Research Progresses of Polyimide in Battery Separators and Solid-State Electrolytes

CHEN Jia-wei; WANG Han; LI Yu-hu; SUN Gui-qi; JIANG Shan; SONG Xin; ZHANG Jian-min

doi:10.14028/j.cnki.1003-3726.2024.24.247

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Research Progresses of Polyimide in Battery Separators and Solid-State Electrolytes

Special Topic: Polymer Functional Membrances | 更新时间：2025-03-28

- Research Progresses of Polyimide in Battery Separators and Solid-State Electrolytes
- Polymer Bulletin Vol. 38, Issue 4, Pages: 546-559(2025)
- 作者机构：
  
  1.青岛大学机电工程学院，青岛 266071
  2.青岛大学动力集成及储能系统工程技术中心，青岛 266071
  3.电动汽车智能化动力，集成技术国家地方联合工程研究中心(青岛)，青岛 266071
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.247
  CLC：
- Received：29 August 2024，
  
  Accepted：2024-10-11，
  
  Published Online：22 November 2024，
  
  Published：20 April 2025
- 稿件说明：
移动端阅览
陈嘉伟, 王焓, 李玉湖, 孙贵琦, 江杉, 宋鑫, 张健敏. 聚酰亚胺在电池隔膜与固态电解质膜中的研究进展. 高分子通报, 2025, 38(4), 546–559.

Chen, J. W.; Wang, H.; Li, Y. H.; Sun, G. Q.; Jiang, S.; Song, X.; Zhang, J. M. Research progresses of polyimide in battery separators and solid-state electrolytes. Polym. Bull. (in Chinese), 2025, 38(4), 546–559.
陈嘉伟, 王焓, 李玉湖, 孙贵琦, 江杉, 宋鑫, 张健敏. 聚酰亚胺在电池隔膜与固态电解质膜中的研究进展. 高分子通报, 2025, 38(4), 546–559. DOI： 10.14028/j.cnki.1003-3726.2024.24.247.

Chen, J. W.; Wang, H.; Li, Y. H.; Sun, G. Q.; Jiang, S.; Song, X.; Zhang, J. M. Research progresses of polyimide in battery separators and solid-state electrolytes. Polym. Bull. (in Chinese), 2025, 38(4), 546–559. DOI： 10.14028/j.cnki.1003-3726.2024.24.247.

摘要

近年来，新能源汽车行业的迅猛发展推动了高能量密度二次电池需求的持续增长。然而，电池使用不当(如过充过放、机械滥用和高温热冲击等)引发的电池短路、燃烧和爆炸等安全事故频发，成为制约其进一步发展的关键问题。当前，电池隔膜和电解液材料的选择局限性是导致安全事故的主要原因。聚酰亚胺(polyimide

PI)凭借其优异的机械性能、耐热性和电化学稳定性，已成为电池隔膜和固态电解质膜领域的研究热点。本文首先综述了传统PI隔膜的制备方法、探讨了基于传统PI隔膜的改性技术，概述了PI在固态电解质膜中的应用，而后深入分析了其在耐热性、电化学稳定性、离子传导和兼容性等方面的独特优势，最后对PI在电池隔膜与固态电解质膜中的应用进行了总结与展望。

Abstract

In recent years

the rapid development of electric vehicle industry has driven a continuously-growing demand for high energy-density secondary batteries. However

safety incidents such as battery short-circuits

fires

and explosions caused by improper usage (

e.g.

over-charging

over-discharging

mechanical abuse

and high-temperature thermal shocks) have become critical issues hindering further development. Currently

the limitations in the selection of battery separators and electrolytes are major causes of safety incidents. Polyimides (PI)

with their excellent mechanical properties

thermal resistance

and electrochemical stability

have become a research hotspot in the fields of battery separators and solid-state electrolytes. This paper first reviews the preparation methods of traditional PI separators

explores modification technologies based on traditional PI separators

and outlines the applications of PI in solid-state electrolytes. Then we delve into the unique advantages of PI in terms of thermal resistance

electrochemical stability

ionic conductivity

and compatibility. Finally

we summarize and provide an outlook on the application of PI in battery separators and solid-state electrolytes.

关键词

Keywords

references

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