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1.中国石油兰州化工研究中心,兰州 730060;
2.厦门大学化学工程与生物工程系,厦门 361005
Published:2012-04,
Received:04 November 2011,
Revised:14 November 2011,
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Jun-ji JIA, Zu-wei ZHENG, Yong ZHU, Zheng-hong LUO. Advances in Polymerization Mechanism Catalyzed by Polypropylene Catalysts. [J]. Polymer Bulletin 25(4):56-60(2012)
DOI:
Jun-ji JIA, Zu-wei ZHENG, Yong ZHU, Zheng-hong LUO. Advances in Polymerization Mechanism Catalyzed by Polypropylene Catalysts. [J]. Polymer Bulletin 25(4):56-60(2012) DOI:
评述了自二十世纪五十年代至今近五十多年聚丙烯催化剂的几个重要发展阶段,着重介绍两类(单活性中心与多活性中心)三种聚丙烯催化剂,即Ziegler-Natta催化剂、茂金属催化剂和后过渡铁金属催化剂催化丙烯聚合的机理。
In this paper
we reviewed the development process for polypropylene catalysts
which is divided into several important periods. In addition
this comments concentrated on two types of catalysts (i.e. the single-and the multi-site catalysts) and three kinds of catalysts (i.e. Ziegler-Natta
metallocene and late-transition iron metal catalysts). We also introduced the polymerization mechanism of the above catalysts.
单、多活性中心Ziegler-Natta催化剂茂金属催化剂后过渡金属催化剂丙烯聚合机理
Single-and multi-siteZiegler-Natta catalystMetallocene catalystLate-transition metal catalystPropylene polymerization mechanism
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