Progress in Research of Anionic Ionomers

Wen-ke YANG; Cong-de QIAO; yao LIU; Jin-shui YAO

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Progress in Research of Anionic Ionomers

更新时间：2022-09-18

- Progress in Research of Anionic Ionomers
- Polymer Bulletin Vol. 25, Issue 6, Pages: 54-62(2012)
- 作者机构：
  
  山东省玻璃与功能陶瓷加工与测试技术重点实验室，山东轻工业学院材料科学与工程学院，济南　250353
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2012-06，
  
  Received：11 November 2011，
  
  Revised：16 December 2011，
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Wen-ke YANG, Cong-de QIAO, yao LIU, Jin-shui YAO. Progress in Research of Anionic Ionomers. [J]. Polymer Bulletin 25(6):54-62(2012)
DOI：

Wen-ke YANG, Cong-de QIAO, yao LIU, Jin-shui YAO. Progress in Research of Anionic Ionomers. [J]. Polymer Bulletin 25(6):54-62(2012) DOI：

摘要

参考近年来文献资料，总结了磺酸型、羧酸型、膦酸型等阴离子型离聚物的合成方法，对离聚物的几种重要聚集态结构模型进行了介绍，对于文献报道的各种模型在应用方面的不足之处也进行了总结。对于离聚物形态结构，介绍了有关微相分离方面的研究以及利用电镜技术得到的新突破。在离聚物的溶液性质方面，介绍了溶液粘度和溶剂作用的相关研究。对于离子对含量和类型等因素对离聚物力学性能和玻璃化转变温度的影响进行了总结，最后指出了离聚物尚需进一步研究的问题。

Abstract

In this paper

the synthesis of the anionic ionomers

such as ionomers with pendent carboxyl

sulfo or phospho groups

was summarized based on the prior work. And some essential morphology models of the ionomer and their infects in application were summarized. For the structure of the ionomer

the studies of microphase separation and some breakthroughs gained by new electron microscopy technology were introduced briefly. As for the solution properties of ionomer

some relative studies of ionomer solution viscosity and the solvent functionality were discussed. And the influence of the amount and type of the ionic groups on the mechanical properties and glass transition temperature was summarized. The further research of the ionomers needed to approach was also indicated.

关键词

离聚物离子簇结构模型溶液性质

Keywords

IonomerIonic clustersMorphological modelsSolution properties

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State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

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