姜明明 , 金之钧 . 专利视角下中国储能技术研究现状分析 . 中国科学院院刊 , 2024 , 39 ( 8 ), 1468 – 1485 .

田孟羽 . 基于高比容量合金负极的锂离子电池相关科学问题研究 . 博士学位论文 , 北京 : 中国科学院大学(中国科学院物理研究所) , 2023 .

邹才能 , 李士祥 , 刘辰光 , 王俪颖 . 新质生产力赋能新型储能技术及其商业模式 . 石油学报 , 2024 , 45 ( 10 ), 1443 – 1461 .

Kita, K. ; Narisawa, M. ; Mabuchi, H. ; Itoh, M. ; Sugimoto, M. ; Yoshikawa, M . Formation of continuous pore structures in Si―C―O fibers by adjusting the melt spinning condition of a polycarbosilane-polysiloxane polymer blend . J. Am. Ceram. Soc. , 2009 , 92 ( 6 ), 1192 – 1197 .

Wen, T. H. ; Wen, Q. B. ; Lu, L. ; Wang, Y. L. ; Jiang, T. X. ; Hu, J. R. ; Zeng, Y. ; Xiong, X . Effects of polymer-derived ZiC interlayer on mechanical properties and ablation performance of C/C-ZiC-ZrC-SiC composites prepared by RMI . J. Eur. Ceram. Soc. , 2024 , 44 ( 10 ), 5623 – 5638 .

Eckel, Z. C. ; Zhou, C. Y. ; Martin, J. H. ; Jacobsen, A. J. ; Carter, W. B. ; Schaedler, T. A . Additive manufacturing of polymer-derived ceramics . Science , 2016 , 351 ( 6268 ), 58 – 62 .

Wang, X. F. ; Schmidt, F. ; Hanaor, D. ; Kamm, P. H. ; Li, S. ; Gurlo, A . Additive manufacturing of ceramics from preceramic polymers: A versatile stereolithographic approach assisted by thiol-ene click chemistry . Addit. Manuf. , 2019 , 27 , 80 – 90 .

Wen, Q. B. ; Yu, Z. J. ; Riedel, R . The fate and role of in situ formed carbon in polymer-derived ceramics . Prog. Mater. Sci. , 2020 , 109 , 100623 .

Sujith, R. ; Jothi, S. ; Zimmermann, A. ; Aldinger, F. ; Kumar, R . Mechanical behaviour of polymer derived ceramics–a review . Int. Mater. Rev. , 2021 , 66 ( 6 ), 426 – 449 .

Wen, Q. B. ; Qu, F. M. ; Yu, Z. J. ; Graczyk-Zajac, M. ; Xiong, X. ; Riedel, R . Si-based polymer-derived ceramics for energy conversion and storage . J. Adv. Ceram. , 2022 , 11 ( 2 ), 197 – 246 .

Colombo, P. ; Mera, G. ; Riedel, R. ; Sorarù, G. D . Polymer-derived ceramics: 40 years of research and innovation in advanced ceramics . J. Am. Ceram. Soc. , 2010 , 93 ( 7 ), 1805 – 1837 .

Packirisamy, S. ; Sreejith, K. J. ; Devapal, D. ; Swaminathan, B . Polymer-derived ceramics and their space applications . Handbook of Advanced Ceramics and Composites . Cham : Springer International Publishing , 2020 . 975 – 1080 .

Ainger, F. , Herbert, J . The preparation of phosphorus-nitrogen compounds as non-porous solids . Angew Chem. Int. Ed , 1959 , 71 ( 20 ), 653 – 653 .

江天兴 , 周天赐 , 文青波 , 余兆菊 , 熊翔 . 聚合物转化超高温陶瓷及其复合材料研究进展 . 硅酸盐学报 , 2024 , 52 ( 9 ), 2827 – 2846 .

Fritz, G. ; Raabe, B . Bildung siliciumorganischer verbindungen. V. die thermische zersetzung von Si(CH 3 ) 4 und Si(C 2 H 5 ) 4 . Z. Für Anorg. Und Allg. Chem. , 1956 , 286 ( 3-4 ), 149 – 167 .

Verbeek, W . Production of shaped articles of homogeneous mixtures of silicon carbide and nitride . USA patent, US3853567 . 1974-12-10 .

Verbeek, W. , Winter, G . Formkoerper aus siliciumcarbid und verfahren zu ihrer herstellung . DE patent, 2236078: A1 . 1974 .

Winter, G. ; Verbeek, W. ; Mansmann, M . Production of shaped articles of silicon carbide and silicon nitride . USA patent, US3892583 . 1975-07-01 .

Yajima, S. ; Hayashi, J. ; Omori, M. ; Okamura, K . Development of a silicon carbide fibre with high tensile strength . Nature , 1976 , 261 ( 5562 ), 683 – 685 .

Yajima, S. ; Okamura, K. ; Hayashi, J. ; Omori, M . Synthesis of continuous SiC fibers with high tensile strength . J. Am. Ceram. Soc. , 1976 , 59 ( 7-8 ), 324 – 327 .

Yajima, S. ; Omori, M. ; Hayashi, J. ; Okamura, K. ; Matsuzawa, T. ; Liaw, C. F . Simple synthesis of the continuous SiC fiber with high tensile strength . Chem. Lett. , 1976 , 5 ( 6 ), 551 – 554 .

Bill, J. ; Aldinger, F . Precursor-derived covalent ceramics . Adv. Mater. , 1995 , 7 ( 9 ), 775 – 787 .

Ionescu, E . Polymer-derived ceramics . Ceram Sci Technol , 2013 : 457 – 500 .

Su, D. ; Li, Y. L. ; An, H. J. ; Liu, X. ; Hou, F. ; Li, J. Y. ; Fu, X . Pyrolytic transformation of liquid precursors to shaped bulk ceramics . J. Eur. Ceram. Soc. , 2010 , 30 ( 6 ), 1503 – 1511 .

Choong Kwet Yive, N. S. ; Corriu, R. J. P. ; Leclercq, D. ; Mutin, P. H. ; Vioux, A . Silicon carbonitride from polymeric precursors: Thermal cross-linking and pyrolysis of oligosilazane model compounds . Chem. Mater. , 1992 , 4 ( 1 ), 141 – 146 .

Kaur, S. ; Cherkashinin, G. ; Fasel, C. ; Kleebe, H. J. ; Ionescu, E. ; Riedel, R . Single-source-precursor synthesis of novel V 8 C 7 /SiC(O)-based ceramic nanocomposites . J. Eur. Ceram. Soc. , 2016 , 36 ( 15 ), 3553 – 3563 .

Kaur, S. ; Riedel, R. ; Ionescu, E . Pressureless fabrication of dense monolithic SiC ceramics from a polycarbosilane . J. Eur. Ceram. Soc. , 2014 , 34 ( 15 ), 3571 – 3578 .

Qazzazie-Hauser, A. ; Honnef, K. ; Hanemann, T . Crosslinking behavior of UV-cured polyorganosilazane as polymer-derived ceramic precursor in ambient and nitrogen atmosphere . Polymers , 2021 , 13 ( 15 ), 2424 .

Su, Z. M. ; Zhang, L. T. ; Li, Y. C. ; Li, S. W. ; Chen, L. F . Rapid preparation of SiC fibers using a curing route of electron irradiation in a low oxygen concentration atmosphere . J. Am. Ceram. Soc. , 2015 , 98 ( 7 ), 2014 – 2017 .

Friedel, T. ; Travitzky, N. ; Niebling, F. ; Scheffler, M. ; Greil, P . Fabrication of polymer derived ceramic parts by selective laser curing . J. Eur. Ceram. Soc. , 2005 , 25 ( 2-3 ), 193 – 197 .

Bahloul, D. ; Pereira, M. ; Goursat, P. ; Choong Kwet Yive, N. S. ; Corriu, R. J. P . Preparation of silicon carbonitrides from an organosilicon polymer: I, thermal decomposition of the cross-linked polysilazane . J. Am. Ceram. Soc. , 1993 , 76 ( 5 ), 1156 – 1162 .

Lee, S. H. ; Weinmann, M. ; Aldinger, F . Particulate-reinforced precursor-derived Si―C―N ceramics: Optimization of pyrolysis atmosphere and schedules . J. Am. Ceram. Soc. , 2005 , 88 ( 11 ), 3024 – 3031 .

Li, K. Z. ; Yuan, G. Q. ; Liu, X. F. ; Guo, Y. ; Huang, R. ; Li, H. ; Zhang, H. J. ; Jia, Q. L. ; Xie, Z. W. ; Zhang, S. W. ; Lei, W . On the practical applicability of rambutan-like SiOC anode with enhanced reaction kinetics for lithium-ion storage . Adv. Funct. Mater. , 2023 , 33 ( 43 ), 2302348 .

Saha, A. ; Raj, R. ; Williamson, D. L . A model for the nanodomains in polymer-derived SiCO . J. Am. Ceram. Soc. , 2006 , 89 ( 7 ), 2188 – 2195 .

Sun, H. ; Zhao, K. J . Atomistic origins of high capacity and high structural stability of polymer-derived SiOC anode materials . ACS Appl. Mater. Interfaces , 2017 , 9 ( 40 ), 35001 – 35009 .

曹东学 . 锂离子电池负极材料技术现状和发展趋势 . 炼油技术与工程 , 2024 , 54 ( 9 ), 1 – 7 .

吴泽 . 高容量锂离子电池硅氧碳基负极材料的制备及性能研究 . 博士学位论文 , 哈尔滨 : 哈尔滨工业大学 , 2019 .

Rohrer, J. ; Vrankovic, D. ; Cupid, D. ; Riedel, R. ; Seifert, H. J. ; Albe, K. ; Graczyk-Zajac, M . Si- and Sn-containing SiOCN-based nanocomposites as anode materials for lithium ion batteries: synthesis, thermodynamic characterization and modeling . Int. J. Mater. Res. , 2017 , 108 ( 11 ), 920 – 932 .

Wilson, A. M. ; Reimers, J. N. ; Fuller, E. W. ; Dahn, J. R . Lithium insertion in pyrolyzed siloxane polymers . Solid State Ion. , 1994 , 74 ( 3-4 ), 249 – 254 .

Xing, W. B. ; Wilson, A. M. ; Eguchi, K. ; Zank, G. ; Dahn, J. R . Pyrolyzed polysiloxanes for use as anode materials in lithium-ion batteries . J. Electrochem. Soc. , 1997 , 144 ( 7 ), 2410 – 2416 .

Sujith, R. ; Gangadhar, J. ; Greenough, M. ; Bordia, R. K. ; Panda, D. K . A review of silicon oxycarbide ceramics as next generation anode materials for lithium-ion batteries and other electrochemical applications . J. Mater. Chem. A , 2023 , 11 ( 38 ), 20324 – 20348 .

Sanchez-Jimenez, P. E. ; Raj, R . Lithium insertion in polymer-derived silicon oxycarbide ceramics . J. Am. Ceram. Soc. , 2010 , 93 ( 4 ), 1127 – 1135 .

Liu, X. ; Zheng, M. C. ; Xie, K . Mechanism of lithium storage in Si―O―C composite anodes . J. Power Sources , 2011 , 196 ( 24 ), 10667 – 10672 .

Radovanovic, E. ; Gozzi, M. F. ; Gonçalves, M. C. ; Yoshida, I. V. P . Silicon oxycarbide glasses from silicone networks . J. Non Cryst. Solids , 1999 , 248 ( 1 ), 37 – 48 .

Graczyk-Zajac, M. ; Vrankovic, D. ; Waleska, P. ; Hess, C. ; Sasikumar, P. V. ; Lauterbach, S. ; Kleebe, H. J. ; Sorarù, G. D . The Li-storage capacity of SiOC glasses with and without mixed silicon oxycarbide bonds . J. Mater. Chem. A , 2018 , 6 ( 1 ), 93 – 103 .

Fukui, H. ; Ohsuka, H. ; Hino, T. ; Kanamura, K . A Si―O―C composite anode: high capability and proposed mechanism of lithium storage associated with microstructural characteristics . ACS Appl. Mater. Interfaces , 2010 , 2 ( 4 ), 998 – 1008 .

Lim, H. ; Kim, H. ; Kim, S. O. ; Kim, K. J. ; Choi, W . Novel approach for controlling free-carbon domain in silicone oil-derived silicon oxycarbide (SiOC) as an anode material in secondary batteries . Chem. Eng. J. , 2021 , 404 , 126581 .

Wilamowska, M. ; Pradeep, V. S. ; Graczyk-Zajac, M. ; Riedel, R. ; Sorarù, G. D . Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries . Solid State Ion. , 2014 , 260 , 94 – 100 .

Fukui, H. ; Ohsuka, H. ; Hino, T. ; Kanamura, K . Influence of polystyrene/phenyl substituents in precursors on microstructures of Si–O–C composite anodes for lithium-ion batteries . J. Power Sources , 2011 , 196 ( 1 ), 371 – 378 .

Li, K. Z. ; Yuan, G. Q. ; Liu, X. F. ; Xie, Q. ; Dong, L. ; Li, Z. Y. ; Zhang, H. J. ; Xie, Z. W. ; Zhang, S. W. ; Lei, W . Deciphering fast lithium storage kinetics via R-based self-derivation effects in siloxanes . Energy Storage Mater. , 2024 , 65 , 103194 .

Kroll, P . Tracing reversible and irreversible Li insertion in SiCO ceramics with modeling and ab-initio simulations . MRS Online Proc. Libr. , 2011 , 1313 ( 1 ), 7 .

Halim, M. ; Hudaya, C. ; Kim, A. Y. ; Lee, J. K . Phenyl-rich silicone oil as a precursor for SiOC anode materials for long-cycle and high-rate lithium ion batteries . J. Mater. Chem. A , 2016 , 4 ( 7 ), 2651 – 2656 .

Lu, K . Porous and high surface area silicon oxycarbide-based materials: a review . Mater. Sci. Eng. R Rep. , 2015 , 97 , 23 – 49 .

Dibandjo, P. ; Graczyk-Zajac, M. ; Riedel, R. ; Pradeep, V. S. ; Soraru, G. D . Lithium insertion into dense and porous carbon-rich polymer-derived SiOC ceramics . J. Eur. Ceram. Soc. , 2012 , 32 ( 10 ), 2495 – 2503 .

Fukui, H. ; Harimoto, Y. ; Akasaka, M. ; Eguchi, K . Lithium species in electrochemically lithiated and delithiated silicon oxycarbides . ACS Appl. Mater. Interfaces , 2014 , 6 ( 15 ), 12827 – 12836 .

Ma, M. B. ; Wang, H. J. ; Niu, M. ; Su, L. ; Fan, X. Y. ; Deng, J. C. ; Zhang, Y. ; Du, X. F . High rate capabilities of HF-etched SiOC anode materials derived from polymer for lithium-ion batteries . RSC Adv. , 2016 , 6 ( 49 ), 43316 – 43321 .

Shi, H. M. ; Yuan, A. B. ; Xu, J. Q . Tailored synthesis of monodispersed nano/submicron porous silicon oxycarbide (SiOC) spheres with improved Li-storage performance as an anode material for Li-ion batteries . J. Power Sources , 2017 , 364 , 288 – 298 .

Xia, K. D. ; Wu, Z. X. ; Xuan, C. J. ; Xiao, W. P. ; Wang, J. ; Wang, D. L . Effect of KOH etching on the structure and electrochemical performance of SiOC anodes for lithium-ion batteries . Electrochim. Acta , 2017 , 245 , 287 – 295 .

Dong, B. B. ; Han, Y. H. ; Wang, T. ; Lei, Z. W. ; Chen, Y. W. ; Wang, F. H. ; Abadikhah, H. ; Khan, S. A. ; Hao, L. Y. ; Xu, X. ; Cao, R. G. ; Yin, L. J. ; Agathopoulos, S . Hard SiOC microbeads as a high-performance lithium-ion battery anode . ACS Appl. Energy Mater. , 2020 , 3 ( 10 ), 10183 – 10191 .

Fukui, H. ; Eguchi, K. ; Ohsuka, H. ; Hino, T. ; Kanamura, K . Structures and lithium storage performance of Si–O–C composite materials depending on pyrolysis temperatures . J. Power Sources , 2013 , 243 , 152 – 158 .

Kaspar, J. ; Graczyk-Zajac, M. ; Riedel, R . Carbon-rich SiOC anodes for lithium-ion batteries: Part II. Role of thermal cross-linking . Solid State Ion. , 2012 , 225 , 527 – 531 .

Kaspar, J. ; Graczyk-Zajac, M. ; Riedel, R . Lithium insertion into carbon-rich SiOC ceramics: Influence of pyrolysis temperature on electrochemical properties . J. Power Sources , 2013 , 244 , 450 – 455 .

Pradeep, V. S. ; Graczyk-Zajac, M. ; Riedel, R. ; Soraru, G. D . New insights in to the lithium storage mechanism in polymer derived SiOC anode materials . Electrochim. Acta , 2014 , 119 , 78 – 85 .

Ahn, D. ; Raj, R . Cyclic stability and C-rate performance of amorphous silicon and carbon based anodes for electrochemical storage of lithium . J. Power Sources , 2011 , 196 ( 4 ), 2179 – 2186 .

Kaspar, J. ; Graczyk-Zajac, M. ; Choudhury, S. ; Riedel, R . Impact of the electrical conductivity on the lithium capacity of polymer-derived silicon oxycarbide (SiOC) ceramics . Electrochim. Acta , 2016 , 216 , 196 – 202 .

Do, K. ; Park, C. ; Hwang, J. ; Kim, S. ; Jung, Y. ; Lee, S. H. ; Lim, H. D. ; Ahn, H . Covalent-assisted seeding of Si nanoparticles into a dual-matrix design toward advanced Si-based Li-ion batteries . J. Mater. Chem. A , 2024 , 12 ( 18 ), 11062 – 11074 .

Wang, J. ; Jin, S. W. ; He, Z. Q. ; Kong, D. B. ; Hu, H. ; Feng, X. ; Chen, D . Rational design of Cu 3 Si interphase for 3D micron-sized SiOC-based anode to enable long-term cycling of lithium-ion battery . Adv. Funct. Mater. , 2025 , 35 ( 3 ), 2413540 .

Shen, J. ; Ahn, D. ; Raj, R . C-rate performance of silicon oxycarbide anodes for Li+ batteries enhanced by carbon nanotubes . J. Power Sources , 2011 , 196 ( 5 ), 2875 – 2878 .

Ma, M. B. ; Wang, H. J. ; Xiong, L. L. ; Huang, S. ; Li, X. ; Du, X. F . Self-assembled homogeneous SiOC@C/graphene with three-dimensional lamellar structure enabling improved capacity and rate performances for lithium ion storage . Carbon , 2022 , 186 , 273 – 281 .

Sang, Z. Y. ; Yan, X. ; Wen, L. ; Su, D. ; Zhao, Z. H. ; Liu, Y. ; Ji, H. M. ; Liang, J. ; Dou, S. X . A graphene-modified flexible SiOC ceramic cloth for high-performance lithium storage . Energy Storage Mater. , 2020 , 25 , 876 – 884 .

David, L. ; Bhandavat, R. ; Barrera, U. ; Singh, G . Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries . Nat. Commun. , 2016 , 7 , 10998 .

Lin, X. J. ; Dong, Y. ; Liu, X. W. ; Chen, X. H. ; Li, A. ; Song, H. H . In-situ pre-lithiated onion-like SiOC/C anode materials based on metallasilsesquioxanes for Li-ion batteries . Chem. Eng. J. , 2022 , 428 , 132125 .

Dahn, J. R. ; Wilson, A. M. ; Xing, W. B. ; Zank, G. A . Electrodes for lithium ion batteries using polysilazanes ceramic with lithium . USA patent, US5631106 . 1997-05-20 .

Liebau-Kunzmann, V. ; Fasel, C. ; Kolb, R. ; Riedel, R . Lithium containing silazanes as precursors for SiCN: Li ceramics: a potential material for electrochemical applications . J. Eur. Ceram. Soc. , 2006 , 26 ( 16 ), 3897 – 3901 .

Kolb, R. ; Fasel, C. ; Liebau-Kunzmann, V. ; Riedel, R . SiCN/C-ceramic composite as anode material for lithium ion batteries . J. Eur. Ceram. Soc. , 2006 , 26 ( 16 ), 3903 – 3908 .

Graczyk-Zajac, M. ; Mera, G. ; Kaspar, J. ; Riedel, R . Electrochemical studies of carbon-rich polymer-derived SiCN ceramics as anode materials for lithium-ion batteries . J. Eur. Ceram. Soc. , 2010 , 30 ( 15 ), 3235 – 3243 .

Reinold, L. M. ; Graczyk-Zajac, M. ; Gao, Y. ; Mera, G. ; Riedel, R . Carbon-rich SiCN ceramics as high capacity/high stability anode material for lithium-ion batteries . J. Power Sources , 2013 , 236 , 224 – 229 .

Graczyk-Zajac, M. ; Wimmer, M. ; Xu, Y. P. ; Buntkowsky, G. ; Neumann, C. ; Riedel, R . Lithium intercalation into disordered carbon/SiCN composite. Part 2: Raman spectroscopy and 7 Li MAS NMR investigation of lithium storage sites . J. Solid State Electrochem. , 2017 , 21 ( 1 ), 47 – 55 .

Wilamowska, M. ; Graczyk-Zajac, M. ; Riedel, R . Composite materials based on polymer-derived SiCN ceramic and disordered hard carbons as anodes for lithium-ion batteries . J. Power Sources , 2013 , 244 , 80 – 86 .

Feng, Y. ; Dou, S. M. ; Wei, Y. Z. ; Zhang, Y. L. ; Song, X. Y. ; Li, X. F. ; Battaglia, V. S . Preparation and capacity-fading investigation of polymer-derived silicon carbonitride anode for lithium-ion battery . ACS Omega , 2017 , 2 ( 11 ), 8075 – 8085 .

Baek, S. H. ; Reinold, L. M. ; Graczyk-Zajac, M. ; Riedel, R. ; Hammerath, F. ; Büchner, B. ; Grafe, H. J . Lithium dynamics in carbon-rich polymer-derived SiCN ceramics probed by nuclear magnetic resonance . J. Power Sources , 2014 , 253 , 342 – 348 .

Su, D. ; Li, Y. L. ; Feng, Y. ; Jin, J . Electrochemical properties of polymer-derived SiCN materials as the anode in lithium ion batteries . J. Am. Ceram. Soc. , 2009 , 92 ( 12 ), 2962 – 2968 .

Kaspar, J. ; Mera, G. ; Nowak, A. P. ; Graczyk-Zajac, M. ; Riedel, R . Electrochemical study of lithium insertion into carbon-rich polymer-derived silicon carbonitride ceramics . Electrochim. Acta , 2010 , 56 ( 1 ), 174 – 182 .

Reinold, L. M. ; Yamada, Y. ; Graczyk-Zajac, M. ; Munakata, H. ; Kanamura, K. ; Riedel, R . The influence of the pyrolysis temperature on the electrochemical behavior of carbon-rich SiCN polymer-derived ceramics as anode materials in lithium-ion batteries . J. Power Sources , 2015 , 282 , 409 – 415 .

Reinold, L. M. ; Graczyk-Zajac, M. ; Fasel, C. ; Riedel, R . Prevention of solid electrolyte interphase damaging on silicon by using polymer derived SiCN ceramics . ECS Trans. , 2011 , 35 ( 34 ), 37 – 44 .

Feng, Y. ; Du, G. X. ; Zhao, X. J. ; Yang, E. C . Preparation and electrochemical performance of SiCN–CNTs composite anode material for lithium ion batteries . J. Appl. Electrochem. , 2011 , 41 ( 8 ), 999 – 1002 .

Zhang, J. W. ; Xu, C. H. ; Liu, Z. P. ; Wang, W. ; Xin, X. ; Shen, L. ; Zhou, X. B. ; Zhou, J. ; Huang, Q . Enhanced rate capability of polymer-derived SiCN anode material for electrochemical storage of lithium with 3-D carbon nanotube network dispersed in nanoscale . J. Nanosci. Nanotechnol. , 2015 , 15 ( 4 ), 3067 – 3075 .

Feng, Y. ; Feng, N. N. ; Wei, Y. Z. ; Bai, Y . Preparation and improved electrochemical performance of SiCN–graphene composite derived from poly (silylcarbondiimide) as Li-ion battery anode . J. Mater. Chem. A , 2014 , 2 ( 12 ), 4168 – 4177 .

Bhandavat, R. ; Singh, G . Improved electrochemical capacity of precursor-derived Si(B)CN-carbon nanotube composite as Li-ion battery anode . ACS Appl. Mater. Interfaces , 2012 , 4 ( 10 ), 5092 – 5097 .

Feng, N. N. ; Feng, Y. ; Wei, Y. Z. ; Zhou, X. P . Preparation and electrochemical performance of a porous polymer-derived silicon carbonitride anode by hydrofluoric acid etching for lithium ion batteries . RSC Adv. , 2014 , 4 ( 45 ), 23694 – 23702 .

Feng, Y. ; Wei, Y. Z. ; Jia, Z. ; Zhang, Y. L. ; Battaglia, V. ; Liu, G . Polymer-derived and sodium hydroxide-treated silicon carbonitride material as anodes for high electrochemical performance Li-ion batteries . ChemistrySelect , 2016 , 1 ( 2 ), 309 – 317 .

Idrees, M. ; Batool, S. ; Kong, J. ; Zhuang, Q. ; Liu, H. ; Shao, Q. ; Lu, N. ; Feng, Y. N. ; Wujcik, E. K. ; Gao, Q. ; Ding, T. ; Wei, R. B. ; Guo, Z. H . Polyborosilazane derived ceramics - Nitrogen sulfur dual doped graphene nanocomposite anode for enhanced lithium ion batteries . Electrochim. Acta , 2019 , 296 , 925 – 937 .

Wang, S. H. ; Hu, X. D. ; Dai, Y. J . Preparation and electrochemical performance of polymer-derived SiBCN-graphene composite as anode material for lithium ion batteries . Ceram. Int. , 2017 , 43 ( 1 ), 1210 – 1216 .

Chen, Q. Q. ; Li, D. X. ; Yang, Z. H. ; Jia, D. C. ; Zhou, Y. ; Riedel, R . BCl 3  modified tris(dichloromethylsilylethyl)borane as a precursor for SiBCN ceramics applied in lithium-ion battery anodes . Ceram. Int. , 2021 , 47 ( 16 ), 22839 – 22853 .

Han, M. S. ; Mu, Y. B. ; Yuan, F. ; Liang, J. B. ; Jiang, T. ; Bai, X. D. ; Yu, J . Vertical graphene growth on uniformly dispersed sub-nanoscale SiOx/N-doped carbon composite microspheres with a 3D conductive network and an ultra-low volume deformation for fast and stable lithium-ion storage . J. Mater. Chem. A , 2020 , 8 ( 7 ), 3822 – 3833 .

Chen, Q. Q. ; Hu, J. L. ; Xia, Q. ; Zhang, L. Z . Complexation-assisted polymerization for the synthesis of functional silicon oxycarbonitride with well-dispersed ultrafine CoS as high-performance anode for lithium-ion batteries . J. Alloys Compd. , 2023 , 949 , 169824 .

赵欣悦 , 胡金龙 , 燕禾 , 段先健 , 吴春蕾 , 王跃林 , 张灵志 . 新型硅氧碳氮负极材料合成及可控化学预锂化 . 新能源进展 , 2024 , 12 ( 6 ), 664 – 670 .

Hirsh, H. S. ; Li, Y. X. ; Tan, D. H. S. ; Zhang, M. H. ; Zhao, E. Y. ; Meng, Y. S . Sodium-ion batteries paving the way for grid energy storage . Adv. Energy Mater. , 2020 , 10 ( 32 ), 2001274 .

Vaalma, C. ; Buchholz, D. ; Weil, M. ; Passerini, S . A cost and resource analysis of sodium-ion batteries . Nat. Rev. Mater. , 2018 , 3 , 18013 .

Syed Ali Riza , 旭日干 , 刘琦 , Muhammad Hassan , 杨强 , 穆道斌 , 李丽 , 吴锋 , 陈人杰 . 钠离子电池负极材料综述 . 新型炭材料(中英文) , 2024 , 39 ( 5 ), 743 – 769 .

Kaspar, J. ; Storch, M. ; Schitco, C. ; Riedel, R. ; Graczyk-Zajac, M . SiOC(N)/hard carbon composite anodes for Na-ion batteries: Influence of morphology on the electrochemical properties . J. Electrochem. Soc. , 2016 , 163 ( 2 ), A156 – A162 .

Chandra, C. ; Kim, J . Silicon oxycarbide produced from silicone oil for high-performance anode material in sodium ion batteries . Chem. Eng. J. , 2018 , 338 , 126 – 136 .

Chandra, C. ; Cahyadi, H. S. ; Alvin, S. ; Devina, W. ; Park, J. H. ; Chang, W. ; Chung, K. Y. ; Kwak, S. K. ; Kim, J . Revealing the sodium storage mechanism in high-temperature-synthesized silicon oxycarbides . Chem. Mater. , 2020 , 32 ( 1 ), 410 – 423 .

Chandra, C. ; Devina, W. ; Sarofil, A. D. M. ; Kim, J . Strategy to enhance the electrochemical performance of silicon oxycarbide as anodes in sodium-ion batteries . Chem. Eng. J. , 2022 , 438 , 135411 .

Putra, R. N. ; Halim, M. ; Ali, G. ; Shaikh, S. F. ; Al-Enizi, A. M. ; Fazal, T. ; Jan Iftikhar, F. ; Saqib, A. N. S . High-rate sodium insertion/extraction into silicon oxycarbide-reduced graphene oxide . New J. Chem. , 2020 , 44 ( 33 ), 14035 – 14040 .

Kim, D. ; Kim, H. ; Lim, H. ; Kim, K. J. ; Jung, H. G. ; Byun, D. ; Kim, C. ; Choi, W . A facile control in free-carbon domain with divinylbenzene for the high-rate-performing Sb/SiOC composite anode material in sodium-ion batteries . Int. J. Energy Res. , 2020 , 44 ( 14 ), 11473 – 11486 .

Lee, Y. ; Lee, K. Y. ; Choi, W . One-pot synthesis of antimony-embedded silicon oxycarbide materials for high-performance sodium-ion batteries . Adv. Funct. Mater. , 2017 , 27 ( 43 ), 1702607 .

Park, J. ; Kim, M. ; Choi, M. ; Ku, M. ; Kam, D. ; Kim, S. O. ; Choi, W . Sb/C composite embedded in SiOC buffer matrix via  dispersion property control for novel anode material in sodium-ion batteries . J. Power Sources , 2023 , 568 , 232908 .

Lim, H. ; Yu, S. ; Chang, W. ; Chung, K. Y. ; Choi, W. ; Kim, S. O . Boosting the sodiation kinetics of Sn anode using a yolk-shell nanohybrid structure for high-rate and ultrastable sodium-ion batteries . Adv. Sci. , 2024 , 11 ( 48 ), 2408450 .

Dey, S. ; Manjunath, K. ; Zak, A. ; Singh, G . WS 2 nanotube-embedded SiOC fibermat electrodes for sodium-ion batteries . ACS Omega , 2023 , 8 ( 11 ), 10126 – 10138 .

Lim, H. ; Yu, S. ; Choi, W. ; Kim, S. O . Hierarchically designed nitrogen-doped MoS 2 /silicon oxycarbide nanoscale heterostructure as high-performance sodium-ion battery anode . ACS Nano , 2021 , 15 ( 4 ), 7409 – 7420 .

Lee, S. ; Seok, E. ; Kang, H. ; Park, D. ; Kim, M. ; Kam, D. ; Choi, M. ; Kim, H. S. ; Choi, W . Silicone oil-based selective SiOC coating onto hydrophobic rGO-MoS 2 composite materials to achieve ultra-stable composite anodes in sodium-ion batteries . J. Ind. Eng. Chem. , 2023 , 126 , 239 – 248 .

Zhang, W. C. ; Liu, Y. J. ; Guo, Z. P . Approaching high-performance potassium-ion batteries via advanced design strategies and engineering . Sci. Adv. , 2019 , 5 ( 5 ), eaav7412 .

Sang, Z. Y. ; Su, D. ; Wang, J. S. ; Liu, Y. ; Ji, H. M . Bi-continuous nanoporous carbon sphere derived from SiOC as high-performance anodes for PIBs . Chem. Eng. J. , 2020 , 381 , 122677 .

Li, Z. T. ; Dong, Y. F. ; Feng, J. Z. ; Xu, T. ; Ren, H. ; Gao, C. ; Li, Y. R. ; Cheng, M. J. ; Wu, W. T. ; Wu, M. B . Controllably enriched oxygen vacancies through polymer assistance in titanium pyrophosphate as a super anode for Na/K-ion batteries . ACS Nano , 2019 , 13 ( 8 ), 9227 – 9236 .

Chandra, C. ; Devina, W. ; Cahyadi, H. S. ; Kwak, S. K. ; Kim, J . Understanding lithium, sodium, and potassium storage mechanisms in silicon oxycarbide . Chem. Eng. J. , 2022 , 428 , 131072 .

Melzi d’Eril, M. ; Joanna Graczyk-Zajac, M. ; Riedel, R . On the reversible sodium plating/stripping reaction in porous SiCN(O) ceramic: A feasibility study . Batter. Supercaps , 2023 , 6 ( 3 ), e202200491 .

谢清水 , 汪依依 , 夏丽 , 张一鸣 , 瞿佰华 , 王敬丰 , 周小元 , 彭栋梁 . 镁离子电池的工作原理与关键材料 . 金属功能材料 , 2024 , 31 ( 1 ), 1 – 27 .

Guo, W. Q. ; Icin, O. ; Vakifahmetoglu, C. ; Kober, D. ; Gurlo, A. ; Bekheet, M. F . Magnesium-ion battery anode from polymer-derived SiOC nanobeads . Adv. Funct. Mater. , 2023 , 33 ( 48 ), 2304933 .

Guo, W. Q. ; Wang, J. ; Gurlo, A. ; Bekheet, M. F . Tin-containing silicon oxycarbonitride ceramic nanocomposites as stable anode for magnesium ion batteries . Batter. Supercaps , 2024 , 7 ( 6 ), e202400032 .

Bruce, P. G. ; Freunberger, S. A. ; Hardwick, L. J. ; Tarascon, J. M . Li-O 2 and Li-S batteries with high energy storage . Nat. Mater. , 2011 , 11 ( 1 ), 19 – 29 .

王唯嘉 , 李丰源 , 张紫萱 , 杨东澍 , 黄英 . 锂硫电池正极材料的研究进展 . 材料开发与应用 , 2023 , 38 ( 3 ), 96 – 104 .

Qu, F. M. ; Graczyk-Zajac, M. ; Vrankovic, D. ; Chai, N. ; Yu, Z. J. ; Riedel, R . Effect of morphology of C-rich silicon carbonitride ceramic on electrochemical properties of sulfur cathode for Li-S battery . Electrochim. Acta , 2021 , 384 , 138265 .

Qu, F. M. ; Yu, Z. J. ; Krol, M. ; Chai, N. ; Riedel, R. ; Graczyk-Zajac, M . Electrochemical performance of carbon-rich silicon carbonitride ceramic as support for sulfur cathode in lithium sulfur battery . Nanomaterials , 2022 , 12 ( 8 ), 1283 .

Weinberger, M. ; Munding, J. ; Lindén, M. ; Wohlfahrt-Mehrens, M . Template-derived submicrometric carbon spheres for lithium-sulfur and sodium-ion battery electrodes . Energy Technol. , 2018 , 6 ( 9 ), 1797 – 1804 .

Sun, J. M. ; Du, Z. Z. ; Liu, Y. H. ; Ai, W. ; Wang, K. ; Wang, T. ; Du, H. F. ; Liu, L. ; Huang, W . State-of-the-art and future challenges in high energy lithium–selenium batteries . Adv. Mater. , 2021 , 33 ( 10 ), 2003845 .

李俊艺 . 碳基锂硒电池正极材料的合理构筑及其储能研究 . 硕士学位论文 , 成都 : 电子科技大学 , 2024 .

Fang, R. Y. ; Xia, Y. ; Liang, C. ; He, X. P. ; Huang, H. ; Gan, Y. P. ; Zhang, J. ; Tao, X. Y. ; Zhang, W. K . Supercritical CO 2 -assisted synthesis of 3D porous SiOC/Se cathode for ultrahigh areal capacity and long cycle life Li–Se batteries . J. Mater. Chem. A , 2018 , 6 ( 48 ), 24773 – 24782 .

Moni, P. ; Deschamps, A. ; Schumacher, D. ; Rezwan, K. ; Wilhelm, M . A new silicon oxycarbide based gas diffusion layer for zinc-air batteries . J. Colloid Interface Sci. , 2020 , 577 , 494 – 502 .

陈萌 , 胡宗辉 , 高瑛 , 柯卓 . 锂离子电池用隔膜研究进展 . 上海轻工业 , 2024 , ( 6 ), 103 – 105 .

Smith, S. A. ; Park, J. H. ; Williams, B. P. ; Joo, Y. L . Polymer/ceramic co-continuous nanofiber membranes via room-curable organopolysilazane for improved lithium-ion battery performance . J. Mater. Sci. , 2017 , 52 ( 7 ), 3657 – 3669 .

Smith, S. A. ; Williams, B. P. ; Joo, Y. L . Effect of polymer and ceramic morphology on the material and electrochemical properties of electrospun PAN/polymer derived ceramic composite nanofiber membranes for lithium ion battery separators . J. Membr. Sci. , 2017 , 526 , 315 – 322 .

何志权 . MXene基电极材料的制备及其电化学性能研究 . 博士学位论文 , 北京 : 北京科技大学 , 2023 .

Sun, H. Y. ; Pan, J. M. ; Yan, X. H. ; Shen, W. ; Zhong, W. Q. ; Cheng, X. N . Mn O 2 nanoneedles loaded on silicon oxycarbide-derived hierarchically porous carbon for supercapacitor electrodes with enhanced electrochemical performance . Ceram. Int. , 2019 , 45 ( 18 ), 24802 – 24810 .

Swain, I. P. ; Pati, S. ; Behera, S. K . A preceramic polymer derived nanoporous carbon hybrid for supercapacitors . Chem. Commun. , 2019 , 55 ( 59 ), 8631 – 8634 .

Duan, L. Q. ; Ma, Q. S. ; Mei, L. ; Chen, Z. H . Fabrication and electrochemical performance of nanoporous carbon derived from silicon oxycarbide . Microporous Mesoporous Mater. , 2015 , 202 , 97 – 105 .

Tolosa, A. ; Krüner, B. ; Jäckel, N. ; Aslan, M. ; Vakifahmetoglu, C. ; Presser, V . Electrospinning and electrospraying of silicon oxycarbide-derived nanoporous carbon for supercapacitor electrodes . J. Power Sources , 2016 , 313 , 178 – 188 .

Yang, J. ; Wu, H. L. ; Zhu, M. ; Ren, W. J. ; Lin, Y. ; Chen, H. B. ; Pan, F . Optimized mesopores enabling enhanced rate performance in novel ultrahigh surface area meso-/ microporous carbon for supercapacitors . Nano Energy , 2017 , 33 , 453 – 461 .

Halim, M. ; Liu, G. C. ; Ardhi, R. E. A. ; Hudaya, C. ; Wijaya, O. ; Lee, S. H. ; Kim, A. Y. ; Lee, J. K . Pseudocapacitive characteristics of low-carbon silicon oxycarbide for lithium-ion capacitors . ACS Appl. Mater. Interfaces , 2017 , 9 ( 24 ), 20566 – 20576 .

Bin Mujib, S. ; Cuccato, R. ; Mukherjee, S. ; Franchin, G. ; Colombo, P. ; Singh, G . Electrospun SiOC ceramic fiber mats as freestanding electrodes for electrochemical energy storage applications . Ceram. Int. , 2020 , 46 ( 3 ), 3565 – 3573 .

Merida, J. ; Colomer, M. T. ; Rubio, F. ; Mazo, M. A . Highly porous carbon materials derived from silicon oxycarbides and effect of the pyrolysis temperature on their electrochemical response . Int. J. Mol. Sci. , 2023 , 24 ( 18 ), 13868 .

Moyano, J. J. ; Mosa, J. ; Aparicio, M. ; Pérez-Coll, D. ; Belmonte, M. ; Miranzo, P. ; Osendi, M. I . Strong and light cellular silicon carbonitride—Reduced graphene oxide material with enhanced electrical conductivity and capacitive response . Addit. Manuf. , 2019 , 30 , 100849 .

David, L. ; Shareef, K. M. ; Abass, M. A. ; Singh, G . Three-dimensional polymer-derived ceramic/graphene paper as a Li-ion battery and supercapacitor electrode . RSC Adv. , 2016 , 6 ( 59 ), 53894 – 53902 .

Okoroanyanwu, U. ; Bhardwaj, A. ; Einck, V. ; Ribbe, A. ; Hu, W. G. ; Rodriguez, J. M. ; Schmidt, W. R. ; Watkins, J. J . Rapid preparation and electrochemical energy storage applications of silicon carbide and silico n oxycarbide ceramic/carbon nanocomposites derived via flash photothermal pyrolysis of organosilicon preceramic polymers . Chem. Mater. , 2021 , 33 ( 2 ), 678 – 694 .

Wang, X. ; Zhang, M. G. ; Chang, P. ; Mei, H. ; Cheng, L. F. ; Zhang, L. T . Phase separation strategy achieves printable corrosion-resistant ternary SiOC supercapacitors with sustained capacitance increase . Chem. Eng. J. , 2023 , 465 , 142746 .

Kolathodi, M. S. ; David, L. ; Abass, M. A. ; Singh, G . Polysiloxane-functionalized graphene oxide paper: Pyrolysis and performance as a Li-ion battery and supercapacitor electrode . RSC Adv. , 2016 , 6 ( 78 ), 74323 – 74331 .

Abass, M. A. ; Syed, A. A. ; Gervais, C. ; Singh, G . Synthesis and electrochemical performance of a polymer-derived silicon oxycarbide/boron nitride nanotube composite . RSC Adv. , 2017 , 7 ( 35 ), 21576 – 21584 .

Mujib, S. B. ; Ribot, F. ; Gervais, C. ; Singh, G . Self-supporting carbon-rich SiOC ceramic electrodes for lithium-ion batteries and aqueous supercapacitors . RSC Adv. , 2021 , 11 ( 56 ), 35440 – 35454 .

Pazhamalai, P. ; Krishnamoorthy, K. ; Sahoo, S. ; Mariappan, V. K. ; Kim, S. J . Carbothermal conversion of siloxene sheets into silicon-oxy-carbide lamellae for high-performance supercapacitors . Chem. Eng. J. , 2020 , 387 , 123886 .

Zhang, E. H. ; Yang, M. Q. ; Zhou, Y. S. ; Ke, X. ; Tang, J. ; Guo, J. H. ; Li, Z. R . Silicon-oxy-carbide intercalated three-dimensional graphene hybrid membrane for all-solid-state supercapacitors . Appl. Surf. Sci. , 2024 , 646 , 158915 .

Xia, K. D. ; Cheng, Y. F. ; Zhang, H. ; Han, F. ; Duan, L. Y. ; Liu, X . Highly microporous nitrogen-doped carbon derived from silicon oxycarbide ceramics for supercapacitor application . J. Inorg. Organomet. Polym. Mater. , 2023 , 33 ( 7 ), 2023 – 2034 .

Reddy, I. N. ; Sreedhar, A. ; Reddy, C. V. ; Shim, J. ; Cho, M. ; Yoo, K. ; Kim, D. ; Gwag, J. S . High performance hierarchical SiCN nanowires for efficient photocatalytic-photoelectrocatalytic and supercapacitor applications . Appl. Catal. B Environ. , 2018 , 237 , 876 – 887 .