Study on Solution Polymerization of 1-Butene Catalyzed by Metallocene in a Microchannel Reactor

WU Shi-hu; WANG Ke-feng; LI Qian; LI Hua-yi

doi:10.14028/j.cnki.1003-3726.2024.23.318

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Study on Solution Polymerization of 1-Butene Catalyzed by Metallocene in a Microchannel Reactor

更新时间：2024-03-25

- Study on Solution Polymerization of 1-Butene Catalyzed by Metallocene in a Microchannel Reactor
- Polymer Bulletin Vol. 37, Issue 4, Pages: 486-490(2024)
- 作者机构：
  
  1..中国科学院化学研究所工程塑料重点实验室，北京　 100190
  2..中国石油天然气股份有限公司石油化工研究院，北京　 102206
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.23.318
  CLC：
- Published：20 April 2024，
  
  Received：19 September 2023，
  
  Accepted：21 October 2023
- 稿件说明：
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吴世虎, 王科峰, 李倩, 李化毅. 微通道反应器中茂金属催化1-丁烯聚合研究. 高分子通报, 2024, 37(4), 486–490

Wu, S. H.; Wang, K. F.; Li, Q.; Li, H. Y. Study on solution polymerization of 1-butene catalyzed by metallocene in a microchannel reactor. Polym. Bull. (in Chinese), 2024, 37(4), 486–490
吴世虎, 王科峰, 李倩, 李化毅. 微通道反应器中茂金属催化1-丁烯聚合研究. 高分子通报, 2024, 37(4), 486–490 DOI： 10.14028/j.cnki.1003-3726.2024.23.318.

Wu, S. H.; Wang, K. F.; Li, Q.; Li, H. Y. Study on solution polymerization of 1-butene catalyzed by metallocene in a microchannel reactor. Polym. Bull. (in Chinese), 2024, 37(4), 486–490 DOI： 10.14028/j.cnki.1003-3726.2024.23.318.

摘要

以

rac

-Me

Si(2

5-Me

-4-Ph-ThCp)

ZrCl

茂金属为主催化剂，甲基铝氧烷(MAO)为助催化剂，二甲苯为溶液在1/8英寸不锈钢管搭建的微通道反应器中进行1-丁烯的溶液聚合。在本研究中，1-丁烯成功在微通道反应器的管道中实现连续聚合，并表征了所得聚合物的结构与性能。

Abstract

Solution homopolymerization of 1-butene was performed in a microchannel reactor constructed of 1/8-inch stainless steel tube

using

rac

-Me

Si(2

5-Me

-4-Ph-ThCp)

ZrCl

metallocene as the main catalyst

methylaluminoxane (MAO) as the cocatalyst

and xylene as the solution. In this study

continuous polymerization of 1-butene was achieved in the microchannel reactor

and the structure and properties of the polybutylenes were characterized.

关键词

微通道反应器茂金属催化剂1-丁烯溶液聚合

Keywords

Microchannel reactorMetallocene1-ButeneSolution polymerization

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