Progress in Polyoxometalate-Polymer Supramolecular Hybrid Materials

Dan-dan CHONG; Jie ZHANG; Xin-hua WAN

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Progress in Polyoxometalate-Polymer Supramolecular Hybrid Materials

更新时间：2022-09-18

- Progress in Polyoxometalate-Polymer Supramolecular Hybrid Materials
- Polymer Bulletin Vol. 27, Issue 8, Pages: 56-68(2014)
- 作者机构：
  
  北京大学高分子化学与物理高分子教育部重点实验室和软物质科学与工程中心，　北京大学化学与分子工程学院，北京100871
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2014-08，
  
  Received：16 June 2014，
  
  Revised：27 June 2014，
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Dan-dan CHONG, Jie ZHANG, Xin-hua WAN. Progress in Polyoxometalate-Polymer Supramolecular Hybrid Materials. [J]. Polymer Bulletin 27(8):56-68(2014)
DOI：

Dan-dan CHONG, Jie ZHANG, Xin-hua WAN. Progress in Polyoxometalate-Polymer Supramolecular Hybrid Materials. [J]. Polymer Bulletin 27(8):56-68(2014) DOI：

摘要

多酸具有多样的拓扑结构和优异的理化性质，在催化、光电材料和药物等领域显示出广阔的应用前景。多酸-有机聚合物超分子自组装杂化材料不仅有效融合了多酸丰富的功能特性和有机聚合物良好的加工性，而且其有序的自组装结构还赋予材料更多优异的功能调控性。静电复合、氢键作用、共价键连等超分子策略是将多酸引入到聚合物基质中的有效方法。本文总结了多酸-有机聚合物超分子杂化材料近几年的最新研究进展，重点介绍了这类杂化材料的构筑策略、其有序的自组装行为以及超分子功能特性的调控等。

Abstract

Polyoxometalates have well-defined structures and remarkable properties with great potentials to meet contemporary material demands in the field of catalysis

electrooptical devices

and pharmaceuticals. The polyoxometalate/ polymer supramolecular hybrid materials not only combine unique properties and functionalities of polyoxometalates with favorable stability and processability of polymers

but also have flexible functional regulation. Suprmolecular strategies including electrostatic interaction

hydrogen bonding

and covalent bonding are widely applied to incorporate polyoxometalates into organic polymer matrices. In this article we provide an overview of lastest progress of the fabrication strategies

self-assembling behavior

and functional regulation of these supramolecular hybrid materials.

关键词

多酸有机聚合物超分子自组装杂化材料

Keywords

PolyoxometalateOrganic polymerSupramolecular assemblyHybrid materials

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