Advances in Relationship between Structure and Properties of Furan-based Polyesters

Peng WANG; Wei HUANG; Ming-qiao LIU; Peng CHEN; Wen-qin WANG

doi:10.14028/j.cnki.1003-3726.2017.04.004

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Advances in Relationship between Structure and Properties of Furan-based Polyesters

更新时间：2022-09-06

- Advances in Relationship between Structure and Properties of Furan-based Polyesters
- Polymer Bulletin Vol. 30, Issue 4, Pages: 33-41(2017)
- 作者机构：
  
  1.宁波大学材料科学与化学工程学院，宁波 315211
  2.中国科学院宁波材料技术与工程研究所，中国科学院海洋新材料与应用技术重点实验室，浙江省海洋材料与防护技术重点实验室，宁波市高分子材料重点实验室，宁波 315201
  3.上海大学高分子材料系，上海 200444
- 作者简介：
- 基金信息：
  
  Ningbo Innovation Project(2015B11003)
- DOI：10.14028/j.cnki.1003-3726.2017.04.004
  CLC：
- Published：01 April 2017，
  
  Received：10 October 2016，
  
  Revised：22 January 2017，
扫描看全文
Peng WANG, Wei HUANG, Ming-qiao LIU, Peng CHEN, Wen-qin WANG. Advances in Relationship between Structure and Properties of Furan-based Polyesters. [J]. Polymer Bulletin 30(4):33-41(2017)
DOI：

Peng WANG, Wei HUANG, Ming-qiao LIU, Peng CHEN, Wen-qin WANG. Advances in Relationship between Structure and Properties of Furan-based Polyesters. [J]. Polymer Bulletin 30(4):33-41(2017) DOI： 10.14028/j.cnki.1003-3726.2017.04.004.

摘要

呋喃基聚酯是指以2，5-呋喃二甲酸（FDCA)为主要单体合成的生物基或部分生物基高分子，其主链含有刚性的呋喃环，因而在结构、性能上与大规模使用的传统石油基芳香族聚酯（如PET、PBT）相似，有望在瓶、片、薄膜、化纤等领域部分替代后者。本文综述了呋喃基聚酯的分子结构、聚集态结构以及力学、气体阻隔、降解等性能方面的最新研究进展，讨论了结构与性能之间的关系。重点关注呋喃基聚酯突出的阻隔性能及其对应的影响因素，主要从分子结构（呋喃环的非对称性和极性）和聚集态结构（结晶等）两方面加以阐明。简介了呋喃基聚酯的发展现状及其在包装、纺织等领域的潜在应用，并展望其主要研究趋势。

Abstract

Furan-based polyesters represent a family of fully or partially bio-based polymers synthesized with 2

5- furandicarboxylic acid (FDCA) as the major monomer. Since the furan ring is rigid

the furan-based polyesters are highly comparable in structure and performance with the traditional fossil-based aromatic polyesters (e. g.

PET and PBT) which have been used in a large scale. It is thus potential to replace the traditional aromatic polyesters with the furan-based polyesters at least partially in bottles

sheets

films

fibers

etc. This paper reviews recent advances in the research on the furan-based polyesters

including the molecular structure

state of aggregation

mechanical

gas-barrier and degradation properties

as well as the relationship between them. Focus is on the outstanding gas-barrier performance of the furan- based polyesters and the relevant governing factors including the molecular structure (the asymmetric geometry and polarity of the furan ring) and the state of aggregation (such as crystallization). A brief introduction is also made on the state-of- the-art and potential applications of the furan-based polyesters in packages and textiles and an outlook is given in the research trend.

关键词

呋喃基聚酯结构性能结构与性能关系

Keywords

Furan-based polyestersStructurePropertiesRelationship between structure and properties

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