Research on Phosphorylated EVOH/DGEBA/PPA Cross-linked Proton Exchange Membranes

Shu-shan WANG; Liang-fang ZHAI; Jian-hong LIU; Cui-hua LI; Rong GUAN

您当前的位置：

首页 >

文章列表页 >

Research on Phosphorylated EVOH/DGEBA/PPA Cross-linked Proton Exchange Membranes

更新时间：2022-09-18

- Research on Phosphorylated EVOH/DGEBA/PPA Cross-linked Proton Exchange Membranes
- Polymer Bulletin Vol. 26, Issue 9, Pages: 177-183(2013)
- 作者机构：
  
  1.湖北大学化学化工学院，武汉　430062
  2.深圳大学化学与化工学院，深圳　518060
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2013-09，
  
  Received：31 May 2013，
  
  Revised：09 July 2013，
扫描看全文
Shu-shan WANG, Liang-fang ZHAI, Jian-hong LIU, Cui-hua LI, Rong GUAN. Research on Phosphorylated EVOH/DGEBA/PPA Cross-linked Proton Exchange Membranes. [J]. Polymer Bulletin 26(9):177-183(2013)
DOI：

Shu-shan WANG, Liang-fang ZHAI, Jian-hong LIU, Cui-hua LI, Rong GUAN. Research on Phosphorylated EVOH/DGEBA/PPA Cross-linked Proton Exchange Membranes. [J]. Polymer Bulletin 26(9):177-183(2013) DOI：

摘要

为了研究适用于高温低湿环境下的燃料电池质子交换膜

本文采用了一种新型交联试剂双酚A二缩水甘油醚型环氧树脂(DGEBA)

按照一定配比对乙烯-乙烯醇的嵌段共聚物(EVOH)进行适度交联

引入多聚磷酸(PPA)对交联膜进行磷酸化

制备了磷酸化EVOH/DGEBA/PPA交联膜。通过傅里叶红外(FTIR)、X射线衍射(XRD)和质子电导率等测试对膜的性能进行了表征。实验结果表明:所制备的膜成功地进行了交联反应和磷酸化反应;交联反应使膜的热稳定性和氧化稳定性得到改善;随磷酸化时间的增加

膜的离子交换容量值和电导率增加

但氧化稳定性有所降低。在相对湿度为60%时

膜的质子电导率要高于Nafion膜

所研制的膜有望在高温低湿环境下的质子交换膜燃料电池中使用。

Abstract

In order to investigate the proton exchange membranes suitable for high temperature and low moisture

a new type of cross-linking reagent diglycidyl ether of bisphenol-A was introduced to react with ethylene-vinyl alcohol copolymer at certain mol ratio

then the phosphorylated EVOH/DGEBA/PPA cross-linked membranes were obtained by phosphorylating EVOH/DGEBA cross-linked membranes with polyphosphoric acid. FTIR

XRD and proton conductivity have been used to characterize the performance of membranes. The experimental results showed that the membranes have been cross-linked and phosphorylated successfully; the thermal stability and oxidation stability of membranes were improved by cross-linking reaction; the IEC value and proton conductivity of membranes increased with increasing the phosphorylation time

however

the oxidation stability decreased. The proton conductivity of membranes was higher than that of Nafion at the relative humidity of 60%

so the prepared membrane is expected to be used in proton exchange membrane fuel cell at high temperature and low humidity atmosphere.

关键词

双酚A二缩水甘油醚型环氧树脂乙烯-乙烯醇共聚物交联磷酸化质子交换膜

Keywords

Diglycidyl ether of bisphenol-AEthylene-vinyl alcohol copolymerCross-linkingPhosphorylationProton exchange membrane

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study on Alcoholysis of Ethylene-vinyl Acetate Copolymer Catalyzed by Alkaline Deep Eutectic Solvents

Study on Mechanism of Transglutaminase Cross-linking Soybean Protein Isolate Simulated by Gauss Software

Research Progress of Proton Exchange Membranes and Electrode Materials for All-vanadium Flow Batteries

Research on the Development of Proton Exchange Membrane Electrode Assembly Technology Based on Patent Analysis

Progress of Tough Self-healing Hydrogels

Related Author

No data

Related Institution

Dalian Institute of Chemical Physics, Chinese Academy of Sciences

School of Textile and Material Engineering, Dalian Polytechnic University

Changchun Medical College

State Key Laboratory of Biobased Material and Green Papermaking,Qilu University of Technology, Shandong Academy of Sciences

Wuhan Library and Intelligence Centre of Chinese Academy of Science

⁰