Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography

Hui WANG; Xiao-dong XU

doi:10.14028/j.cnki.1003-3726.2011.01.002

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Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography

更新时间：2022-09-18

- Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography
- Polymer Bulletin Vol. 24, Issue 1, Pages: 94-99(2011)
- 作者机构：
  
  高分子材料研究中心，哈尔滨工程大学材料科学与化学工程学院，哈尔滨　150001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.01.002
  CLC：
- Published：2011-01，
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Hui WANG, Xiao-dong XU. Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography. [J]. Polymer Bulletin 24(1):94-99(2011)
DOI：

Hui WANG, Xiao-dong XU. Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography. [J]. Polymer Bulletin 24(1):94-99(2011) DOI： 10.14028/j.cnki.1003-3726.2011.01.002.

摘要

具有旋光活性的合成高分子基于它的手性结构而具有广泛的应用

其中最实际和广泛的应用是在高效液相色谱中作为手性固定相来拆分对映异构体

目前已成为合成化学、分析化学以及制药化学领域必不可少的分离材料。本文简要介绍了高效液相色谱手性固定相拆分法

综述了合成高分子

包括加聚物特别是聚甲基丙烯酸酯类和聚甲基丙烯酰胺类聚合物、聚酰胺及其它合成聚合物

在高效液相色谱中作为手性固定相的应用进展

并展望了该领域今后的发展趋势。

Abstract

Optical active synthetic polymers were widely applied based on their chiral structure.The most practical and extensive application of them was using as chiral stationary phases (CSP) in high performance liquid chromatography (HPLC) for the resolution of enantiomers.Recently

optical active synthetic polymers have become necessary separation materials in the fields of synthetic chemistry

analytical chemistry and pharmaceutics.In this paper

the resolution method of enantiomers by CSP in HPLC was briefly introduced.The progress and application of synthetic polymers

which included addition polymers

eapecially polymethacrylates and polymethacrylamide

polyamides and other synthetic polymes

in CSPs for HPLC were reviewed in detail

as well as the future prospect of this field was outlined.

关键词

合成高分子手性固定相高效液相色谱手性分离

Keywords

Synthetic polymerChiral stationary phaseHigh performance liquid chromatographyChiral separation

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