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1.西北民族大学化工学院,兰州 730030
2.西北民族大学实验教学部,兰州 730030
Received:28 October 2024,
Accepted:2024-11-26,
Published Online:07 January 2025,
Published:20 March 2025
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黎金凤, 孙万虹. 聚吡咯/铁基复合材料的制备及其应用. 高分子通报, 2025, 38(3), 417–429.
Li, J. F.; Sun, W. H. Preparation and application of polypyrrole/iron-based composites. Polym. Bull. (in Chinese), 2025, 38(3), 417–429.
黎金凤, 孙万虹. 聚吡咯/铁基复合材料的制备及其应用. 高分子通报, 2025, 38(3), 417–429. DOI: 10.14028/j.cnki.1003-3726.2025.24.327.
Li, J. F.; Sun, W. H. Preparation and application of polypyrrole/iron-based composites. Polym. Bull. (in Chinese), 2025, 38(3), 417–429. DOI: 10.14028/j.cnki.1003-3726.2025.24.327.
聚吡咯(PPy)是一种价格低廉、具有高效储存能力的导电聚合物,但由于溶解程度较小,其生产和应用受限。因此,为了拓展其应用范围,多功能PPy复合材料的设计与研究备受关注。PPy/铁基复合材料制备方法有水热法、聚合法、一锅法等。PPy/铁基复合材料应用研究主要集中在电容器、吸波材料、吸附剂、传感器、医药及催化剂等领域,特别在超级电容器的电极材质、电磁波的吸收、重金属离子的吸附以及催化降解等方面表现出优异的性能,具有广阔的应用前景。随着制备技术的不断发展和应用领域的进一步拓展,PPy/铁基复合材料有望在更多领域发挥重要作用。
Polypyrrole (PPy) is an inexpensive conductive polymer with efficient storage capacity
but its limited solubility restricts its production and application. Therefore
to expand its application scope
the design and research of multifunctional PPy composites have garnered significant attention. PPy/iron-based composites are prepared
via
methods such as the hydrothermal method
polymerization method
and one-pot method. The research on the application of PPy/iron composites primarily focuses on fields such
as capacitors
electromagnetic wave absorbing materials
adsorbents
sensors
pharmaceuticals
and catalysts. In particular
they exhibit excellent performance in the electrode materials of supercapacitors
the absorption of electromagnetic waves
the adsorption of heavy metal ions
and catalytic degradation
showcasing broad application prospects. With the continuous development of preparation technology and further expansion of application fields
PPy/iron-based composites are expected to play a significant role in more areas.
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Ma, M. L. ; Bi, Y. X. ; Jiao, Z. G. ; Yue, J. W. ; Liao, Z. J. ; Wang, Y. ; Ma, Y. ; Huang, W. B . Facile fabrication of metal-organic framework derived Fe/Fe 3 O 4 /FeN/N-doped carbon composites coated with PPy for superior microwave absorption . J. Colloid Interface Sci. , 2022 , 608 , 525 – 535 .
Dai, B. ; Dong, F. ; Wang, H. Y. ; Qu, Y. M. ; Ding, J. X. ; Ma, Y. ; Ma, M. L. ; Li, T. X . Fabrication of CuS/Fe 3 O 4 @polypyrrole flower-like composites for excellent electromagnetic wave absorption . J. Colloid Interface Sci. , 2023 , 634 , 481 – 494 .
Mandal, P. ; Bala, S. ; Poddar, S. ; Sarkar, S. ; Shankar Biswas, H . Fabrication of graphene-Fe 3 O 4 -poly-pyrrole based ternary material as an electrode for pseudocapacitor application . Mater. Today Proc. , 2022 , 65 , 1001 – 1010 .
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Mukherjee, P. ; R S, V. ; Borenstein, A. ; Zidki, T . Compositing redox-rich Co-Co@Ni-Fe PBA nanocubes into cauliflower-like conducting polypyrrole as an electrode material in supercapacitors . Mater. Chem. Front. , 2023 , 7 ( 6 ), 1110 – 1119 .
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DİNÇER, C. ; Getİren, B. ; Gökalp, C. ; Çiplak, Z. ; Karakeçİlİ, A. ; Yildiz, N . An anticancer drug loading and release study to ternary GO-Fe 3 O 4 -PPy and Fe 3 O 4 @PPy-NGQDs nanocomposites for photothermal chemotherapy . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 633 , 127791 .
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