Application of Photo-Induced ATRP/Click Technology in Synthesis of Topological Polymers

Man-fang CHENG; Ze-yu LIU; Wen-qing WANG; Na LI; Liang-cai LEI; Hai-ying LI

doi:10.14028/j.cnki.1003-3726.2021.04.002

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Application of Photo-Induced ATRP/Click Technology in Synthesis of Topological Polymers

更新时间：2022-08-30

- Application of Photo-Induced ATRP/Click Technology in Synthesis of Topological Polymers
- Polymer Bulletin Vol. 34, Issue 4, Pages: 7-14(2021)
- 作者机构：
  
  辽宁石油化工大学化学化工与环境学部,抚顺 113001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2021.04.002
  CLC：
- Published：20 April 2021，
  
  Received：24 December 2019，
  
  Revised：21 December 2020，
扫描看全文
Man-fang CHENG, Ze-yu LIU, Wen-qing WANG, Na LI, Liang-cai LEI, Hai-ying LI. Application of Photo-Induced ATRP/Click Technology in Synthesis of Topological Polymers. [J]. Polymer Bulletin 34(4):7-14(2021)
DOI：

Man-fang CHENG, Ze-yu LIU, Wen-qing WANG, Na LI, Liang-cai LEI, Hai-ying LI. Application of Photo-Induced ATRP/Click Technology in Synthesis of Topological Polymers. [J]. Polymer Bulletin 34(4):7-14(2021) DOI： 10.14028/j.cnki.1003-3726.2021.04.002.

摘要

随着绿色合成理念的不断提升

操作简便的光化学逐渐引起研究者的广泛关注。光化学与活性/可控原子转移自由基聚合(ATRP)或高活性、高选择性的点击化学(Click)相结合

能够为准确构建各种拓扑结构的聚合物提供一种行之有效的方法。近年来

光诱导ATRP/Click技术在高分子的制备中得到越来越多的应用

众多具有复杂结构和特殊功能的聚合物已见报道。本文对该领域的最新研究进行了综述

重点介绍了嵌段、接枝、环状及其它拓扑结构聚合物的制备以及这些聚合物在药物载体、生物材料、光电和热敏材料等方面的应用。

Abstract

Photo-chemistry has attracted widespread attention of researchers due to its easily-operating and environmentfriendly technology. Photo-Induced living/controlled atom transfer radical polymerization and click chemistry (Photo- Induced ATRP/Click) is an effective method to accurately synthesize polymers with various topological structures. In the past decade

photo-induced ATRP/Click technique has been used frequently in the preparation of polymers

and more and more macromolecules with complex structures and special functions have been prepared by the technique. In this paper

the recent development in the field was summarized and the emphases were on the preparation of block

graft

cyclic and other topological polymers through photo-induced ATRP/Click. In addition

the applications of these polymers in pharmaceutical carriers

bio-materials

photo-electrics and thermal-sensitive materials were reviewed.

关键词

光化学ATRPClick高分子合成

Keywords

Photo-chemistryATRPClick chemistryPolymer synthesis

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