Recent Development in the Synthesis of Polyhedral Oligomeric Silsesquioxane

Jian-kun HU; Xiao-fen YU; A-ding LU; Juan LI; Shu-ling GONG

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Recent Development in the Synthesis of Polyhedral Oligomeric Silsesquioxane

更新时间：2022-09-18

- Recent Development in the Synthesis of Polyhedral Oligomeric Silsesquioxane
- Polymer Bulletin Vol. 27, Issue 10, Pages: 52-61(2014)
- 作者机构：
  
  1.浙江省海洋开发研究院，舟山　316021
  2.武汉大学化学与分子科学学院，武汉　430072
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2014-10，
  
  Received：31 October 2013，
  
  Revised：27 March 2014，
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Jian-kun HU, Xiao-fen YU, A-ding LU, Juan LI, Shu-ling GONG. Recent Development in the Synthesis of Polyhedral Oligomeric Silsesquioxane. [J]. Polymer Bulletin 27(10):52-61(2014)
DOI：

Jian-kun HU, Xiao-fen YU, A-ding LU, Juan LI, Shu-ling GONG. Recent Development in the Synthesis of Polyhedral Oligomeric Silsesquioxane. [J]. Polymer Bulletin 27(10):52-61(2014) DOI：

摘要

多面体低聚倍半硅氧烷(POSS)由于具有规整的立体结构、纳米尺寸、优良的相容性和修饰性，使其成为分子结构设计和材料改性的最佳选择之一。因此，POSS的合成引起了人们广泛的关注，深入研究它的合成方法与反应机理具有十分重要的学术意义和应用价值。本论文综述了 POSS的合成研究进展（包括水解缩合法、官能团衍生法、缺角闭环法等），重点介绍了全同取代(T

)、单官能团(T

R')、多官能团（T

8-n

）及半缩合POSS(T

)的制备方法与途径，并总结了 POSS的合成经验及发展方向。

Abstract

Polyhedral oligomeric silsesquioxane (POSS) shows some of the important features

including the Si-O cage size and the distribution of the eight pendant arms from the cube in a three-dimensional arrangement. These cubic Si-O cages have thus become very popular as nanometer-scale building blocks in a wide range of polymeric materials. In this contribution

the recent development in the synthesis of POSS was reviewed

and in particular the synthesis method of T

8-n

and partially condensed POSS (T

) was described. Meanwhile

the synthesis ways and experiences about many POSS compounds were also summarized. Finally

the potential development in the synthesis of POSS was also discussed.

关键词

倍半硅氧烷POSS合成制备

Keywords

Polyhedral oligomeric silsesquioxanePOSSSynthesisPreparation

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