Lewis Acid Mediated Stereoregular Free Radical Polymerization

Shi WU; Xiao-lei SUN; Li-yuan GUO; Jia-an ZHANG

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Lewis Acid Mediated Stereoregular Free Radical Polymerization

更新时间：2022-09-18

- Lewis Acid Mediated Stereoregular Free Radical Polymerization
- Polymer Bulletin Vol. 27, Issue 7, Pages: 13-17(2014)
- 作者机构：
  
  湖北科技学院药学院，咸宁　437100
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2014-07，
  
  Received：24 July 2013，
  
  Revised：09 November 2013，
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Shi WU, Xiao-lei SUN, Li-yuan GUO, Jia-an ZHANG. Lewis Acid Mediated Stereoregular Free Radical Polymerization. [J]. Polymer Bulletin 27(7):13-17(2014)
DOI：

Shi WU, Xiao-lei SUN, Li-yuan GUO, Jia-an ZHANG. Lewis Acid Mediated Stereoregular Free Radical Polymerization. [J]. Polymer Bulletin 27(7):13-17(2014) DOI：

摘要

聚合物链的立体规整性对聚合物的性质和功能有重要影响。自由基聚合在工业上应用广泛，由于自身特点，其立体规整性聚合研究在工业和学术上均具有重要意义。Lewis酸广泛地应用于自由基立体规整性聚合，是自由基立体规整性聚合研究的热点。本文对Lewis酸调控自由基立体规整性聚合进行了较全面的综述，介绍了用于自由基立体规整性聚合的Lewis酸、成功的单体、聚合机理、聚合条件对立体规整性的影响，并对Lewis酸调控的发展方向做一简要介绍。

Abstract

Because of its inherent characteristics and wide application

Lewis acids have been widely applied in the stereocontrol of radical polymerization. In this paper

a comprehensive review on the Lewis acids mediated stereoregular radical polymerization was made

including the Lewis acids employed

monomers studied

reaction mechanism

and the effect of polymerization condition on the tacticities of the resultant polymers. A short outlook of the future development in the thereof direction was proposed.

关键词

自由基聚合立体规整性Lewis酸研究进展

Keywords

Radical polymerizationTacticityLewis acidResearch progress

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