Catalytic and Nucleation Study of Ti3C2T<italic style="font-style: italic">x</italic> MXene on Furanic Polyesters

FEI Xuan; JIANG Yan-hua; WANG Ying-jie; LU Guang-ming; ZHAO Wei-wei; LIU Xiao-qing

doi:10.14028/j.cnki.1003-3726.2024.23.249

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Catalytic and Nucleation Study of Ti₃C₂T_x MXene on Furanic Polyesters

更新时间：2024-02-06

- Catalytic and Nucleation Study of Ti₃C₂T_x MXene on Furanic Polyesters
- Polymer Bulletin Vol. 37, Issue 3, Pages: 377-384(2024)
- 作者机构：
  
  中国科学院宁波材料技术与工程研究所，宁波 315201
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.23.249
  CLC：
- Published：20 March 2024，
  
  Received：17 August 2023，
  
  Accepted：08 October 2023
- 稿件说明：
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费璇, 江艳华, 王英杰, 卢光明, 赵伟伟, 刘小青. Ti₃C₂T_x MXene对聚2,5-呋喃二甲酸乙二醇酯的催化成核作用研究. 高分子通报, 2024, 37(3), 377–384

Fei, X.; Jiang, Y. H.; Wang, Y. J.; Lu, G. M.; Zhao, W. W.; Liu, X. Q. Catalytic and nucleation study of Ti₃C₂T_x MXene on furanic polyesters. Polym. Bull. (in Chinese), 2024, 37(3), 377–384
费璇, 江艳华, 王英杰, 卢光明, 赵伟伟, 刘小青. Ti₃C₂T_x MXene对聚2,5-呋喃二甲酸乙二醇酯的催化成核作用研究. 高分子通报, 2024, 37(3), 377–384 DOI： 10.14028/j.cnki.1003-3726.2024.23.249.

Fei, X.; Jiang, Y. H.; Wang, Y. J.; Lu, G. M.; Zhao, W. W.; Liu, X. Q. Catalytic and nucleation study of Ti₃C₂T_x MXene on furanic polyesters. Polym. Bull. (in Chinese), 2024, 37(3), 377–384 DOI： 10.14028/j.cnki.1003-3726.2024.23.249.

摘要

长期以来，聚酯催化剂主要为锑系化合物，存在潜在的重金属污染风险。为开发一种高效环保的聚酯缩聚催化剂，本工作首先对新型二维材料Ti

MXene与代表性锑系催化剂Sb

进行催化对比研究。结果发现，Ti

MXene对聚2

5-呋喃二甲酸乙二醇酯(PEF)有显著的缩聚催化活性，所得PEF特性黏度可以达到0.74 dL/g。其次，使用差示扫描量热仪(DSC)对两种催化剂制备的PEF聚酯进行热性能与结晶动力学研究，确认了具有异质纳米片结构的Ti

MXene可以作为成核剂提升PEF的结晶速率。最后，机械性能研究表明，催化剂种类不影响PEF的拉伸模量与拉伸强度，进一步表明Ti

MXene与PEF的相容性较好。综上，本工作表明Ti

MXene是PEF的高效催化/成核剂。

Abstract

Polyester catalysts are mainly antimony-based compounds for a long time

which have potential heavy-metal hazards. To develop an efficient and environmentally friendly polycondensation catalyst

firstly

a comparative catalytic study of the novel two-dimensional material Ti

MXene and the representative antimony-based catalyst Sb

was conducted. The results showed that Ti

MXene exhibited significant catalytic activity for the condensation of polyethylene 2

5-furandicarboxylate (PEF) with intrinsic viscosity up to 0.74 dL/g. Secondly

the thermal properties and crystallization kinetics of PEF prepared by both catalysts were investigated using differential scanning calorimetry (DSC). Ti

MXene with the heterogeneous nanosheet structure was confirmed as a nucleating agent to enhance the crystallization rate of PEF. Finally

the mechanical investigation showed that the catalyst type did not affect the mechanical properties of PEF

indicating the good compatibility of Ti

MXene with PEF. In summary

this work showed that Ti

MXene is an efficient catalyst/nucleating agent for PEF.

关键词

25-呋喃二甲酸聚酯MXene催化合成结晶性能

Keywords

25-Furandicarboxylic acidPolyestersMXeneCatalytic synthesisCrystallization property

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Catalytic and Nucleation Study of Ti3C2Tx MXene on Furanic Polyesters

DOI：10.14028/j.cnki.1003-3726.2024.23.249

摘要

Abstract

关键词

Keywords

references

Catalytic and Nucleation Study of Ti₃C₂T_x MXene on Furanic Polyesters