Electrorheological Effect of Poly(ionic liquid)s

MA Rui-jing; PANG Hao-ming; YIN Jian-bo

doi:10.14028/j.cnki.1003-3726.2024.24.251

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Electrorheological Effect of Poly(ionic liquid)s

更新时间：2025-01-23

- Electrorheological Effect of Poly(ionic liquid)s
- Polymer Bulletin Vol. 38, Issue 2, Pages: 205-225(2025)
- 作者机构：
  
  1.西北工业大学物理科学与技术学院智能材料实验室，西安 710129
  2.运城学院山西省智能光电传感应用技术创新中心，运城 044000
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.251
  CLC：
- Received：30 August 2024，
  
  Accepted：07 October 2024，
  
  Published Online：18 November 2024，
  
  Published：20 February 2025
- 稿件说明：
移动端阅览
马瑞婧, 逄浩明, 尹剑波. 聚离子液的电流变效应. 高分子通报, 2025, 38(2), 206–226.

Ma, R. J.; Pang， H. M.; Yin, J. B. Electrorheological effect of poly(ionic liquid)s. Polym. Bull. (in Chinese), 2025, 38(2), 206–226.
马瑞婧, 逄浩明, 尹剑波. 聚离子液的电流变效应. 高分子通报, 2025, 38(2), 206–226. DOI： 10.14028/j.cnki.1003-3726.2024.24.251.

Ma, R. J.; Pang， H. M.; Yin, J. B. Electrorheological effect of poly(ionic liquid)s. Polym. Bull. (in Chinese), 2025, 38(2), 206–226. DOI： 10.14028/j.cnki.1003-3726.2024.24.251.

摘要

聚离子液是一种由离子液聚合而成的新型聚电解质，不同于传统聚电解质，它含有憎水的大尺寸氟化反离子，因而具有天然的疏水性和非水环境下反离子迁移特性。该特性使聚离子液有成为新一代非水聚电解质电流变材料的潜力，从而克服传统聚电解质电流变材料需吸附水来激活离子迁移和电流变效应而带来的漏导电流大、热不稳定和介电击穿等问题。本文系统介绍了近十年关于聚离子液的电流变效应的研究进展，包括线性聚离子液、交联聚离子液、复合聚离子液和离子共价有机框架材料的电流变效应，特别是详细介绍了聚离子液的电流变效应与结构关系，以期为未来研发高性能聚离子液电流变材料提供参考。

Abstract

Poly(ionic liquid)s (PILs) are new types of polyelectrolytes

which are synthesized by ionic liquid monomer polymerization. Different from traditional polyelectrolytes

PILs contain large-size fluorinated counterions and thus they possess a natural hydrophobicity and a counterion migration characteristic in non-aqueous state. These characteristics endow PILs with potential as the next generation non-aqueous polyelectrolyte-based electrorheological (ER) materials

which can overcome the problems of traditional polyelectrolyte-based ER materials

including high leakage current

thermal instability

and dielectric breakdown caused by adsorbed water. To highlight PILs as potential next generation ER materials

we review the research progress of ER effect of PILs in the past decade including the ER effect of linear PILs

cross-linked PILs

composite PILs

and ion-covalent organic framework materials. In particular

the review gives a discussion about the relationship between the ER effect of PILs and their structure in order to provide a guide for the design and preparation of high-performance PILs-based ER materials in the future.

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references

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