Preparation and Characterization of Poly(butylene adipate-<italic style="font-style: italic">co</italic>-terephthalate)/Poly(3-hydroxybutyrate-<italic style="font-style: italic">co</italic>-4-hydroxybutyrate) Blends

XIAO Xiang-lian; YIN Lin-li; ZHANG Xi-bai; LEI Ya-fang; YANG Yi-hu; CHEN Rui; ZHOU Chao; ZHANG Xiang-nan; HUANG Jian-ping

doi:10.14028/j.cnki.1003-3726.2024.23.245

您当前的位置：

首页 >

文章列表页 >

Preparation and Characterization of Poly(butylene adipate-co-terephthalate)/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) Blends

更新时间：2024-02-06

- Preparation and Characterization of Poly(butylene adipate-co-terephthalate)/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) Blends
- Polymer Bulletin Vol. 37, Issue 3, Pages: 338-344(2024)
- 作者机构：
  
  1..湖南工学院材料科学与工程学院，衡阳 421002
  2..深圳光华伟业股份有限公司，深圳 518057
  3..孝感易生新材料有限公司，孝感 432100
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.23.245
  CLC：
- Received：14 July 2023，
  
  Accepted：17 August 2023，
  
  Published：20 March 2024
- 稿件说明：
移动端阅览
肖湘莲, 尹琳丽, 张熙柏, 雷雅芳, 杨义浒, 陈锐, 周超, 张向南, 黄建平. 聚对苯二甲酸-己二酸丁二酯/聚3-羟基丁酸酯4-羟基丁酸酯共混材料的制备及性能表征. 高分子通报, 2024, 37(3), 338–344

Xiao, X. L.; Yin, L. L.; Zhang, X. B.; Lei, Y. F.; Yang, Y. H.; Chen, R.; Zhou, C.; Zhang, X. N.; Huang, J. P. Preparation and characterization of poly(butylene adipate-co-terephthalate)/poly(3-hydroxybutyrate-co-4-hydroxybutyrate) blends. Polym. Bull. (in Chinese), 2024, 37(3), 338–344
肖湘莲, 尹琳丽, 张熙柏, 雷雅芳, 杨义浒, 陈锐, 周超, 张向南, 黄建平. 聚对苯二甲酸-己二酸丁二酯/聚3-羟基丁酸酯4-羟基丁酸酯共混材料的制备及性能表征. 高分子通报, 2024, 37(3), 338–344 DOI： 10.14028/j.cnki.1003-3726.2024.23.245.

Xiao, X. L.; Yin, L. L.; Zhang, X. B.; Lei, Y. F.; Yang, Y. H.; Chen, R.; Zhou, C.; Zhang, X. N.; Huang, J. P. Preparation and characterization of poly(butylene adipate-co-terephthalate)/poly(3-hydroxybutyrate-co-4-hydroxybutyrate) blends. Polym. Bull. (in Chinese), 2024, 37(3), 338–344 DOI： 10.14028/j.cnki.1003-3726.2024.23.245.

摘要

采用熔融共混制备了聚对苯二甲酸-己二酸丁二酯(poly(butylene adipate-

-terephthalate)，PBAT)与聚3-羟基丁酸酯4-羟基丁酸酯(poly(3-hydroxybutyrate

-co

-4-hydroxybutyrate)，P34HB)的共混材料。研究了P34HB含量(0 wt%

5 wt%、10 wt%、15 wt%、20 wt%)对共混材料熔体流动性能、力学性能、热性能和界面微观形貌的影响，及其PBAT/P34HB吹塑薄膜的力学性能和氧气阻隔性能。结果表明，P34HB的加入降低了材料的熔体黏度，提高了材料的流动性以及薄膜的直角撕裂性能、穿刺性能和氧气阻隔性能。当P34HB含量为5 wt%时，共混材料综合性能最佳，两相相容性良好，共混材料和吹塑薄膜均具有优异的力学性能，薄膜的拉伸性能和穿刺强度最高，是性能优异的包装和农膜材料。

Abstract

The blends of poly(butylene adipate-

-terephthalate) (PBAT)/poly(3-hydroxybutyrate-

-4-hydroxybutyrate) (P34HB) were prepared by melt-compounding. The effects of P34HB content (0 wt%

5 wt%

10 wt%

15 wt%

20 wt%) on the melt flowability

tensile properties

thermal behavior and interfacial morphology of the blends were investigated. The mechanical properties and barrier properties of the blown films were also studied. The results indicated that the incorporation of P34HB increased the melt flowability of PBAT

improved the right-angle tear strength

puncture strength and oxygen barrier property of blown films. When the weight content of P34HB is 5 wt%

the blend exhibited the highest comprehensive performance

PBAT and P34HB showed good compatibility

the blend displayed excellent mechanical properties for both injection samples and blown films

and the film demonstrated the highest tensile and puncture strength

showing promising application prospects for package and agriculture film.

关键词

Keywords

references

D. Garcia-Garcia, ; L. Quiles-Carrillo, ; R. Balart, ; S. Torres-Giner, ; M. P Arrieta, . Innovative solutions and challenges to increase the use of poly(3-hydroxybutyrate) in food packaging and disposables . Eur. Polym. J. , 2022 , 178 , 111505 .

H. Dahlbo, ; V. Poliakova, ; V. Mylläri, ; O. Sahimaa, ; R Anderson, . Recycling potential of post-consumer plastic packaging waste in Finland . Waste Manag. , 2018 , 71 , 52 – 61 .

L. Shen, ; E Worrell, . Plastic recycling . Handbook of Recycling . Amsterdam : Elsevier , 2014 , 179 – 190 .

M Shimao, . Biodegradation of plastics . Curr. Opin. Biotechnol. , 2001 , 12 ( 3 ), 242 – 247 .

M. Eesaee, ; P. Ghassemi, ; D. D. Nguyen, ; S. Thomas, ; S. Elkoun, ; P Nguyen-Tri, . Morphology and crystallization behaviour of polyhydroxyalkanoates-based blends and composites: a review . Biochem. Eng. J. , 2022 , 187 , 108588 .

T. Ahmed, ; M. Shahid, ; F. Azeem, ; I. Rasul, ; A. A. Shah, ; M. Noman, ; A. Hameed, ; N. Manzoor, ; I. Manzoor, ; S Muhammad, . Biodegradation of plastics: current scenario and future prospects for environmental safety . Environ. Sci. Pollut. Res. Int. , 2018 , 25 ( 8 ), 7287 – 7298 .

X. L. Xiao, ; V. S. Chevali, ; P. G. Song, ; D. N. He, ; H Wang, . Polylactide/hemp hurd biocomposites as sustainable 3D printing feedstock . Compos. Sci. Technol. , 2019 , 184 , 107887 .

X. L. Xiao, ; V. S. Chevali, ; P. G. Song, ; B. Yu, ; Y. H. Yang, ; H Wang, . Enhanced toughness of PLLA/PCL blends using poly(d-lactide)-poly( ε -caprolactone)-poly(d-lactide) as compatibilizer . Compos. Commun. , 2020 , 21 , 100385 .

A. R. de Matos Costa, ; A. Crocitti, ; L. Hecker de Carvalho, ; S. C. Carroccio, ; P. Cerruti, ; G Santagata, . Properties of biodegradable films based on poly(butylene succinate) (PBS) and poly(butylene adipate- co -terephthalate) (PBAT) blends . Polymers , 2020 , 12 ( 10 ), 2317 .

H. R. Yang, ; G. Jia, ; H. Wu, ; C. C. Ye, ; K. Yuan, ; S. L. Liu, ; L. M. Zhou, ; H. Xu, ; L. J. Gao, ; J. Cui, ; S. M Fang, . Design of fully biodegradable super-toughened PLA/PBAT blends with asymmetric composition via reactive compatibilization and controlling morphology . Mater. Lett. , 2022 , 329 , 133067 .

F. V. Ferreira, ; L. S. Cividanes, ; R. F. Gouveia, ; L. M. F Lona, . An overview on properties and applications of poly(butylene adipate -co- terephthalate)-PBAT based composites . Polym. Eng. Sci. , 2019 , 59 ( s2 ), E7 – E15 .

王杰 , 王泽云 , 辛德华 , 周洪福 , 田华峰 , 吴卫东 . PBAT改性及其发泡材料的研究进展 . 高分子通报 , 2023 , 36 ( 2 ), 191 – 199 .

K. Ghosh, ; B. H Jones, . Roadmap to biodegradable plastics—current state and research needs . ACS Sustain. Chem. Eng. , 2021 , 9 ( 18 ), 6170 – 6187 .

S. S. de Campos, ; A. de Oliveira, ; T. F. M. Moreira, ; T. B. V. da Silva, ; M. V. da Silva, ; J. A. Pinto, ; A. P. Bilck, ; O. H. Gonçalves, ; I. P. Fernandes, ; M. F. Barreiro, ; F. Yamashita, ; P. Valderrama, ; M. A. Shirai, ; F. V Leimann, . TPCS/PBAT blown extruded films added with curcumin as a technological approach for active packaging materials . Food Packag. Shelf Life , 2019 , 22 , 100424 .

D. C. França, ; T. G. Almeida, ; G. Abels, ; E. L. Canedo, ; L. H. Carvalho, ; R. M. R. Wellen, ; K. Haag, ; K Koschek, . Tailoring PBAT/PLA/Babassu films for suitability of agriculture mulch application . J. Nat. Fibers , 2019 , 16 ( 7 ), 933 – 943 .

张田伟 , 梁嘉欣 , 岳双双 , 王拴紧 , 韩东梅 , 黄盛 , 孟跃中 , 肖敏 . 可生物降解的半芳香聚酯聚碳酸丙烯酯共聚物/聚己二酸-对苯二甲酸丁二酯共混物的制备及性能表征 . 高分子学报 , 2023 , 54 ( 8 ), 1144 – 1154 .

X. Wang, ; S. X. Peng, ; H. Chen, ; X. L. Yu, ; X. P Zhao, . Mechanical properties, rheological behaviors, and phase morphologies of high-toughness PLA/PBAT blends by in situ reactive compatibilization . Compos. B , 2019 , 173 , 107028 .

H. W. Pan, ; Y. P. Hao, ; Y. Zhao, ; X. Z. Lang, ; Y. Zhang, ; Z. Wang, ; H. L. Zhang, ; L. S Dong, . Improved mechanical properties, barrier properties and degradation behavior of poly(butylenes adipate -co- terephthalate)/poly(propylene carbonate) films . Korean J. Chem. Eng. , 2017 , 34 ( 5 ), 1294 – 1304 .

李梅 , 李志强 , 邵蔚 . 聚(3-羟基丁酸- co -4-羟基丁酸酯)/碳纳米管复合微孔发泡薄膜研究 . 功能材料 , 2014 , 45 ( 18 ), 18087 – 18091 .

高兆营 , 马莹 , 刘慧芳 , 闫松 , 王战勇 . 生物降解聚(3-羟基丁酸 -co- 4-羟基丁酸酯)改性研究进展 . 工程塑料应用 , 2015 ; 43 ( 12 ), 127 – 131 .

X. Y. Wang, ; H. W. Pan, ; S. L. Jia, ; Z. W. Cao, ; L. J. Han, ; H. L. Zhang, ; L. S Dong, . Mechanical properties, crystallization and biodegradation behavior of the polylactide/poly(3-hydroxybutyrate- co -4-hydroxybuty-rate)/poly(butylene adipate- co -terephthalate) blown films . Chinese J. Polym. Sci. , 2020 , 38 ( 10 ), 1072 – 1081 .

Y. H. Jian, ; Y. F Zhu, . Poly(3-hydroxybutyrate 4-hydroxy-butyrate) (P34HB) as a potential polymer for drug-eluting coatings on metal coronary stents . Polymers , 2022 , 14 ( 5 ), 994 .

S. Jurczyk, ; M. Musio, ; M. Sobota, ; M. Klim, ; A. Hercog, ; P. Kurcok, ; H. Janeczek, ; J Rydz, . (Bio)degradable polymeric materials for sustainable future—Part 2: degradation studies of P(3HB- co -4HB)/cork composites in different environments . Polymers , 2019 , 11 ( 3 ), 547 .

李梅 , 许军 , 李志强 . 聚(3-羟基丁酸酯- co -4-羟基丁酸酯)的扩链改性 . 合成树脂及塑料 , 2011 , 28 ( 1 ), 66 – 70 .

R. Al-Itry, ; Franco, K. Lamnawar, ; A. Maazouz, . Improvement of thermal stability, rheological and mechanical properties of PLA, PBAT and their blends by reactive extrusion with functionalized epoxy . Polym. Degrad. Degrad. Stabil. , 2012 , 97 ( 10 ), 1898 – 1914 .

M. Zhang, ; C. Jiang, ; Q. H. Wu, ; G. L. Zhang, ; F. X. Liang, ; Z. Z Yang, . Poly(lactic acid)/poly(butylene succinate) (PLA/PBS) layered composite gas barrier membranes by anisotropic Janus nanosheets compartibilizers . ACS Macro Lett. , 2022 , 11 ( 5 ), 657 – 662 .

张也 . 生物可降解聚己二酸对苯二甲酸丁二酯(PBAT)共混物及薄膜的制备与性能研究 . 长春 : 长春工业大学 , 2022 .

F. Wu, ; M. Misra, ; A. K Mohanty, . Challenges and new opportunities on barrier performance of biodegradable polymers for sustainable packaging . Prog. Polym. Sci. , 2021 , 117 , 101395 .

Views

586

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Studies on Mechanical Properties of Polymer Films under Nanoconfinement Effect

Study on Graphene Oxide Modified Polyvinylbutyral Transparent Polymer Films

Research Progress of β Crystal Structures of Poly(3-hydroxybutyrate) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Their Relationship with Mechanical and Degradation Properties

Molecular Structure Design and Development Status of High Performance Polyimide Fiber

Research Progress of Polymer Fiber Reinforced 3D Printing Concrete Materials

Related Author

GUO Yun-long

BAI Pei

XIAO Yu-han

YANG Xue-lun

YUE Rui-heng

HUANG Cai-yang

LIU Ying-liang

CAO Shao-kui

Related Institution

University of Michigan-Shanghai Jiao Tong University Joint Institute, Shanghai Jiao Tong University

School of Materials Science and Engineering, Zhengzhou University

Guangdong Huatong New Material Technology Co., Ltd.

Institute of Chemistry, Chinese Academy of Sciences

School of Packaging and Materials Engineering, Hunan University of Technology

⁰

Preparation and Characterization of Poly(butylene adipate-co-terephthalate)/Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) Blends

DOI：10.14028/j.cnki.1003-3726.2024.23.245

摘要

Abstract

关键词

Keywords

references