Self-healing Functional Polymers Triggered <italic style="font-style: italic">via</italic> External Stimuli

ZHANG Ze-ping; RONG Min-zhi; ZHANG Ming-qiu

doi:10.14028/j.cnki.1003-3726.2024.24.180

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Self-healing Functional Polymers Triggered via External Stimuli

更新时间：2024-11-20

- Self-healing Functional Polymers Triggered via External Stimuli
- Polymer Bulletin Vol. 37, Issue 11, Pages: 1503-1523(2024)
- 作者机构：
  
  聚合物复合材料及功能材料教育部重点实验室，广东省高性能树脂基复合材料重点实验室，中山大学绿色化学与分子工程研究院，中山大学化学学院，广州 510275
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.180
  CLC：
- Published：20 November 2024，
  
  Published Online：09 August 2024，
  
  Received：16 June 2024，
  
  Accepted：14 July 2024
- 稿件说明：
移动端阅览
张泽平, 容敏智, 章明秋. 外场作用下的自修复功能高分子. 高分子通报, 2024, 37(11), 1503–1523

Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Self-healing functional polymers triggered via external stimuli. Polym. Bull. (in Chinese), 2024, 37(11), 1503–1523
张泽平, 容敏智, 章明秋. 外场作用下的自修复功能高分子. 高分子通报, 2024, 37(11), 1503–1523 DOI： 10.14028/j.cnki.1003-3726.2024.24.180.

Zhang, Z. P.; Rong, M. Z.; Zhang, M. Q. Self-healing functional polymers triggered via external stimuli. Polym. Bull. (in Chinese), 2024, 37(11), 1503–1523 DOI： 10.14028/j.cnki.1003-3726.2024.24.180.

摘要

含有特定官能团、分子结构或者功能填料的功能高分子材料在电子信息、能源、生物医用等高新技术领域有着广阔的应用前景。由于功能高分子材料在制造和使用过程中，不可避免地会遭受损伤，以及化学成分和分子结构的变化，从而导致功能的衰减甚至丧失。自修复功能高分子可以在一定的外场作用下，通过化学或物理作用，实现非结构功能的恢复，显著提高材料的服役寿命和耐久性。本文综述了机械力、电场、光、微波、磁场、直接加热、湿度/水和化学试剂等外场条件激发的自修复功能高分子的研究进展，并仔细分析了各类激发方法的基本原理、实施过程和特点。在此基础上，进一步讨论了该领域的挑战和发展趋势，希望能推动自修复功能高分子材料的实际应用发展。

Abstract

Functional polymer materials containing specific functional groups

structures or functional fillers have broad application prospects in the fields of electronic information

energy and biology. During their manufacturing and usage

damage and variations in chemical compositions and molecular structures would inevitably occur

leading to attenuation and even

loss of valuable functionalities. Self-healing functional polymers can achieve the non-structural recovery of functional properties

via

chemical or physical interactions under external stimuli

which significantly improve service life and durability of the materials. The present article reviews the research progress of self-healing functional polymers triggered by external fields such as mechanical force

electric field

light

microwave

magnetic field

direct heating

humidity/water and chemical reagents. Meantime

the basic principles

implementation processes

and characteristics of various excitation methods are carefully analyzed. Based on the above analyses

the challenges and development trend of this emerging field are further discussed

in hope of promoting practical application of self-healing functional polymer materials.

关键词

自修复外场作用功能恢复功能高分子高分子复合材料

Keywords

Self-healingExternal conditionsFunctional restorationFunctional polymersPolymer composite materials

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Self-healing Functional Polymers Triggered via External Stimuli

DOI：10.14028/j.cnki.1003-3726.2024.24.180

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