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1.浙江大学医学院附属邵逸夫医院,微创器械创新与应用国家工程研究中心,杭州 310016
2.浙江大学生物医学工程与仪器科学学院,杭州 310027
3.浙江大学,高分子科学与工程学系,杭州 310058
4.浙江大学,学生职业发展培训中心,杭州 310058
Received:27 July 2025,
Accepted:31 August 2025,
Published Online:30 September 2025,
Published:20 November 2025
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郑澜, 李峥, 李寒莹, 胡昌翠, 李天瑜. 基于新型导电水凝胶的纸基导体及其在科普实验教学中应用的研究. 高分子通报, 2025, 38(11), 1704-1712.
Zheng, L.; Li, Z.; Li, H. Y.; Hu, C. C.; Li, T. Y. Research on paper-based conductors based on novel conductive hydrogels and their application in popular science experiment teaching. Polym. Bull. (in Chinese), 2025, 38(11), 1704-1712.
郑澜, 李峥, 李寒莹, 胡昌翠, 李天瑜. 基于新型导电水凝胶的纸基导体及其在科普实验教学中应用的研究. 高分子通报, 2025, 38(11), 1704-1712. DOI: 10.14028/j.cnki.1003-3726.2025.25.119.
Zheng, L.; Li, Z.; Li, H. Y.; Hu, C. C.; Li, T. Y. Research on paper-based conductors based on novel conductive hydrogels and their application in popular science experiment teaching. Polym. Bull. (in Chinese), 2025, 38(11), 1704-1712. DOI: 10.14028/j.cnki.1003-3726.2025.25.119.
探究实践是提升小学生科学核心素养的重要途径,也是引导学生探索一个科学现象从“不可能”到“可能”的必经之路。传统金属导体在质量、柔性与制备成本等方面的局限,催生了柔性导电材料的技术革新,进而为电子科技发展提供了全新路径。本研究基于中小学科学教育需求,设计科普实验课程:制备聚(3
4-乙烯二氧噻吩)-聚苯乙烯磺酸(PEDOT:PSS)导电纸实现普通纸张的导电功能化改造,引入十二烷基苯磺酸(DBSA)改性技术进一步优化其导电性能,系统对比普通纸(绝缘体)、基础导电纸(半导体)和改性导电纸的电阻特性差异。基于戴维·库伯提出的“学习圈”理论,创新设计了强调持续反思与动手实践相结合的实验流程,引导学生对实验进行“观察—测量—分析—反思”,帮助学生理解背后的原理,突破纸张不能导电的思维定式,认识新材料在柔性电子领域的应用潜力,培养青少年的科学认知态度与创新思维能力。
Exploratory practice is conducive to developing the core scientific competency of primary school students
and it is also important to show students how a scientific phenomenon can be transformed from impossible to possible. The limitations of traditional metal conductors in terms of quality
flexibility
and fabrication cost give rise to technological innovation in flexible conductive materials and provide a new route for the development of electronic science and technology. Based on the needs of science education in primary and secondary schools
this study designed an engaging science experiment course focused on preparing poly(3
4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) conductive paper. This initiative aimed to facilitate the functional transformation of ordinary paper into a conductive medium by introducing dodecylbenzenesulfonic acid (DBSA) modification technology to further enhance its conductivity. The experimental design systematically compared the resistance characteristics of ordinary paper (an insulator)
basic conductive paper (a semiconductor)
and modified conductive paper. Therefore
this study employs the learning circle theory proposed by David Kolb to design an experimental process that emphasizes the combination of continuous reflection and hands-on practice. During this process
students can experience the chain of “observation—measurement—analysis—reflection” to help them dismantle preconceived notions regarding the electrical non-conductivity of paper while highlighting the application potential of novel materials within flexible electronics. Ultimately
this study aimed to foster students’ scientific awareness and innovative thinking concerning functional materials.
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Yoo, D. ; Kim, J. ; Kim, J. H . Direct synthesis of highly conductive poly(3, 4-ethylenedioxythiophene): poly(4-styrenesulfonate) (PEDOT: PSS)/graphene composites and their applications in energy harvesting systems . Nano Res. , 2014 , 7 ( 5 ), 717 – 730 .
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Morais, R. M. ; Klem, M. S. ; Ozório, M. S. ; Gomes, T. C. ; Alves, N . Roughness influence on the sheet resistance of the PEDOT: PSS printed on paper . Curr. Appl. Phys. , 2018 , 18 ( 2 ), 254 – 260 .
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Li, T. Y. ; Liang, B. ; Ye, Z. C. ; Zhang, L. ; Xu, S. Y. ; Tu, T. T. ; Zhang, Y. M. ; Cai, Y. ; Zhang, B. ; Fang, L. ; Mao, X. Y. ; Zhang, S. S. ; Wu, G. ; Yang, Q. F. ; Zhou, C. C. ; Cai, X. J. ; Ye, X. S . An integrated and conductive hydrogel-paper patch for simultaneous sensing of chemical–electrophysiological signals . Biosens. Bioelectron. , 2022 , 198 , 113855 .
汤浩 , 周浩楠 , 黄权波 , 葛文娇 , 王蕾 , 杨洋 , 王小慧 . 生物质与纸基柔性电子材料的研究进展 . 中国造纸 , 2022 , 41 ( 11 ), 75 – 86 .
Pal, A. ; Cuellar, H. E. ; Kuang, R. ; Caurin, H. F. N. ; Goswami, D. ; Martinez, R. V . Self-powered, paper-based electrochemical devices for sensitive point-of-care testing . Adv. Mater. Technol. , 2017 , 2 ( 10 ), 1700130 .
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Xu, Y. D. ; Zhao, G. G. ; Zhu, L. ; Fei, Q. H. ; Zhang, Z. ; Chen, Z. Y. ; An, F. F. ; Chen, Y. Y. ; Ling, Y. ; Guo, P. J. ; Ding, S. ; Huang, G. L. ; Chen, P. Y. ; Cao, Q. ; Yan, Z . Pencil-paper on-skin electronics . Proc. Natl. Acad. Sci. USA , 2020 , 117 ( 31 ), 18292 – 18301 .
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