Synthesis, UV-Curing and Properties of Acrylated Polysiloxane

XIE Mei-chang; HUANG Hai-qing; XIANG Hong-ping

doi:10.14028/j.cnki.1003-3726.2026.25.354

您当前的位置：

首页 >

文章列表页 >

Synthesis, UV-Curing and Properties of Acrylated Polysiloxane

更新时间：2026-05-29

- Synthesis, UV-Curing and Properties of Acrylated Polysiloxane
- Polymer Bulletin (2026)
- 作者机构：
  
  广东工业大学材料与能源学院　广州　 511400
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.25.354
  CLC：
- Received：04 December 2025，
  
  Accepted：02 March 2026，
- 稿件说明：
移动端阅览
谢美昌, 黄海清, 向洪平. 丙烯酸酯改性聚硅氧烷的合成及其紫外光固化性能. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.25.354

Xie, M. C.; Huang, H. Q.; Xiang, H. P. Synthesis, UV-curing and properties of acrylated polysiloxane. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.25.354
谢美昌, 黄海清, 向洪平. 丙烯酸酯改性聚硅氧烷的合成及其紫外光固化性能. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.25.354 DOI：

Xie, M. C.; Huang, H. Q.; Xiang, H. P. Synthesis, UV-curing and properties of acrylated polysiloxane. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.25.354 DOI：

摘要

以八甲基环四硅氧烷(D

)和3-甲基丙烯酰氧基丙基甲基二甲氧基硅烷(KH-571)为原料，通过开环–缩聚法成功制备出紫外光固化丙烯酸酯化聚硅氧烷。通过实时红外光谱(RTIR)、傅里叶变换红外光谱(FTIR)、核磁共振波谱(NMR)和热重分析(TG)等表征手段，系统研究了其分子结构、光聚合动力学、机械性能和热稳定性。实验结果表明，该丙烯酸酯化聚硅氧烷具有快速的光聚合能力，且丙烯酸酯双键转化率随丙烯酰氧基含量的增加而显著提高。同时，样品具有良好的机械性能和热稳定性，且通过调节反应物的配比可有效调控其性能。当聚合物链段中二甲基与丙烯酰氧基的链节数之比15:1时，所制备的样品PSi-15的丙烯酰氧基含量最高，交联程度最大，表现出最佳的拉伸强度(616.32 kPa)；而样品PSi-50丙烯酰氧基含量较低，Si―O―Si柔性链段提供了较好的分子柔顺性，能够在强度与柔韧性之间取得较好的平衡，展现出最佳的韧性(92.31 kJ/m

)。该光固化聚硅氧烷凭借其原料简单、成本低、固化效率高及性能可调的特点，具有广泛的应用前景。

Abstract

A UV-curable acrylated polysiloxane was prepared from octamethylcyclotetrasiloxane (D

) and 3-methacryloxypropylmethyldimethoxysilane (KH-571)

via

ring-opening polycondensation

which is simple

low-cost

and highly efficient. The molecular structure

photopolymerization kinetics

mechanical properties

and thermal stability of the resultant material were systematically investigated using multiple characterization techniques

including real-time infrared spectroscopy (RTIR)

Fourier-transform infrared spectroscopy (FTIR)

nuclear magnetic resonance (NMR) spectroscopy

and thermogravimetric analysis (TG). The experimental results demonstrated that the acrylated polysiloxane possessed excellent

rapid photopolymerization capability

with the double bond conversion rate increasing significantly as the acryloyloxy group content increased. The prepared samples exhibited superior mechanical properties and thermal stability

which could be effectively regulated by adjusting the reactant ratio. Specifically

sample PSi-15

with a methyl-to-acryloyloxy chain segment ratio of 15:1

had the highest acryloyloxy group content and crosslinking degree

thereby exhibiting the optimal tensile strength (616.32 kPa). In contrast

sample PSi-50 had a lower acryloyloxy group content

and the flexible Si―O―Si segments endowed the polymer with good molecular flexibility. At this reactant ratio

the sample achieved a favorable balance between strength and flexibility

showing the best toughness (92.31 kJ/m

). Owing to its readily available raw materials

low cost

high curing efficiency

and tunable performance

this UV-curable polysiloxane has broad application prospects in relevant fields.

关键词

Keywords

references

Xiang, H. P. ; Wang, X. W. ; Ou, Z. R. ; Lin, G. H. ; Yin, J. F. ; Liu, Z. ; Zhang, L. Y. ; Liu, X. X . UV-curable, 3D printable and biocompatible silicone elastomers . Prog. Org. Coat. , 2019 , 137 , 105372 .

Bao, Y. Y. ; Paunović, N. ; Leroux, J. C . Challenges and opportunities in 3D printing of biodegradable medical devices by emerging photopolymerization techniques . Adv. Funct. Mater. , 2022 , 32 ( 15 ), 2109864 .

Cao, Q . Self-powered electronic skin . Science , 2020 , 369 ( 6500 ), 154 – 156 .

叶娟 , 祖兆基 , 林子谦 , 向洪平 , 章明秋 . 本征型自修复聚硅氧烷材料: 从单重动态交联网络到多重动态交联网络 . 高分子学报 , 2023 , 54 ( 7 ), 1028 – 1054 .

Christmann, J. ; Ley, C. ; Allonas, X. ; Ibrahim, A. ; Croutxé-Barghorn, C . Experimental and theoretical investigations of free radical photopolymerization: Inhibition and termination reactions . Polymer , 2019 , 160 , 254 – 264 .

Hubmann, M. ; von Gunten, K. ; Alessi, D. S. ; Curtis, J. M . Epoxidized linseed lipids as a durable and fast-curing alternative to drying oils . Prog. Org. Coat. , 2021 , 159 , 106406 .

Peng, J. ; Zhou, C. L. ; Chen, B. ; Zhang, H. J. ; Pan, X. Y. ; Xiong, W. T. ; Luo, X. H. ; Liu, Y. L . Rational design of waterborne biobased epoxy methacrylates using citric acid and epoxy soybean oil for UV-curable coatings . Ind. Crops Prod. , 2024 , 209 , 117958 .

Czachor-Jadacka, D. ; Pilch-Pitera, B . Progress in development of UV curable powder coatings . Prog. Org. Coat. , 2021 , 158 , 106355 .

Stiles, A. ; Tison, T. A. ; Pruitt, L. ; Vaidya, U . Photoinitiator selection and concentration in photo- polymer formulations towards large-format additive manufacturing . Polymers , 2022 , 14 ( 13 ), 2708 .

Ribas-Massonis, A. ; Cicujano, M. ; Duran, J. ; Besalú, E. ; Poater, A . Free-radical photopolymerization for curing products for refinish coatings market . Polymers , 2022 , 14 ( 14 ), 2856 .

Qi, Y. S. ; Meng, X. ; Yang, J. W. ; Zeng, Z. H. ; Chen, Y. L . Synthesis and properties of ultraviolet/moisture dual-curable polysiloxane acrylates . J. Appl. Polym. Sci. , 2005 , 96 ( 3 ), 846 – 853 .

Chen, Z. G. ; Chisholm, B. ; Kim, J. ; Stafslien, S. ; Wagner, R. ; Patel, S. ; Daniels, J. ; Vander Wal, L. ; Li, J. ; Ward, K. ; Callow, M. ; Thompson, S. ; Siripirom, C . UV-curable, oxetane-toughened epoxy-siloxane coatings for marine fouling-release coating applications . Polym. Int. , 2008 , 57 ( 6 ), 879 – 886 .

Xue, L. ; Wang, D. X. ; Yang, Z. Z. ; Liang, Y. ; Zhang, J. ; Feng, S. Y . Facile, versatile and efficient synthesis of functional polysiloxanes via thiol-ene chemistry . Eur. Polym. J. , 2013 , 49 ( 5 ), 1050 – 1056 .

Yagci, Y. ; Jockusch, S. ; Turro, N. J . Photoinitiated polymerization: advances, challenges, and opportunities . Macromolecules , 2010 , 43 ( 15 ), 6245 – 6260 .

Ali Tehfe, M. ; Louradour, F. ; Lalevée, J. ; Fouassier, J. P . Photopolymerization reactions: on the way to a green and sustainable chemistry . Appl. Sci. , 2013 , 3 ( 2 ), 490 – 514 .

Sangermano, M. ; Razza, N. ; Crivello, J. V . Cationic UV-curing: technology and applications . Macromol. Mater. Eng. , 2014 , 299 ( 7 ), 775 – 793 .

Crivello, J. V. ; Acosta Ortiz, R . Synthesis of epoxy monomers that undergo synergistic photopolymerization by a radical-induced cationic mechanism . J. Polym. Sci. Part A Polym. Chem. , 2001 , 39 ( 20 ), 3578 – 3592 .

Zhao, T. T. ; Yu, R. ; Li, X. P. ; Zhang, Y. ; Yang, X. ; Zhao, X. J. ; Huang, W . A comparative study on 3D printed silicone-epoxy/acrylate hybrid polymers via pure photopolymerization and dual-curing mechanisms . J. Mater. Sci. , 2019 , 54 ( 6 ), 5101 – 5111 .

Huo, M. ; Hu, J. G. ; Clarke, D. R . Covalent adaptable networks with rapid UV response based on reversible thiol-ene reactions in silicone elastomers . Macromolecules , 2023 , 56 ( 22 ), 9107 – 9116 .

Yang, M. Q. ; Mao, J. ; Nie, W. ; Dong, Z. X. ; Wang, D. P. ; Zhao, Z. L. ; Ji, X. L . Facile synthesis and responsive behavior of PDMS- b-PEG diblock copolymer brushes via photoinitiated “thiol-ene” click reaction . J. Polym. Sci. Part A Polym. Chem. , 2012 , 50 ( 10 ), 2075 – 2083 .

Abdellah, L. ; Boutevin, B. ; Youssef, B . Synthesis and applications of photocrosslinkable poly(siloxanes) . Prog. Org. Coat. , 1994 , 23 ( 3 ), 201 – 236 .

Zhang, W. ; Wang, R. L. ; Yang, Z. ; Bai, Y. P. ; Meng, L. H. ; Wang, Y . Synthesis of UV rapid curing silicone coatings via photoinitiated thiol-ene click polymerization for pressure-sensitive adhesive . Polymer , 2023 , 283 , 126222 .

Lukin, R. Y. ; Kuchkaev, A. M. ; Sukhov, A. V. ; Bekmukhamedov, G. E. ; Yakhvarov, D. G . Platinum-catalyzed hydrosilylation in polymer chemistry . Polymers , 2020 , 12 ( 10 ), 2174 .

Woods, R. ; Feldbacher, S. ; Zidar, D. ; Langer, G. ; Satzinger, V. ; Schmidt, V. ; Pucher, N. ; Liska, R. ; Kern, W . 3D optical waveguides produced by two photon photopolymerisation of a flexible silanol terminated polysiloxane . J. Appl. Polym. Sci. , 2022 , 140 ( 5 ), 1234 – 1240 .

Liu, P. ; Gu, A. J. ; Liang, G. Z. ; Guan, Q. B. ; Yuan, L . Preparation and properties of novel high performance UV-curable epoxy acrylate/hyperbranched polysiloxane coatings . Prog. Org. Coat. , 2012 , 74 ( 1 ), 142 – 150 .

王小伟 , 向洪平 , 刘珠 , 刘晓暄 . 紫外光固化丙烯酸酯化聚硅氧烷的合成及其弹性体性能研究 . 有机硅材料 , 2019 , 33 ( 2 ), 84 – 90 .

Wang, S. C. ; Xie, M. C. ; Yu, B. ; Zu, Z. J. ; Zhang, L. Y. ; Xiang, H. P . Cycloaliphatic epoxy-functionalized polysiloxanes for UV-mask 3D printing via cationic photopolymerization . Addit. Manuf. , 2025 , 111 , 104977 .

Jin, H. ; Zhong, X. X. ; Zhong, C. C. ; Dai, W. S. ; Xiang, H. P. ; Zhang, L. Y . UV-curable, 3D printable, thermally conductive polysiloxane composites for thermal interface devices . Addit. Manuf. , 2025 , 99 , 104658 .

Yu, T. X. ; Liu, Y. Y. ; Tian, F. Y. ; Ning, N. Y. ; Yu, B. ; Tian, M . Silicone elastomer with high elongation at break used in digital light processing 3D printing . Chin. J. Polym. Sci. , 2023 , 41 ( 11 ), 1786 – 1795 .

Callau, M. ; Fajolles, C. ; Leroy, J. ; Verneuil, E. ; Guenoun, P . A silicone-based slippery polymer coating with humidity–dependent nanoscale topography . J. Colloid Interface Sci. , 2023 , 642 , 724 – 735 .

Xue, L. ; Zhang, Y. Y. ; Zuo, Y. J. ; Diao, S. ; Zhang, J. ; Feng, S. Y . Preparation and characterization of novel UV-curing silicone rubber via thiol-ene reaction . Mater. Lett. , 2013 , 106 , 425 – 427 .

Ju, H. K. ; Kang, Y. K. ; Lee, C. ; Kim, D. W . Fluorinated polymers derived from tetrafunctional cyclic siloxanes possessing low optical loss and high thermo-optic property . Mol. Cryst. Liq. Cryst. , 2010 , 520 ( 1 ), 412 – 419 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation and Properties of Low Migration Thermal Conductive Silicone Gel

Study on Structure and Luminescence Properties of Polysiloxane with Aggregation-induced Emission

Research Progress of Hyperbranched Silicon Functional Polymer

Research Advances on Polysiloxane Interpenetrating Polymer Network

Synthesis and Characterization of Polysiloxane Containing p-Silphenylene Prepared by Ring-Opening Polymerization and Dehydration Condendation

Related Author

LU Yong-lai

LI Jing-chao

YE Neng

WANG Zhi-jian

YANG Dan

Tian BAI

Hong-xia YAN

Song NIU

Related Institution

Center of Advanced Elastomer Materials, Beijing University of Chemical Technology

Northwestern Polytechnical University

Key Laboratory of Green Preparation and Application for Functional Materials,Ministry of Education; School of Materials Science and Engineering, Hubei University

College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Engineering

State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology

⁰