Research Progress on Dye-based Poly(vinyl alcohol) Polarizer Development

MA Rong; LIU Jia-li; ZHANG Qian-lei; WANG Jia-ming; LI Jia-ming; TANG Cheng-hong; WANG Dao-liang

doi:10.14028/j.cnki.1003-3726.2026.25.356

您当前的位置：

首页 >

文章列表页 >

Research Progress on Dye-based Poly(vinyl alcohol) Polarizer Development

更新时间：2026-04-30

- Research Progress on Dye-based Poly(vinyl alcohol) Polarizer Development
- Polymer Bulletin Vol. 39, Issue 5, Pages: 720-734(2026)
- 作者机构：
  
  安徽皖维先进功能膜材料研究院有限公司　合肥 230036
  安徽皖维高新材料股份有限公司　合肥 238012
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.25.356
  CLC：
- Received：05 December 2025，
  
  Accepted：19 January 2026，
  
  Online First：16 April 2026，
  
  Published：20 May 2026
- 稿件说明：
移动端阅览
马蓉, 柳佳利, 张前磊, 汪佳敏, 李家鸣, 唐成宏, 王道亮. 聚乙烯醇基染料系偏光片研究进展. 高分子通报, 2026, 39(5), 720–734.

Ma, R.; Liu, J. L.; Zhang, Q. L.; Wang, J. M.; Li, J. M.; Tang, C. H.; Wang, D. L. Research progress on dye-based poly(vinyl alcohol) polarizer development. Polym. Bull. (in Chinese), 2026, 39(5), 720–734.
马蓉, 柳佳利, 张前磊, 汪佳敏, 李家鸣, 唐成宏, 王道亮. 聚乙烯醇基染料系偏光片研究进展. 高分子通报, 2026, 39(5), 720–734. DOI： 10.14028/j.cnki.1003-3726.2026.25.356.

Ma, R.; Liu, J. L.; Zhang, Q. L.; Wang, J. M.; Li, J. M.; Tang, C. H.; Wang, D. L. Research progress on dye-based poly(vinyl alcohol) polarizer development. Polym. Bull. (in Chinese), 2026, 39(5), 720–734. DOI： 10.14028/j.cnki.1003-3726.2026.25.356.

摘要

随着信息化社会的发展，显示技术向柔性化、高耐候性方向发展，染料系偏光片因其优异的耐高温高湿性能而受到广泛关注。本文系统总结了以聚乙烯醇(PVA)为基材的染料系偏光片的研究进展，重点阐述了其制备原理、PVA光学膜性质及其对偏光性能的影响。围绕提升染料系偏光片光学性能与耐久性的关键问题，讨论了染料分子结构优化、染料配方、染色工艺以及PVA基膜改性等多元化改性策略。相关研究表明，通过构建染料与PVA间的强界面相互作用，可显著增强染料在PVA基膜中的取向有序性与耐湿热稳定性；同时，PVA基膜的复合改性不仅提升了其力学与耐水性能，也为染料分子提供了更稳定的取向平台。最后，展望了染料系偏光片在面向柔性显示与严苛环境应用中面临的挑战与发展方向，强调了“结构–加工–性能”关联机制研究的重要性，为新一代高性能复合材料型偏光片的设计与开发提供了理论依据与技术路径。

Abstract

With the advancement of display technologies toward flexibility and high weatherability

dye-based polarizers have attracted widespread attention owing to their excellent resistance to high temperature and humidity. This review systematically summarizes recent research progress on poly(vinyl alcohol) (PVA)-based dye-type polarizing films

focusing on their preparation principles

PVA optical film properties

and the effects of these mechanisms on polarizing performance. To address the key challenges of enhancing optical performance and durability

diversified modification strategies are discussed

including molecular structure optimization of dyes

synergistic dye compounding

improvements in dyeing processes

and modifications of the PVA substrate. Studies have shown that constructing strong interfacial interactions between dyes and the PVA matrix can significantly improve the orientation order and moisture-heat stability of the dyes. Composite modification of the PVA substrate not only enhanced its mechanical and water-resistant properties but also provided a more stable orientation platform for the dye molecules. Finally

this review outlines the challenges and future directions for dye-based polarizers in flexible displays and harsh-environment applications

emphasizing the importance of establishing a “structure-processing-performance” relationship. This study provides a theoretical basis and technical pathway for the design and development of a new generation of high-performance composite-based polarizers.

关键词

Keywords

references

Sato, T . Recent trends in retardation films . Int. Polym. Sci. Technol. , 2012 , 39 ( 1 ), 15 – 24 .

Land, E. H . Some aspects of the development of sheet polarizers . JOSA , 1951 , 41 ( 12 ), 957 – 963 .

Ma, J. ; Ye, X. ; Jin, B . Structure and application of polarizer film for thin-film-transistor liquid crystal displays . Displays , 2011 , 32 ( 2 ), 49 – 57 .

望月典明 , 樋下田贵大 . 用于红外线波长区域的染料系偏光板 . 中国专利 , CN114460678A . 2022-05-10 .

望月典明 , 樋下田贵大 , 服部由侑 , 中村光则 . 无色彩的偏光元件、以及使用该偏光元件的无色彩偏光板及显示装置 . 中国专利 , CN111448493B . 2022-03-04 .

樋下田贵大 , 望月典明 . 偶氮化合物或其盐, 以及含有偶氮化合物或其盐的染料系偏光膜及染料系偏光板 . 中国专利 , CN110114418B . 2021-03-30 .

Tashiro, K. ; Takahama, T. ; Wang, M. F . X-ray study of poly(vinyl alcohol)-iodine complex prepared from the dilute iodine solution as a hint to know the inner structure of polarizer . Polymer , 2021 , 233 , 124180 .

Liang, X. X. ; Zhong, H. J. ; Ding, H. Y. ; Yu, B. ; Ma, X. ; Liu, X. Y. ; Chong, C. M. ; He, J. W . Polyvinyl alcohol (PVA)-based hydrogels: recent progress in fabrication, properties, and multifunctional applications . Polymers , 2024 , 16 ( 19 ), 2755 – 2793 .

Mochizuki, N. ; Ishinabe, T. ; Fujiwara, D. ; Nakamura, D. ; Koma, N. ; Fujikake, H . Achromatic dye-type polarizer for paper white reflective liquid crystal displays . ITE Trans. Media. Tech , 2018 , 6 ( 4 ), 262 – 268 .

Takahama, T. ; Saharin, S. M. ; Tashiro, K . Details of the intermolecular interactions in poly(vinyl alcohol)-iodine complexes as studied by quantum chemical calculations . Polymer , 2016 , 99 , 566 – 579 .

Umoren, S. A. ; Obot, I. B. ; Madhankumar, A. ; Gasem, Z. M . Effect of degree of hydrolysis of polyvinyl alcohol on the corrosion inhibition of steel: theoretical and experimental studies . J. Adhes. Sci. Technol. , 2015 , 29 ( 4 ), 271 – 295 .

杨琥 , 程镕时 . 聚乙烯醇-碘复合物在水溶液中的形成 . 高分子通报 , 2008 , ( 1 ), 7 – 15 .

Choi, Y. S. ; Miyasaka, K . Structure and properties of poly(vinyl alcohol)-iodine complex formed in the crystal phase of poly(vinyl alcohol) films . J. Appl. Polym. Sci. , 1994 , 51 ( 4 ), 613 – 618 .

Zachmann, H. G . Structure in Polymers with Special Properties . Berlin, Heidelberg : Springer , 1993 .

Choi, J. H. ; Lyoo, W. S. ; Ghim, H. D. ; Ko, S. W . High molecular weight syndiotacticity-rich poly(vinyl alcohol) gel in aging process . Colloid Polym. Sci. , 2000 , 278 ( 12 ), 1198 – 1204 .

Wang, H. J. ; He, J. W. ; Zou, L. M. ; Wang, C. ; Wang, Y. L . Synthesis of syndiotacticity-rich high polymerization degree PVA polymers with VAc and VPa, fabrication of PVA fibers with superior mechanical properties by wet spinning . J. Polym. Res. , 2021 , 28 ( 10 ), 386 .

党鋆 , 张军华 . 低聚合度聚乙烯醇对高聚合度聚乙烯醇水溶性的影响 . 高分子通报 , 2014 , ( 1 ), 49 – 53 .

Ngui, M. O. ; Mallapragada, S. K . Quantitative analysis of crystallization and skin formation during isothermal solvent removal from semicrystalline polymers . Polymer , 1999 , 40 ( 19 ), 5393 – 5400 .

Keshavarz, L. ; Khansary, M. A. ; Shirazian, S . Phase diagram of ternary polymeric solutions containing nonsolvent/solvent/polymer: theoretical calculation and experimental validation . Polymer , 2015 , 73 , 1 – 8 .

Bouyer, D. ; M’Barki, O. ; Pochat-Bohatier, C. ; Faur, C. ; Petit, E. ; Guenoun, P . Modeling the membrane formation of novel PVA membranes for predicting the composition path and their final morphology . AIChE. J. , 2017 , 63 ( 7 ), 3035 – 3047 .

Li, C. X. ; Chen, H. ; Fu, Z. Z. ; Zhang, Q. ; Wang, K. ; Fu, Q . Exploring formation rationale of skin-core heterogeneity during PVA solutions evaporation by laser-induced fluorescence analysis . Polymer , 2021 , 224 , 123759 .

Fei, W. H. ; Wu, Z. S. ; Cheng, H. ; Xiong, Y. Q. ; Chen, W. ; Meng, L. P . Molecular mobility and morphology change of poly(vinyl alcohol) (PVA) film as induced by plasticizer glycerol . J. Polym. Sci. , 2023 , 61 ( 17 ), 1959 – 1970 .

周文贤 , 李铭全 . 新型高耐久染料系聚乙烯醇偏光膜的性能研究 . 中国塑料 , 2022 , 36 ( 4 ), 53 – 59 .

Chang, J. B. ; Hwang, J. H. ; Park, J. S. ; Kim, J. P . The effect of dye structure on the dyeing and optical properties of dichroic dyes for PVA polarizing film . Dyes Pigm. , 2011 , 88 ( 3 ), 366 – 371 .

Shahab, S. ; Hajikolaee, F. H. ; Filippovich, L. ; Darroudi, M. ; Loiko, V. A. ; Kumar, R. ; Borzehandani, M. Y . Molecular structure and UV-Vis spectral analysis of new synthesized azo dyes for application in polarizing films . Dyes Pigm. , 2016 , 129 , 9 – 17 .

Agabekov, V. ; Ariko, N. ; Filippovich, L . Spectral-polarizing properties and light stability of film polarizers with azodyes . J. Soc. Inf. Disp. , 2006 , 14 ( 7 ), 627 – 632 .

服部由侑 , 森田陵太郎 , 望月典明 . 偶氮化合物或其盐, 以及含有该化合物或其盐的染料系偏光膜及染料系偏光板 . 中国专利 , CN113227257B . 2021-08-06 .

望月典明 , 樋下田贵大 , 西口卓斗 . 染料系偏光元件和偏振片 . 中国专利 , CN103547949B . 2017-07-21 .

佐野秀雄 , 门脇雅美 , 长谷川龙一 , 米山富雄 . 三偶氮染料、含该染料的各向异性染料膜用组合物、各向异性染料膜及偏光元件 . 中国专利 , CN101087853 . 2007-12-12 .

李建红 , 钱琨 , 冯素伟 , 许春江 . 基于多波段二色性染料的偏光片光学提升方法 . 中国专利 , CN120352969A . 2025-07-22 .

李晓莲 , 张宗英 , 王兵 . 有机二向性染料彩色偏振片的合成及性能 . 2010中国平板显示学术会议论文集 . 上海 : 中国光学光电子行业协会 , 2010 . 442 – 443 .

付华 . 二色性偶氮染料的化学修饰及其偏光膜的偏光性研究 . 西南科技大学硕士学位论文 , 2006 .

龚建勋 , 刘正义 , 曾德长 , 闻立时 . 溶致液晶偏振薄膜的研究 . 功能材料与器件学报 , 2006 , 12 ( 5 ), 383 – 388 .

Do Kim, Y. ; Lee, J. U. ; Lee, J. J . Improving durability of dye-based polarizing films using novel reactive dyes as dichroic materials . Polymers , 2023 , 15 ( 22 ), 4365 .

Chang, J. B. ; Yuk, S. B. ; Park, J. S. ; Kim, J. P . Dichroic and spectral properties of anthraquinone-based azo dyes for PVA polarizing film . Dyes Pigm. , 2012 , 92 ( 1 ), 737 – 744 .

吕荣文 , 高崑玉 . 活性染料的发展趋向 . 染料与染色 , 2004 , 41 ( 3 ), 131 – 136 .

赵雪 , 赵德峰 , 简卫 , 陈美芬 . 活性染料复配技术的进展 . 国际纺织导报 , 2011 , 39 ( 12 ), 38 – 40 .

Almodarresiyeh, H. A. ; Shahab, S. ; Filippovich, L. ; Kumar, R. ; Lugovsky, A. ; Agabekov, V . Broad band thermostable polarizing film based on poly(vinyl alcohol), a quinoline derivative and ZnO nanoparticles . RSC Adv. , 2016 , 6 ( 48 ), 42062 – 42068 .

Kato, H. ; Koma, N. ; Toda, J. ; Mochizuki, N. ; Higeta, T. ; Nishiguchi, T . 56-2: Development of a higher-performance polarizer with dye components . SID Symp. Dig. Tech. Pap. , 2016 , 47 ( 1 ), 757 – 760 .

周文贤 . 偏光膜染色工艺初探 . 广州化工 , 2022 , 50 ( 1 ), 67 – 68 .

李广鑫 , 曾特壕 , 张卓莉 , 陈朝晖 , 李中原 . 一种低收缩高耐久型染料系偏光片及其制备方法 . 中国专利 , CN114002770A . 2024-02-13 .

Lyoo, W. S. ; Yeum, J. H. ; Park, J. M. ; Kwak, J. W. ; Kim, J. H. ; Kim, S. S. ; Ji, B. C. ; Noh, S. K . Role of molecular weight of atactic poly(vinyl alcohol) (PVA) in the polarizing efficiency of PVA/azo dye complex film with high durability . J. Appl. Polym. Sci. , 2005 , 96 ( 4 ), 967 – 974 .

范吉吉 , 朱清梅 , 步亚楠 , 陈秀琼 , 颜慧琼 , 林强 . 食品软包装用高阻隔性聚丙烯酸/聚乙烯醇水性复合涂料的研究 . 复合材料学报 , 2025 , 1 – 12 .

周闯 , 李普旺 , 屈云慧 , 杨子明 , 何祖宇 , 王超 , 刘运浩 , 宋书会 , 于丽娟 . 聚乙烯醇膜耐水改性的研究进展 . 高分子通报 , 2021 , 34 ( 2 ), 9 – 17 .

Ye, K. ; Li, Y. H. ; Zhang, W. W. ; Zhang, Q. L. ; Chen, W. ; Meng, L. P. ; Wang, D. L. ; Li, L. B . Stretch-induced structural evolution of poly(vinyl alcohol) at different concentrations of boric acid: an in-situ synchrotron radiation small- and wide- angle X-ray scattering study . Polym. Test. , 2019 , 77 , 105913 .

Edwin, H. L . Treatment of polarizing polyvinyl alcohol-iodine sorption complex image with boric acid . USA patent , US2445581(A) , 1943-12-09 .

Morimune, S. ; Kotera, M. ; Nishino, T. ; Goto, K. ; Hata, K . Poly(vinyl alcohol) nanocomposites with nanodiamond . Macromolecules , 2011 , 44 ( 11 ), 4415 – 4421 .

宫贵贞 . 碳点改性聚乙烯醇性能的研究进展 . 复合材料学报 , 2024 , 41 ( 1 ), 92 – 107 .

Wang, J. M. ; Wu, Y. P. ; Xue, Y. ; Liu, D. ; Wang, X. B. ; Hu, X. ; Bando, Y. ; Lei, W. W . Super-compatible functional boron nitride nanosheets/polymer films with excellent mechanical properties and ultra-high thermal conductivity for thermal management . J. Mater. Chem. C , 2018 , 6 ( 6 ), 1363 – 1369 .

Bonderer, L. J. ; Studart, A. R. ; Gauckler, L. J . Bioinspired design and assembly of platelet reinforced polymer films . Science , 2008 , 319 ( 5866 ), 1069 – 1073 .

赵肖娟 , 李海文 , 权爽 , 李思仪 . 蒙脱土-纤维素纳米晶组装体对聚乙烯醇薄膜力学性能的提升 . 复合材料学报 , 2022 , 39 ( 7 ), 3242 – 3250 .

王松 , 贾志欣 , 周向阳 , 谢东 , 陈明周 , 罗远芳 , 贾德民 . 埃洛石纳米管/聚乙烯醇-淀粉复合膜的结构与性能 . 复合材料学报 , 2017 , 34 ( 12 ), 2689 – 2694 .

陈晓 , 陈宁 , 王琪 . 聚乙烯醇/纳米羟基磷灰石复合材料微型注塑研究 . 高分子通报 , 2013 , 26 ( 6 ), 26 – 32 .

Feng, Z. X. ; Xu, D. ; Shao, Z. B. ; Zhu, P. ; Qiu, J. H. ; Zhu, L. X . Rice straw cellulose microfiber reinforcing PVA composite film of ultraviolet blocking through pre-cross-linking . Carbohydr. Polym. , 2022 , 296 , 119886 .

钦浩函 , 冯前 , 刘昭懿 , 赵伟 , 朱旭 , 徐朝阳 . 含木质素纳米纤维/聚乙烯醇紫外屏蔽复合薄膜制备与性能 . 复合材料学报 , 2025 , 1 – 15 .

邓浩 , 项爱民 . 聚乙烯醇/纳米二氧化硅复合偏光膜的制备及结构与性能研究 . 中国塑料 , 2008 , 22 ( 4 ), 70 – 73 .

杨洋 , 汪亚威 , 黄睿 , 蔡福水 , 陈国华 . 石墨烯量子点对PVA偏光膜的改性 . 华侨大学学报(自然科学版) , 2021 , 42 ( 04 ), 501 – 506 .

Zhang, J. ; Xu, W. R. ; Zhang, Y. C. ; Han, X. D. ; Chen, C. ; Chen, A . In situ generated silica reinforced polyvinyl alcohol/liquefied chitin biodegradable films for food packaging . Carbohydr. Polym. , 2020 , 238 , 116182 .

Yu, Z. ; Li, B. Q. ; Chu, J. Y. ; Zhang, P. F . Silica in situ enhanced PVA/chitosan bi odegradable films for food packages . Carbohydr. Polym. , 2018 , 184 , 214 – 220 .

Liu, Z. G. ; Lu, H. C. ; Zhang, H. L. ; Li, L . Poly(vinylalcohol)/polylactic acid blendfilm with enhanced processability, compatibility, and mechanical property fabricated via melt processing . J. Appl. Polym. Sci. , 2021 , 138 ( 41 ), 51204 .

Views

384

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Advances in Poly(α,β,β-trifluorostyrene) and Its Derivatives

Advances in Structure and Properties of Poly(vinyl alcohol) Optical Films for New Displays

High-toughness Dual-network Ion-conductive Hydrogel for Flexible Wearable Sensors

Preparation and Properties of Poly(lactic acid)/β-Tricalcium Phosphate Composite Medical Porous Bone Scaffolds Based on Fused Deposition Modeling 3D Printing

Preparation and Rubber Compound Performance of Low Hysteresis High Abrasion Carbon Black

Related Author

WANG Dao-iang

WU Jun-yi

DU Li-jun

GUO Qing-yun

WANG Yu-feng

HUO Li-yao

MA Hao-zhe

YANG Shu-guang

Related Institution

Shanghai Huayi 3F New Materials Co., Ltd.

State Key Laboratory of Advanced Fiber Materials, Center for Advanced Low-dimension Materials, College of Materials Science and Engineering, Donghua University

National Synchrotron Radiation Laboratory, School of Nuclear Science and Technology, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China

Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University

Anhui Wanwei Advanced Functional Membrane Material Research Institute Co. Ltd.

⁰