Study on the Composition and Structure of <italic style="font-style: italic">Taraxacum koksaghyz</italic> Rubber from Different Origins

ZHENG Jia-gang; ZHANG Xue-chao; WANG Hao-zhi; ZHANG Xiao-ke; ZHAO Yan-fang; LIAO Xiao-xue

doi:10.14028/j.cnki.1003-3726.2024.24.202

您当前的位置：

首页 >

文章列表页 >

Study on the Composition and Structure of Taraxacum koksaghyz Rubber from Different Origins

更新时间：2024-11-20

- Study on the Composition and Structure of Taraxacum koksaghyz Rubber from Different Origins
- Polymer Bulletin Vol. 37, Issue 11, Pages: 1589-1596(2024)
- 作者机构：
  
  1.海南大学材料科学与工程学院，海口 570228
  2.伊犁哈萨克自治州农业科学研究所，伊宁 835100
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.202
  CLC：
- Published：20 November 2024，
  
  Published Online：29 August 2024，
  
  Received：11 July 2024，
  
  Accepted：06 August 2024
- 稿件说明：
移动端阅览
郑加刚, 张学超, 王浩志, 张小珂, 赵艳芳, 廖小雪. 不同产地蒲公英橡胶的组分和结构初探. 高分子通报, 2024, 37(11), 1589–1596

Zheng, J. G.; Zhang, X. C.; Wang, H. Z.; Zhang, X. K.; Zhao, Y. F.; Liao, X. X. Study on the composition and structure of Taraxacum koksaghyz rubber from different origins. Polym. Bull. (in Chinese), 2024, 37(11), 1589–1596
郑加刚, 张学超, 王浩志, 张小珂, 赵艳芳, 廖小雪. 不同产地蒲公英橡胶的组分和结构初探. 高分子通报, 2024, 37(11), 1589–1596 DOI： 10.14028/j.cnki.1003-3726.2024.24.202.

Zheng, J. G.; Zhang, X. C.; Wang, H. Z.; Zhang, X. K.; Zhao, Y. F.; Liao, X. X. Study on the composition and structure of Taraxacum koksaghyz rubber from different origins. Polym. Bull. (in Chinese), 2024, 37(11), 1589–1596 DOI： 10.14028/j.cnki.1003-3726.2024.24.202.

摘要

三叶天然橡胶因其卓越的物理机械性能而被广泛应用于社会生产生活中，其在需求量较大和应用广泛的同时，仍面临着种植地有限、病虫害和高成本等问题。蒲公英橡胶作为当前最具发展潜力的产胶植物之一，研究不同种植地的蒲公英橡胶组分和结构对于解决天然橡胶资源紧缺具有重要意义。本文采用溶剂法和酶解法提取蒲公英橡胶，分析其杂质含量、氮含量、灰分含量、凝胶含量，以及塑性初值和塑性保持率等理化性质。同时，利用傅里叶变换红外光谱(FTIR)和核磁共振波谱(NMR)对三叶天然橡胶和蒲公英橡胶的结构进行表征。结果表明，用溶剂法提取的蒲公英橡胶中，新疆产的蒲公英橡胶杂质含量、灰分含量高于内蒙古产的，而氮含量、凝胶含量、塑性初值、塑性保持率则低于内蒙古产的。酶解法提取的橡胶中，新疆产的蒲公英橡胶灰分含量高于内蒙古产的，而杂质含量、氮含量、凝胶含量、塑性初值、塑性保持率均低于内蒙古产的；同种方法提取的不同产地的蒲公英橡胶分子量相差不大；不同提取方法和不同产地的蒲公英橡胶在结构上与天然橡胶相同，均为顺-1

4-聚异戊二烯。

Abstract

Hevea brasiliensis is widely used in societal production and daily life due to its excellent physical and mechanical properties. Despite its high demand and broad applications

it still faces limitations such as restricted cultivation areas

susceptibility to pests and diseases

and high costs.

Taraxacum koksaghyz

rubber

being one of the most promising rubber-producing plants

holds significant potential for optimizing cultivation and application through the study of its composition and structure from different growing regions. In this study

solvent extraction and enzymatic hydrolysis were employed to extract

Taraxacum koksaghyz

rubber

analyzing its impurity content

nitrogen content

ash content

gel content

plasticity initial value

and plasticity retention index. Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) spectroscopy were used to characterize the structure of both Hevea brasiliensis rubber and

Taraxacum koksaghyz

rubber. Re

sults showed that for solvent-extracted rubber

Taraxacum koksaghyz

rubber from Xinjiang had higher impurity and ash content but lower nitrogen content

gel content

plasticity initial value

and plasticity retention index

compared to those from Inner Mongolia. For enzymatically hydrolyzed rubber

Taraxacum koksaghyz

rubber from Xinjiang had higher ash content but lower impurity content

nitrogen content

gel content

plasticity initial value

and plasticity retention index

compared to those from Inner Mongolia. The molecular weight of

Taraxacum koksaghyz

rubber from different origins

extracted by the same method

was similar

exceeding one million. The structure of

Taraxacum koksaghyz

rubber from different methods and origins was identical to that of natural rubber

being cis-1

4-polyisoprene.

关键词

蒲公英橡胶产地提取方法理化性质结构

Keywords

Taraxacum koksaghyz rubberOriginExtraction methodPhysicochemical propertiesStructure

references

刘源博. 蒲公英橡胶草橡胶定量分析、橡胶提取及结构与性能表征. 北京: 北京化工大学, 2016.

杨柳, 姜莹, 陈宇方, 颜渊, 巍朱芙蓉, 周志诚, 刘国钧, 王进. 天然橡胶、异戊橡胶和天然橡胶/异戊橡胶并用胶的鉴定方法. 合成橡胶工业, 2023, 46(6), 449-456.

Xu, M. H.; Zhang, Y.; Yang, X.; Xing, J. F.; Qi, J. Y.; Zhang, S. M.; Zhang, Y. H.; Ye, D.; Tang, C. R.Genome-wide analysis of the SWEET genes in Taraxacum kok-saghyz rodin: an insight into two latex-abundant isoforms. Plant Physiol. Biochem., 2023, 194, 440-448.

Zhuo, Y. P.; Zhang, C.; Zhao, Y. F.; Hu, B. X.; Liao, S. Q.; Liao, X. X.Composition properties of rubber from parts of Taraxacum kok-saghyz roots. J. Rubber Res., 2021, 24(4), 607-613.

Zhao, S.; Jie, X.; Ma, Z.; Wang, Z.; Zhang, J. C.; Li, Y. S.; Nie, Q. H.; Ma, Y.Preparation of Taraxacum koksaghyz rubber and biofuel ethanol simultaneously by the yeast fermentation process. ACS Omega, 2023, 8(27), 24185-24197.

李卓, 刘禹, 李淑君, 梁素钰. 橡胶草草根化学组成分析. 广东化工, 2015, 42(15), 16-18.

Salehi, M.; Bahmankar, M.; Naghavi, M. R.; Cornish, K.Rubber and latex extraction processes for Taraxacum koksaghyz. Ind. Crops Prod., 2022, 178, 114562.

Yuan, B.; Ding, G.; Ma, J.; Wang, L.; Yu, L.; Ruan, X.; Zhang, X.; Zhang, W.; Wang, X.; Xie, Q.Comparison of morphological characteristics and determination of different patterns for rubber particles in dandelion and different rubber grass varieties. Plants, 2020, 9(11), E1561.

Saeedi, F.; Naghavi, M. R.; Sabokdast, M.; Jariani, P. L.E.Rodin, as a novel potential source of natural rubber in Iran: a good candidate for commercial use. Iran. Polym. J., 2023, 32(10), 1257-1269.

David, A. R. C.; Upul, H.; Katrina, C.; Colleen, M.; Frederick C, M.Alkaline pretreatment of Taraxacum kok-saghyz (TK) roots for the extraction of natural rubber (NR). Biochem. Eng. J., 2022, 181, 108376.

谢全亮, 李鸿彬, 王旭初. 橡胶草90年来主要研究成果及最新研究进展. 植物科学学报, 2019, 37(3), 404-412.

Salehi, M.; Cornish, K.; Bahmankar, M.; Naghavi, M. R.Natural rubber-producing sources, systems, and perspectives for breeding and biotechnology studies of Taraxacum kok-saghyz. Ind. Crops Prod., 2021, 170, 113667.

Sikandar, S.; Ujor, V. C.; Ezeji, T. C.; Rossington, J. L.; Michel, F. C.; McMahan, C. M.; Ali, N.; Cornish, K.Thermomyces lanuginosus STm: a source of thermostable hydrolytic enzymes for novel application in extraction of high-quality natural rubber from Taraxacum kok-saghyz (rubber dandelion). Ind. Crops Prod., 2017, 103, 161-168.

卓杨鹏, 廖小雪, 廖禄生, 张学超, 廖双泉, 张福全, 张晨, 赵艳芳. 蒲公英橡胶的提取及其结构性能初探. 热带作物学报, 2021, 42(12), 3617-3624.

Ramirez-Cadavid, D. A.; Valles-Ramirez, S.; Cornish, K.; Michel, F. C.Simultaneous quantification of rubber, inulin, and resins in Taraxacum kok-saghyz (TK) roots by sequential solvent extraction. Ind. Crops Prod., 2018, 122, 647-656.

向同. 天然橡胶和蒲公英橡胶中单体含量检测及分子量关系研究. 北京: 北京化工大学, 2019.

Cornish, K.; McMahan, C. M.; Williams, S. C.; Kostyal, D. A.; Willoughby, B. N.; Marsh, R. S.Characterization of the molecular structure and composition of Taraxacum kok-saghyz rubber. Ind. Crops. Prod., 2013, 45, 192-200.

Cornish, K.Impact of extraction methods on the quality and yield of Taraxacum koksaghyz rubber. Ind. Crops Prod., 2017, 109, 515-521.

Kongcharoen, R.; Tan, S.; Wang, Q.Superior electro-strictive strain achieved under low electric fields in relaxor ferroelectric polymers. J. Mater. Chem. A, 2019, 7, 5201-5208.

van Beilen, J. B.; Poirier, Y.Establishment of new crops for the production of natural rubber. Trends Biotech-nol., 2007, 25(11), 522-529.

刘根实. 蒲公英橡胶绿色提取技术及结构与性能研究. 北京: 北京化工大学, 2018.

马喆. 蒲公英橡胶发酵工艺研究. 北京: 北京化工大学, 2020.

颉翔. 蒲公英橡胶工程化工艺设计与优化. 北京: 北京化工大学, 2021.

Zwart, H.; Krabbenborg, L.; Zwier, J.Is dandelion rubber more natural? Naturalness, biotechnology and the transition towards a bio-based society. J. Agric. Environ. Ethics, 2015, 28(2), 313-334.

Ikeda, Y.; Junkong, P.; Ohashi, T.; Phakkeeree, T.; Sakaki, Y.; Tohsan, A.; Kohjiya, S.; Cornish, K.Strain-induced crystallization behaviour of natural rubbers from guayule and rubber dandelion revealed by simultaneous time-resolved WAXD/tensile measurements: indis-pensable function for sustainable resources. RSC Adv., 2016, 6(98), 95601-95610.

严青青, 邢涛, 王莉, 张龑, 高强, 徐麟, 王永刚. 不同Ca2+浓度对蒲公英和橡胶草种子萌发及根系生长的影响. 新疆农业科学, 2022, 59(5), 1128-1134.

罗登林, 刘娟, 曹偲霆, 徐宝成, 任广跃, 李鹏燕. 无机盐对短链菊粉凝胶性能影响的研究. 食品安全质量检测学报, 2014, 5(7), 2021-2026.

Zhang, N.; Guo, T. Y.; Ma, X.; Liu, J. H.; Dong, Y. Y.; Zhang, J. C.Rational rubber extraction and simultaneous determination of rubber content and molecular weight distribution in Taraxacum kok-saghyz rodin by size-exclusion chromatography. Chromatographia, 2019, 82(10), 1459-1466.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Structure and Physicochemical Properties of Waxy Maize Starch by Jet Mill

Structure and Physicochemical Properties of Pea Starch by Ball-millling Treatment

Application of Gaussian Software in Teaching of Polymer Chemistry

The Relationship between Polymer Structure and Properties-key Points to the Structure

Structure and Properties of Modified Diatomite/Rubber Composites

Related Author

Li-dong WANG

Fang KOU

Ting-ting LIU

Lin GUO

Hai-lin CONG

Kun-yan SUI

Yan-xin WANG

Yi-fan WANG

Related Institution

National Coarse Cereals Engineering Research Center, Heilongjiang Bayi Agricultural University

Food Science College, Northeast Agricultural University

College of Materials Science and Engineering, Qingdao University

College of Material Science and Technology, Zhejiang University of Technology

College of Materials Science and Engineering, Qiqihar University

⁰

Study on the Composition and Structure of Taraxacum koksaghyz Rubber from Different Origins

DOI：10.14028/j.cnki.1003-3726.2024.24.202

摘要

Abstract

关键词

Keywords

references