Progress on the Metal-Free Anionic Polymerization

Zhen-long YAN; Wei-qu LIU; Hong-lei WANG; Kui SU

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Progress on the Metal-Free Anionic Polymerization

更新时间：2022-09-18

- Progress on the Metal-Free Anionic Polymerization
- Polymer Bulletin Vol. 27, Issue 4, Pages: 35-43(2014)
- 作者机构：
  
  1.中国科学院广州化学研究所，广州　510650；
  2.中国科学院大学，北京　100049
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2014-04，
  
  Received：05 July 2013，
  
  Revised：18 October 2013，
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Zhen-long YAN, Wei-qu LIU, Hong-lei WANG, Kui SU. Progress on the Metal-Free Anionic Polymerization. [J]. Polymer Bulletin 27(4):35-43(2014)
DOI：

Zhen-long YAN, Wei-qu LIU, Hong-lei WANG, Kui SU. Progress on the Metal-Free Anionic Polymerization. [J]. Polymer Bulletin 27(4):35-43(2014) DOI：

摘要

有机非金属盐阴离子聚合是活性/可控阴离子聚合的一个重要分支。有机非金属盐阴离子聚合方法最大的特点是可以在很宽的温度范围内（-20~70℃）引发（甲基）丙烯酸酯类单体聚合，分子量分布窄，显示出可控/活性的特征。该聚合方法为分子设计和合成（甲基）丙烯酸烷基酯的均聚物、嵌段聚合物、接枝聚合物和功能性聚合物提供了有效的途径。本文综述了有机非金属盐阴离子引发剂在合成（甲基）丙烯酸酯类单体中的研究进展，包括聚合的反应机理、特点、研究现状及其前景展望。

Abstract

Metal-free anionic polymerization is an important branch of controlled/living anionic polymerization

which has the excellent characterization to initiate alkyl (meth) acrylates monomers at wide temperature range ( - 20~70℃) with narrow molecular weight distribution in a controlled/living manner. This method provides an effective method to design and synthesize homopolymer

block copolymer

graft copolymer and functional polymer of alkyl (meth) acrylates. This paper reviews the pass and recent developments in metal-free anionic polymerization of alkyl (meth) acrylates using different initiators

including the mechanism of reaction

reactive characterizations

investigation situation and future prospect.

关键词

有机非金属盐阴离子聚合室温活性聚合（甲基）丙烯酸烷基酯类单体

Keywords

Metal-free anionic polymerizationRoom temperatureLiving polymerizationAlky (methyl)acrylate

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