Advances in Synthesis and Functionality of Non-isocyanate Polyurethane

LIU Mei-qin; ZHAO Yu-mei; SHI Hong-cui; MA Xiao-long

doi:10.14028/j.cnki.1003-3726.2024.24.177

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Advances in Synthesis and Functionality of Non-isocyanate Polyurethane

更新时间：2024-11-20

- Advances in Synthesis and Functionality of Non-isocyanate Polyurethane
- Polymer Bulletin Vol. 37, Issue 11, Pages: 1570-1580(2024)
- 作者机构：
  
  1.山西铁道职业技术学院，太原 030013
  2.山西省应用化学研究所，太原 030027
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.177
  CLC：
- Published：20 November 2024，
  
  Published Online：13 August 2024，
  
  Received：13 June 2024，
  
  Accepted：17 July 2024
- 稿件说明：
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刘美琴, 赵玉梅, 石红翠, 马小龙. 非异氰酸酯聚氨酯的合成与功能性研究进展. 高分子通报, 2024, 37(11), 1570–1580

Liu, M. Q.; Zhao, Y. M.; Shi, H. C.; Ma, X. L. Advances in synthesis and functionality of non-isocyanate polyurethane. Polym. Bull. (in Chinese), 2024, 37(11), 1570–1580
刘美琴, 赵玉梅, 石红翠, 马小龙. 非异氰酸酯聚氨酯的合成与功能性研究进展. 高分子通报, 2024, 37(11), 1570–1580 DOI： 10.14028/j.cnki.1003-3726.2024.24.177.

Liu, M. Q.; Zhao, Y. M.; Shi, H. C.; Ma, X. L. Advances in synthesis and functionality of non-isocyanate polyurethane. Polym. Bull. (in Chinese), 2024, 37(11), 1570–1580 DOI： 10.14028/j.cnki.1003-3726.2024.24.177.

摘要

近年来，非异氰酸酯聚氨酯(NIPU)的研究重点已经不单是探索可靠的合成路线，功能性NIPU逐渐成为新的研究热点之一。本文首先总结了NIPU的4种合成方法，介绍了各方法的特点，其中环碳酸酯开环法以其高效、便利的特点，在生物基NIPU、功能性NIPU中被广泛采用。之后，文章重点探讨了NIPU在自修复、可再加工性、形状记忆和水性化等功能性研究方面的进展，这些功能性研究不仅提升了NIPU在可持续发展以及环境安全等方面的优势，也增加了NIPU技术落地的可能性。

Abstract

In recent years

the research focusing on non-isocyanate polyurethanes (NIPUs) has shifted from exploring reliable synthesis routes to the exploration of functional NIPUs

which has become a new research hotspot. This review summarizes four synthesis methods of NIPUs and introduces the characteristics of each method. Among them

the ring-opening approach of cyclic carbonates has been widely adopted in the synthesis of bio-based NIPUs and functional NIPUs due to its high efficiency and convenience. Subsequently

the review focuses on the progress of NIPU research in functional aspects such as self-healing

reprocessability

shape memory

and water-based formulations. These studies not only enhance the advantages of NIPUs in sustainable development and environmental safety but also increase the feasibility of NIPU technology implementation.

关键词

非异氰酸酯聚氨酯合成功能性

Keywords

Non-isocyanate polyurethaneSynthesisFunctionality

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