Research Progress on Heat Resistant Modification of Polylactide

LI Hao-chen; ZHANG Xiang; LONG Yun-rui; XING Qian; LI Rong-bo

doi:10.14028/j.cnki.1003-3726.2024.23.265

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Research Progress on Heat Resistant Modification of Polylactide

更新时间：2024-03-25

- Research Progress on Heat Resistant Modification of Polylactide
- Polymer Bulletin Vol. 37, Issue 4, Pages: 430-441(2024)
- 作者机构：
  
  1..北京工商大学化学与材料工程学院，北京　 100048
  2..中国石油天然气股份有限公司石油化工研究院，北京　 100195
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.23.265
  CLC：
- Published：20 April 2024，
  
  Received：01 August 2023，
  
  Accepted：07 October 2023
- 稿件说明：
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李昊晨, 张祥, 龙云瑞, 邢倩, 李荣波. 聚乳酸耐热改性的研究进展. 高分子通报, 2024, 37(4), 430–441

Li, H. C.; Zhang, X.; Long, Y. R.; Xing, Q.; Li, R. B. Research progress on heat resistant modification of polylactide. Polym. Bull. (in Chinese), 2024, 37(4), 430–441
李昊晨, 张祥, 龙云瑞, 邢倩, 李荣波. 聚乳酸耐热改性的研究进展. 高分子通报, 2024, 37(4), 430–441 DOI： 10.14028/j.cnki.1003-3726.2024.23.265.

Li, H. C.; Zhang, X.; Long, Y. R.; Xing, Q.; Li, R. B. Research progress on heat resistant modification of polylactide. Polym. Bull. (in Chinese), 2024, 37(4), 430–441 DOI： 10.14028/j.cnki.1003-3726.2024.23.265.

摘要

聚乳酸(PLA)是一种兼具良好生物相容性、力学以及加工性能的生物基可降解脂肪族聚酯，因此，在医药、食品包装等领域得到广泛应用。然而，PLA结晶速率慢、所得制品结晶度低、耐热性差，严重制约了其在高温环境下的使用。本文综述了国内外聚乳酸耐热改性方面的研究进展，重点阐述通过化学共聚、交联、共混以及外场作用(热处理、拉伸)等手段提高PLA耐热性的方法，并对耐热聚乳酸材料的发展前景进行了展望。

Abstract

Polylactide (PLA) is a biodegradable polymer with excellent biocompatibility

mechanical properties

and processing properties

which has been widely used in fields such as medicine and food packaging. However

the slow crystallization rate

low crystallinity

and poor heat resistance of PLA seriously restrict its application in high-temperature environments. The research progress of heat-resistant modification of PLA at home and abroad is reviewed. The progress of improving the heat resistance of PLA by means of chemical copolymerization

crosslinking

blending and external field (heat treatment

stretching) is emphasized. The development prospect of heat-resistant polylactic acid materials is prospected.

关键词

聚乳酸耐热性结晶共混立构晶

Keywords

PolylactideHeat resistanceCrystallizationBlendingStereocomplex

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