Cellulose-Supported Metal Catalysts : Recent Developments in the Molecular Design and Applications in Organic Transformations

Feng-jun XUE; Yu-ping WEI

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Cellulose-Supported Metal Catalysts : Recent Developments in the Molecular Design and Applications in Organic Transformations

更新时间：2022-09-18

- Cellulose-Supported Metal Catalysts : Recent Developments in the Molecular Design and Applications in Organic Transformations
- Polymer Bulletin Vol. 27, Issue 10, Pages: 116-124(2014)
- 作者机构：
  
  天津大学理学院化学系，天津　300072
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2014-10，
  
  Received：23 November 2013，
  
  Revised：18 January 2014，
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Feng-jun XUE, Yu-ping WEI. Cellulose-Supported Metal Catalysts : Recent Developments in the Molecular Design and Applications in Organic Transformations. [J]. Polymer Bulletin 27(10):116-124(2014)
DOI：

Feng-jun XUE, Yu-ping WEI. Cellulose-Supported Metal Catalysts : Recent Developments in the Molecular Design and Applications in Organic Transformations. [J]. Polymer Bulletin 27(10):116-124(2014) DOI：

摘要

高分子负载金属催化剂由于催化活性好、稳定性高、反应后容易和产物分离、易于从反应体系中分离回收和重复使用等原因，近年来成为了人们的研究热点之一。纤维素是自然界中储量最丰富的天然高分子，其在大多数有机溶剂中稳定，且其比表面积大，结构中含有大量羟基，可参与许多反应。本文以自然界中储量丰富、无毒、可降解、可再生的天然高分子纤维素为载体，按照纤维素负载金属催化剂制备方式的不同，综述了纤维素负载Pd、Ag、Au、Cu等金属催化剂的制备及其在有机反应中的应用。

Abstract

Most of the polymer-supported metal catalysts have obvious advantages such as high catalytic activity

easy separation and purification of product after reaction and easy recovery and reuse several times without any remarkable loss in catalytic activity. Cellulose is one of the most abundant natural polymer on earth. It is stable in most organic solvents

has high surface area and hydroxyl functional groups that are capable of chelating to metal ions and particles thereby providing required stability. In addition

it is biodegradable

non-toxic and available at low price. In this paper

synthesis of cellulose- based metal catalysts and their applications in organic transformation were summarized.

关键词

纤维素负载催化剂有机反应金属异相催化

Keywords

Cellulose-supported catalystOrganic reactionMetalHeterogeneous catalysis

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