Reaction Mechanism and Viscoelasticity of Succinic Acid Based Epoxy Vitrimer

WANG Zong-tao; ZHANG Jin-mei; QIU Yu-hao; CUI Zhi-bo; CHEN Si-qi; HE Qing-cheng; ZHAO Ya-qi; TAN Yan-fang; FENG Qiao

doi:10.14028/j.cnki.1003-3726.2025.24.328

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Reaction Mechanism and Viscoelasticity of Succinic Acid Based Epoxy Vitrimer

更新时间：2025-02-27

- Reaction Mechanism and Viscoelasticity of Succinic Acid Based Epoxy Vitrimer
- Polymer Bulletin Vol. 38, Issue 3, Pages: 480-486(2025)
- 作者机构：
  
  河南城建学院材料与化工学院，平顶山 467000
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2025.24.328
  CLC：
- Received：29 October 2024，
  
  Accepted：2024-12-10，
  
  Published Online：27 January 2025，
  
  Published：20 March 2025
- 稿件说明：
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王宗涛, 张金妹, 邱玉浩, 崔智博, 陈思琪, 何庆诚, 赵亚奇, 谭延方, 冯巧. 丁二酸基环氧树脂类玻璃反应机制与黏弹性. 高分子通报, 2025, 38(3), 480–486.

Wang, Z. T.; Zhang, J. M.; Qiu, Y. H.; Cui, Z. B.; Chen, S. Q.; He, Q. C.; Zhao, Y. Q.; Tan, Y. F.; Feng, Q. Reaction mechanism and viscoelasticity of succinic acid based epoxy vitrimer. Polym. Bull. (in Chinese), 2025, 38(3), 480–486.
王宗涛, 张金妹, 邱玉浩, 崔智博, 陈思琪, 何庆诚, 赵亚奇, 谭延方, 冯巧. 丁二酸基环氧树脂类玻璃反应机制与黏弹性. 高分子通报, 2025, 38(3), 480–486. DOI： 10.14028/j.cnki.1003-3726.2025.24.328.

Wang, Z. T.; Zhang, J. M.; Qiu, Y. H.; Cui, Z. B.; Chen, S. Q.; He, Q. C.; Zhao, Y. Q.; Tan, Y. F.; Feng, Q. Reaction mechanism and viscoelasticity of succinic acid based epoxy vitrimer. Polym. Bull. (in Chinese), 2025, 38(3), 480–486. DOI： 10.14028/j.cnki.1003-3726.2025.24.328.

摘要

丁二酸是一种可通过生物发酵得到的可再生化学品，可用于合成生物基环氧类玻璃高分子(vitrimer)，所得的高分子材料兼具绿色可再生、高性能、可重复加工等优点。本工作基于丁二酸合成了一种生物基环氧vitrimer材料，并使用红外光谱和旋转流变仪，从分子结构变化和流变学角度，研究了羧基与环氧基团反应特点，以及单体向聚合物转变过程中出现的凝胶化现象和热固化历程，并对材料的热稳定性、黏弹性、机械性能等进行研究，为新型环氧vitrimer材料的开发和研究提供理论依据。

Abstract

Succinic acid is a renewable chemical obtained through biological fermentation and can serve as a bio-material for epoxy resin preparation. The obtained epoxy vitrimer combines the properties of renewable

high-performance

and reprocessable together. In this study

we synthesized a bio-based epoxy vitrimer using succinic acid and utilized infrared spectroscopy and a rotary rheometer to investigate the gelation and curing process during the polymerization procedure from monomer to polymer

monitoring molecular structure translation and viscoelastic change. Furthermore

we studied the thermal stability

viscoelasticity

and mechanical properties of the vitrimers to provide a theoretical basis for the development and research of new epoxy resin vitrimer materials.

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references

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