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天津科技大学材料科学与化学工程学院,天津 300457
Published:2013-12,
Received:12 March 2013,
Revised:27 June 2013,
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Bo DONG, Yue-ming SUN, Mei WANG, Yan-hui CHEN, Tao JIANG. Recent Progresses of Ethylene Tetramerization toward 1-Octene. [J]. Polymer Bulletin 26(12):38-43(2013)
DOI:
Bo DONG, Yue-ming SUN, Mei WANG, Yan-hui CHEN, Tao JIANG. Recent Progresses of Ethylene Tetramerization toward 1-Octene. [J]. Polymer Bulletin 26(12):38-43(2013) DOI:
乙烯四聚高选择性合成1-辛烯
具有"原子经济性"反应的高选择性和低能耗性
符合绿色化工的发展趋势
备受学术界及工业界的青睐。本文综述了近年来乙烯四聚合成1-辛烯研究的最新进展
涉及乙烯四聚催化体系中的配体和助催化剂以及反应体系的溶剂等方面
讨论了乙烯四聚合成1-辛烯的反应机理
并展望了该技术的工业应用前景。
With the development of green chemical engineering
1-octene prepared vis ethylene tetramerization is Atomic economy’ reaction. It has an advantage of high selectivity and low energy consumption
which have attracted considerable attention in the academic and industrial field. In this paper
the latest progress of ethylene tetramerization to 1-octene has been summarized from ligand
cocatalyst
solvent and the reaction mechanisms.
乙烯四聚1-辛烯铬催化剂
Ethylene tetramerization1-OcteneChromium-based catalyst
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