Application of Dynamic Mechanical Analysis in Characterization of Vitrimers

LIU Wei-wei; CHEN Yu-di; HAN Yi-tian; LI Ya-li; ZHAO Jin; GUO Shu; ZOU Tao

doi:10.14028/j.cnki.1003-3726.2024.23.216

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Application of Dynamic Mechanical Analysis in Characterization of Vitrimers

更新时间：2024-02-06

- Application of Dynamic Mechanical Analysis in Characterization of Vitrimers
- Polymer Bulletin Vol. 37, Issue 3, Pages: 328-337(2024)
- 作者机构：
  
  北京市科学技术研究院分析测试研究所(北京市理化分析测试中心)，有机材料检测技术与质量评价北京市重点实验室，北京 100089
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.23.216
  CLC：
- Received：27 June 2023，
  
  Accepted：28 July 2023，
  
  Published：20 March 2024
- 稿件说明：
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刘卫卫, 陈宇迪, 韩倚天, 李亚莉, 赵瑾, 郭姝, 邹涛. 动态力学分析技术在类玻璃高分子性能表征中的应用. 高分子通报, 2024, 37(3), 328–337

Liu, W. W.; Chen, Y. D.; Han, Y. T.; Li, Y. L.; Zhao, J.; Guo, S.; Zou, T. Application of dynamic mechanical analysis in characterization of vitrimers. Polym. Bull. (in Chinese), 2024, 37(3), 328–337
刘卫卫, 陈宇迪, 韩倚天, 李亚莉, 赵瑾, 郭姝, 邹涛. 动态力学分析技术在类玻璃高分子性能表征中的应用. 高分子通报, 2024, 37(3), 328–337 DOI： 10.14028/j.cnki.1003-3726.2024.23.216.

Liu, W. W.; Chen, Y. D.; Han, Y. T.; Li, Y. L.; Zhao, J.; Guo, S.; Zou, T. Application of dynamic mechanical analysis in characterization of vitrimers. Polym. Bull. (in Chinese), 2024, 37(3), 328–337 DOI： 10.14028/j.cnki.1003-3726.2024.23.216.

摘要

类玻璃高分子因结合了热塑性材料可塑形变的能力以及热固性材料永久定型的特征，目前在高分子研究领域备受青睐。采用动态力学分析技术可深入研究此类材料的动态黏弹性和流变行为，建立类玻璃高分子交联网络、动态键等结构与材料性能间的关系。本文重点阐述动态力学分析技术在类玻璃高分子的动态黏弹性、交联网络结构、流变行为、膨胀及形状记忆行为等方面的表征应用，为此类材料的结构设计、性能评价以及加工应用等从测试表征角度提供参考。

Abstract

Vitrimers are booming in macromolecule research field because of the combination of the plasticity of thermoplastic materials and the permanent properties of thermosetting materials. The dynamic viscoelastic and rheological behaviors of these materials can be studied in-depth by dynamic mechanics analysis

contributing to establishing the relationships between vitrimer structures

such as crosslinking networks and dynamic bonds

and material properties. In this short review

applications of dynamic mechanical analysis in the detection of the dynamic viscoelasticity

cross-linking network structures

rheological behavior

expansion and shape memory behavior of vitrimers are summarized

providing a reference for the structural design

performance characterization and processing applications of such materials.

关键词

Keywords

references

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