability Study for Allyl Methyl Phenol Ether/Bismaleimide/Diallyl Bisphenol A Ternary Blend. [J]. Polymer Bulletin 26(5):71-75(2013) DOI：

摘要

双马来酰亚胺(BMI)/二烯丙基双酚-A(DABP-A)共混体树脂体系

具有高韧性和优异的耐热性能

但粘度大

导致加工工艺复杂

应用困难。而烯丙基甲酚醚(AMPE)含有活性基团

与上述树脂体系能发生交联反应

将其作为活性稀释剂

选择合适比例

能在减小粘度的同时

提高体系的机械强度和耐热性能。实验中将AMPE加入到BMI/DABPA树脂体系

并改变AMPE在树脂体系中的质量分数

测定质量分数与体系粘度、热稳定性等性能之间的关系

确定最佳的比例为AMPE:BMI:DABPA=10〜20:36:29.2

而热失重实验也表明

复合材料热稳定性得到了进一步提高。该结论对于企业改进生产工艺

降低生产成本

提高产品质量

改善生产效益

具有重要意义。

Abstract

The bismaleimide (BMI) /diallyl bisphenol A (DABPA) blend system is an important system for usage for its high stability

but its high viscosity prevent its usage in factory. Possessing high active group

allyl methyl phenol ether can react with BMI/DABPA resin through cross-linking reaction under heat condition

it has been used as the reactive diluent. Thus AMPE can reduce the viscosity of the resin system and increase heat resistance. Through determination the viscosity and TGA data of this blend containing different content allyl cresol ether

an appropriate proportion (AMPE: BMI: DABPA =10〜20: 36 : 29. 2) has been obtained to increase the production benefit. This conclusion will be helpful for industry to increase product quality and productivity effect.

关键词

双马来酰亚胺树脂二烯丙烯双酚A烯丙基甲酚醚活性稀释剂

Keywords

Bismaleimide resinDiallyl bisphenol AAllyl methyl phenol etherReactive diluent

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Institute of Polymer Science, Zhongshan University

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