Synthesis of Poly(aspartic acid) /3,5-Diamino Benzoic Acid Graft Copolymer and Evaluation of Its Scale and Corrosion Inhibitions

Shi-hong CEN; Hui-ting SHAN; Yu-feng WU; Gao-feng ZHANG; Ying XU

doi:10.14028/j.cnki.1003-3726.2016.06.009

您当前的位置：

首页 >

文章列表页 >

Synthesis of Poly(aspartic acid) /3,5-Diamino Benzoic Acid Graft Copolymer and Evaluation of Its Scale and Corrosion Inhibitions

更新时间：2022-09-12

- Synthesis of Poly(aspartic acid) /3,5-Diamino Benzoic Acid Graft Copolymer and Evaluation of Its Scale and Corrosion Inhibitions
- Polymer Bulletin Vol. 29, Issue 6, Pages: 63-70(2016)
- 作者机构：
  
  1.河南大学化学化工学院，开封 475004
  2.郑州工业应用技术学院，郑州 451150
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2016.06.009
  CLC：
- Published：20 June 2016，
  
  Received：10 August 2015，
  
  Revised：11 January 2016，
扫描看全文
Shi-hong CEN, Hui-ting SHAN, Yu-feng WU, Gao-feng ZHANG, Ying XU. Synthesis of Poly(aspartic acid) /3,5-Diamino Benzoic Acid Graft Copolymer and Evaluation of Its Scale and Corrosion Inhibitions. [J]. Polymer Bulletin 29(6):63-70(2016)
DOI：

Shi-hong CEN, Hui-ting SHAN, Yu-feng WU, Gao-feng ZHANG, Ying XU. Synthesis of Poly(aspartic acid) /3,5-Diamino Benzoic Acid Graft Copolymer and Evaluation of Its Scale and Corrosion Inhibitions. [J]. Polymer Bulletin 29(6):63-70(2016) DOI： 10.14028/j.cnki.1003-3726.2016.06.009.

摘要

通过氨基开环的方法合成了聚天冬氨酸/3，5-二氨基苯甲酸接枝共聚物（PASP/3，5-DMBA），采用静态阻垢、动态腐蚀等方法考察了该共聚物的阻垢和缓蚀性能。结果表明，3，5-二氨基苯甲酸的引入可有效改善聚天冬氨酸（PASP）的阻垢与缓蚀性能，尤其在较低的浓度下对CaSO

和Ca

（PO

）

的阻垢性能有明显的提高。当PASP/3，5-DMBA药剂用量分别为1. 25mg/L、6mg/L时，其对CaCO

、CaSO

的阻垢效率接近100%。当用量为18mg/L时，对Ca

（PO

）

的阻垢效率可达75%。通过扫描电镜（SEM）观察发现，加入PASP/3，5- DMBA后钙垢晶体结构发生了畸变，呈分散开花状。

Abstract

Poly(aspartic acid)/3

5-diamino benzoic acid graft copolymer(PASP/3

5-DMBA) was synthesized by using PSI and 3

5-DMBA as the starting materials

and its scale and corrosion inhibitions were evaluated by static and rotary loss test respectively. The results showed that the introduction of 3

5-DMBA could effectively improve the scale and corrosion performances of PASP. Remarkably the scale inhibition rates against CaSO

and Ca

(PO

)

increased significantly at low dosages. The inhibition efficiencies of PASP/3

5-DMBA against CaCO

and CaSO

were close to 100 % when the dosages were 1. 25mg/L and 6mg/L respectively. Scale inhibition efficiency against Ca

(PO

)

could reach to 75% when the dosage was 18mg/L. After PASP/3

5-DMBA was added

CaCO

CaSO

and Ca

(PO

)

deposits showed flower and cascade patterns with floppy accumulation as observed by scanning electron microscopy (SEM).

关键词

聚天冬氨酸接枝共聚物阻垢缓蚀聚天冬氨酸接枝共聚物阻垢缓蚀

Keywords

Poly(aspartic acid)Graft copolymerScale inhibitionCorrosion inhibitionPoly(aspartic acid)Graft copolymerScale inhibitionCorrosion inhibition

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Recent Progresses in Cellulose-based Functional Materials

Progress in Synthesis of Graft Copolymer via Cationic Polymerization

Electroactive and Biodegradable Aniline Copolymer

Preparation of Block and Graft Copolymer with Iniferters

Molecular Design,Synthesis and Properties of Polyoxyethylene-containing Amphiphilic Block and Graft Copolymers

Related Author

No data

Related Institution

Laboratory of Polymer Physics and Chemistry,Beijing National Laboratory of Molecular Sciences, Institute of Chemistry,Chinese Academy of Sciences

National Engineering Research Center for Engineering Plastics, Technical Institute of Physics & Chemistry, Chinese Academy of Sciences

State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology

Department of chemistry , Tsinghua University

Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education

⁰