Multiscale Structural Design and Property Regulation of Ionogels

WANG Qing-hua; ZHANG Xin-yue; LYU Xiao-lin

doi:10.14028/j.cnki.1003-3726.2026.26.310

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Multiscale Structural Design and Property Regulation of Ionogels

更新时间：2026-10-10

- Multiscale Structural Design and Property Regulation of Ionogels
- Polymer Bulletin (2026)
- 作者机构：
  
  福州大学材料科学与工程学院　福州 350108
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.26.310
  CLC：
- Received：03 August 2026，
  
  Accepted：27 August 2026，
- 稿件说明：
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王清华, 张馨月, 吕晓林. 离子凝胶的多尺度结构设计与性质调控. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.26.310

Wang, Q. H.; Zhang, X. Y.; Lyu, X. L. Multiscale structural design and property regulation of ionogels. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.26.310
王清华, 张馨月, 吕晓林. 离子凝胶的多尺度结构设计与性质调控. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.26.310 DOI：

Wang, Q. H.; Zhang, X. Y.; Lyu, X. L. Multiscale structural design and property regulation of ionogels. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.26.310 DOI：

摘要

离子凝胶克服了水凝胶易挥发、易冻结的环境敏感性，兼具高离子电导率、热稳定性等优异特性，在柔性电子、软体机器人和能源存储领域潜力巨大。但简单网络结构往往难以兼顾力学强度、导电性能与自修复能力，制约了其实际应用。本综述依据调控尺度与作用机制，将现有设计策略归纳为分子工程与结构工程2类。分子工程聚焦亚纳米至纳米尺度的动态网络设计，涵盖双网络、链缠结、滑环效应、氢键、离子相互作用、金属配位、动态共价键及协同效应，结构工程着眼纳米至微米尺度的空间构型调控，包括微相分离、纳米结晶域、纳米复合、取向结构及梯度结构。在此基础上，进一步总结了离子凝胶在能源存储与转换、柔性传感及软体机器人等应用领域的发展。本综述系统梳理了离子凝胶的多尺度结构设计策略和应用进展，讨论了未来发展的核心挑战，以期为高性能离子凝胶的理性设计和器件集成提供参考。

Abstract

Ionogels overcome the environmental sensitivity of hydrogels

which are prone to evaporation and freezing. They exhibit excellent properties such as high ionic conductivity and thermal stability

showing great potential in flexible electronics

soft robotics

and energy storage. However

simple network structures often fail to simultaneously achieve mechanical robustness

ionic conductivity

and self-healing capability

which limits their practical applications. This review categorizes existing design strategies into molecular engineering and structural engineering based on the regulation scale and underlying mechanisms. Molecular engineering focuses on dynamic network design at the sub-nanometer to nanometer scale

including double networks

chain entanglement

sliding ring effects

hydrogen bonding

ionic interactions

metal coordination

dynamic covalent bonds

and synergistic effects. Structural engineering addresses spatial configuration regulation from the nanometer to micrometer scale

including microphase separation

nanocrystalline domains

nanocomposites

oriented structures

and gradient structures. Furthermore

this review summarizes the progress of ionogels in applications such as energy storage and conversion

flexible sensing

and soft robotics. This article systematically outlines the design approaches and application advances in ionogels

and discusses key challenges for future development

aiming to provide a reference for the rational design of high-performance ionogels and device integration.

关键词

Keywords

references

Boufidis, D. ; Garg, R. ; Angelopoulos, E. ; Cullen, D. K. ; Vitale, F . Bio-inspired electronics: soft, biohybrid, and “living” neural interfaces . Nat. Commun ., 2025 , 16 , 1861 .

Zheng, Q. W. ; Xin, L. M. ; Zhang, Q. ; Shen, F. ; Lu, X. ; Cao, C. ; Xin, C. F. ; Zhao, Y. ; Liu, H. M. ; Peng, Y. ; Luo, J. ; Guo, H. Y. ; Li, Z. J . Leech-inspired amphibious soft robot driven by high-voltage triboelectricity . Adv. Mater ., 2025 , 37 ( 8 ), 2417380 .

Zhang, X. Y. ; Lin, Y. ; Shen, S. T. ; Du, Z. H. ; Lin, Z. Q. ; Zhou, P. P. ; Huang, H. L. ; Lyu, X. L. ; Zou, Z. G . Intrinsic anti-freezing, tough, and transparent hydrogels for smart optical and multi-modal sensing applications . Adv. Mater ., 2025 , 37 ( 8 ), 2413856 .

Du, Z. H. ; Wang, Q. H. ; Xiao, A. Q. ; Zhou, P. P. ; Lyu, X. L. ; Zou, Z. G . Anti-swelling and mechanically robust composite hydrogels in aquatic environments . Chinese J. Polym. Sci ., 2026 , 44 , 1027 – 1034 .

Zhang, X. C. ; Li, D. ; Yang, X. X. ; Wang, L. ; Li, G. ; Wong, T. W. ; Li, T. F. ; Yang, W. ; Luo, Z. S . Hydro-locking in hydrogel for extreme temperature tolerance . Science , 2025 , 387 ( 6737 ), 967 – 973 .

Xu, Z. R. ; Huang, Y. F. ; Sun, S. Y. ; Wang, P. ; He, Z. Y. ; Tian, H. ; Ma, X . Programmable ultralong phosphorescent ionogels for intelligent monitoring . Angew. Chem. Int. Ed ., 2025 , 64 ( 47 ), e202518340 .

Xiong, J. F. ; Duan, M. Z. ; Zou, X. Y. ; Gao, S. N. ; Guo, J. N. ; Wang, X. W. ; Li, Q. N. ; Li, W. Z. ; Wang, X. L. ; Yan, F . Biocompatible tough ionogels with reversible supramolecular adhesion . J. Am. Chem. Soc ., 2024 , 146 ( 20 ), 13903 – 13913 .

Han, X. K. ; Lu, T. Y. ; Huang, Y. Y. ; Liu, G. T. ; Guo, S. Y . Supramolecular-reinforced hard-phase ionogels with exceptional mechanical robustness and damage tolerance . Adv. Mater ., 2025 , 37 ( 41 ), e10713 .

Ma, D. X. ; Zhou, Y. ; Peng, R. G. ; Zhen, Y. P. ; Gao, L. K. ; Ma, L. R. ; Ding, N. B. ; Yang, C. ; Luo, Y. L. ; Zhang, Y. ; Lu, K. L. ; Cui, Y. L. ; Yan, Z. Y. ; Liu, L. ; Wang, G. X . High-sensitivity, dual-mode, flexible, electrooxidized cellulose-based electronic skins with compatible mechanical properties and antimicrobial activity for wide-temperature applications . Mater. Horiz ., 2026 , 13 ( 4 ), 2005 – 2021 .

Wang, J. W. ; Zheng, Y. P. ; Cui, T. Y. ; Huang, T. Y. ; Liu, H. D. ; Zhu, J. X. ; Song, L. ; Hu, Y . Bioinspired ultra-robust ionogels constructed with soft-rigid confinement space for multimodal monitoring electronics . Adv. Funct. Mater ., 2024 , 34 ( 6 ), 2312383 .

Xu, A. L. ; Liu, J. Y. ; Wang, Y. G. ; Xiao, Z. F. ; Xie, Y. J . Leaf-inspired cellulose ionogels under spatial confinement with synergistically enhanced mechanical and sensing performance for flexible sensors . Adv. Funct. Mater ., 2026 , 36 ( 14 ), e19010 .

Xu, C. G. ; Chen, Y. ; Zhao, S. Y. ; Li, D. K. ; Tang, X. ; Zhang, H. L. ; Huang, J. X. ; Guo, Z. G. ; Liu, W. M . Mechanical regulation of polymer gels . Chem. Rev ., 2024 , 124 ( 18 ), 10435 – 10508 .

Xu, Z. ; Xu, T. ; Feng, J. Q. ; Guo, P. ; Yao, X. ; Qin, H. L. ; Cong, H. P . Nanoconfined entanglement-enhanced phase separation enables tough and contractile ionogel fibers . Nat. Commun ., 2026 , 17 , 1003 .

Chen, Y. X. ; Yue, C. J. ; Zhang, H. ; Li, H. J. ; Chen, W. Z. ; Wang, W. Q. ; Chen, T. ; Wei, S. X . Anti-swelling, underwater adhesion, and luminescent polymeric ionogels for multifunctional marine wearable skin . ACS Appl. Mater. Interfaces , 2026 , 18 ( 1 ), 3250 – 3261 .

Jiang, J. L. ; Song, X. N. ; Chen, Y. X. ; Zhou, H. F. ; Zhao, L . Toward tough and recyclable ionogels with high thermal sensitivity via microphase separation for sustainable ionic skins . Chem. Eng. J ., 2026 , 537 , 176521 .

Jin, Y. F. ; Liu, M. Q. ; Wang, X. L. ; Feng, J. C. ; Wang, X. R. ; Cao, X. R. ; Piao, Y. J. ; An, C. J . Simultaneous enhancement of thermoelectric and mechanical properties in recyclable transparent ionogels via in-situ phase separation . ACS Appl. Mater. Interfaces , 2026 , 18 ( 15 ), 22161 – 22170 .

Liu, Y. X. ; Long, Y. ; Zhao, B. Q. ; Jian, X. Y. ; Sha, W. ; Wang, J. W. ; Chen, Y. H. ; Wang, T. N. ; Yang, H. W. ; Hu, W. G. ; Li, X. X . Cation- π interaction and π -delocalization coupled ionogel electrodes for triboelectric and bioelectronic interfaces . Nano Energy , 2026 , 153 , 111954 .

Zhang, L. W. ; Liu, S. ; Wang, Z. Z. ; Lei, Z. Y. ; Wu, P. Y . An enthalpy-entropy compensated ionogel with a broadband viscoelastic plateau for non-invasive and high-fidelity neurointerfaces . Adv. Mater ., 2026 , 38 ( 16 ), e21208 .

Dang, C. ; Shao, C. Y. ; Liu, H. C. ; Chen, Y. A. ; Qi, H. S . Cellulose melt processing assisted by small biomass molecule to fabricate recyclable ionogels for versatile stretchable triboelectric nanogenerators . Nano Energy , 2021 , 90 , 106619 .

Wang, T. ; Chu, Y. Q. ; Fang, Y. Z. ; Liu, Z. F . Stretchable alternating current electroluminescent fiber based on transparent and highly conductive dual-network imidazolium chloride ion-gel electrodes for wearable display applications . J. Mater. Chem. C , 2025 , 13 ( 7 ), 3482 – 3492 .

Hu, A. K. ; Liu, C. ; Cui, Z. Y. ; Cong, Z. H. ; Niu, J . Wearable sensors adapted to extreme environments based on the robust ionogel electrolytes with dual hydrogen networks . ACS Appl. Mater. Interfaces , 2022 , 14 ( 10 ), 12713 – 12721 .

Wang, S. B. ; Zhang, D. ; Zhou, J. H. ; He, X. M. ; Zheng, S. Y. ; Yang, J. T . Zwitterionic ionogels with water-mediated stiffness transition for shape memory and moisture electric generation . Nano Energy , 2024 , 120 , 109166 .

Wu, Q. R. ; Xu, Y. D. ; Han, S. J. ; Zhu, J. D. ; Chen, A. B. ; Zhang, J. Y. ; Chen, Y. J. ; Yang, X. X. ; Huang, J. R. ; Guan, L. H . A liquid-free conducting ionoelastomer for 3D printable multifunctional self-healing electronic skin with tactile sensing capabilities . Mater. Horiz ., 2023 , 10 ( 9 ), 3610 – 3621 .

Qiu, J. M. ; Song, Y. Y. ; Li, J. ; Lu, C. H. ; Wu, X. D. ; Xiong, R . Chiral photonic ionic skin for ultrafast, hysteresis-free mechanosensing . ACS Nano , 2025 , 19 ( 46 ), 39827 – 39838 .

Kang, T. ; Dai, J. Y. ; Huang, Y. ; Kim, H. ; Keten, S. ; Kim, J . Entanglements and fracture in polymers . Chem. Rev ., 2025 , 125 ( 22 ), 11032 – 11057 .

Yan, Y. Z. ; Jing, X. ; Wang, G. R. ; Feng, P. Y. ; Mi, H. Y. ; Liu, Y. J. ; Geng, L. H . Solvent-driven dual-network entanglement for organo-hydrogels with high strength and toughness . Sci. China Mater ., 2026 , 69 , 3492 – 3502 .

Yao, L. ; Huang, Y. ; Chen, G. Q. ; Zhou, Z. Q. ; Zhu, H. ; Zhang, Q. ; Zhu, S. P . Anti-creep adhesive tapes via trapped-entanglement-regulated topological networks . Adv. Mater ., 2026 , 38 ( 7 ), e13105 .

Mei, H. G. ; Liu, C. ; Jiang, N. ; Wang, J. ; He, Z. J. ; Yang, X. ; Wang, Y. F. ; Zhao, D. ; Wang, Y. P. ; Zhang, S. ; Li, G. F. ; Huang, F. H . Robust ionic gel elastomers derived from molecularly entangled nodes . Angew. Chem. Int. Ed ., 2025 , 64 ( 32 ), e202506559 .

Lai, X. L. ; Han, X. K. ; Liu, G. T. ; Guo, S. Y . A tough PVA ionogel with high damage tolerance, impact resistance, and sensitivity for advanced flexible armor . Chem. Eng. J ., 2026 , 527 , 172040 .

Liu, Y. S. ; Li, Y. J. ; Zuo, F. Z. ; Gao, Z. Y. ; Song, H. Z . Doubly reversible thermochromic and thermoresponsive photoluminescent ionogels with high stretchability, low hysteresis, and excellent thermomechanical stability . Macromolecules , 2025 , 58 ( 14 ), 7245 – 7257 .

Zhou, P. P. ; Zhan, W. Q. ; Shen, S. T. ; Zhang, H. ; Zou, Z. G. ; Lyu, X. L . Strain-stiffening, robust yet compliant ionic elastomer from highly entangled polymer networks and metal-oxygen interactions . Adv. Funct. Mater ., 2024 , 34 ( 38 ), 2402952 .

Li, W. H. ; Li, M. ; Pi, M. H. ; Shen, H. W. ; Zhu, S. L. ; Cui, W. ; Ran, R . Recyclable strong tough ionogels via the synergy of solvent-induced cross-linking and chain entanglement . Macromolecules , 2025 , 58 ( 18 ), 9819 – 9831 .

Tamate, R. ; Kamiyama, Y. ; Kojio, K . Stiff and fracture-resistant ion gels enabled by synergetic physical entanglement and hydrogen bonding . Small , 2025 , 21 ( 48 ), e09922 .

Ando, S. ; Ito, K . Recent progress and future perspective in slide-ring based polymeric materials . Macromolecules , 2025 , 58 ( 5 ), 2157 – 2177 .

Deng, X. T. ; Chen, J. ; Jia, X. ; Da, X. Y. ; Zhao, Y. J. ; Gao, Y. Y. ; Gao, Y. ; Kong, X. P. ; Ding, S. J. ; Gao, G. X . Highly tough slide-crosslinked gel polymer electrolyte for stable lithium metal batteries . Angew. Chem. Int. Ed ., 2024 , e202410818 .

Zhu, H. R. ; Zeng, X. Y. ; Liu, X. W. ; Zhu, J. X. ; Hua, J. H. ; Lan, J. L. ; Yu, Y. H. ; Yang, X. P . Slide-crosslinked polyrotaxane topological networks: quasi-solid electrolyte for high-voltage lithium metal batteries . Adv. Sci ., 2025 , 12 ( 39 ), e08598 .

Du, R. C. ; Gao, J. ; Zhang, Z. K. ; Kong, D. S. ; Li, Z. P. ; Song, M. L. ; Zhu, H. S. ; Jin, X. X. ; Sun, X. C. ; Cao, Y. ; Hu, J. L. ; Zhang, Q. H. ; Jia, X. D . Friction modulation via ring-size engineering of polyrotaxanes for synergistically tough and low-hysteresis ionogels . Macromolecules , 2026 , 59 ( 4 ), 2179 – 2192 .

Enoki, T. ; Hashimoto, K. ; Oda, T. ; Ito, K. ; Mayumi, K . Tough and durable slide-ring ion gels for stretchable electronics leveraging strain-induced crystallization of poly(ethylene glycol) . Macromolecules , 2024 , 57 ( 24 ), 11498 – 11506 .

Yan, S. S. ; Liu, J. J. ; He, Z. N. ; Jia, H. ; Chen, Z. H. ; Zhang, Y. H. ; Gohy, J. F . High-performance ionogels from dynamic polyrotaxane-based networks . Angew. Chem. Int. Ed ., 2025 , 64 ( 20 ), e202503307 .

Du, R. C. ; Bao, T. W. ; Zhu, T. S. ; Zhang, J. ; Huang, X. X. ; Jin, Q. ; Xin, M. ; Pan, L. J. ; Zhang, Q. H. ; Jia, X. D . A low-hysteresis and highly stretchable ionogel enabled by well dispersed slidable cross-linker for rapid human-machine interaction . Adv. Funct. Mater ., 2023 , 33 ( 30 ), 2212888 .

Guo, Y. Y. ; Liu, Y. F. ; Yuan, C. L. ; Champness, N. R. ; Wang, J. C. ; Yang, L. X . Unraveling positive deformation rate-elongation relationships in tough and highly stretchable ionogels under rapid deformation . Nat. Commun ., 2026 , 17 , 340 .

Li, H. L. ; Xu, F. C. ; Lin, X. R. ; Li, Y . Self-healing ionogel with unprecedented high gel-sol transition temperature enables self-healing zinc-air battery operation at 100 ℃ . Adv. Funct. Mater ., 2026 , 36 ( 3 ), e13459 .

Li, X. ; Zhang, Y. N. ; Zhang, Y. T. ; Lin, W. T. ; Lu, H. B. ; Ji, K. M. ; Chen, M. M . Gel electrolyte self-healing via dynamic reversible bonds for stable lithium plating/stripping in lithium metal batteries . ACS Appl. Mater. Interfaces , 2026 , 18 ( 5 ), 8152 – 8164 .

Ge, G. ; Mandal, K. ; Haghniaz, R. ; Li, M. C. ; Xiao, X. ; Carlson, L. ; Jucaud, V. ; Dokmeci, M. R. ; Ho, G. W. ; Khademhosseini, A . Deep eutectic solvents-based ionogels with ultrafast gelation and high adhesion in harsh environments . Adv. Funct. Mater ., 2023 , 33 ( 9 ), 2207388 .

Xu, F. C. ; Li, H. L. ; Li, Y . Sea cucumber-inspired polyurethane demonstrating record-breaking mechanical properties in room-temperature self-healing ionogels . Adv. Mater ., 2024 , 36 ( 44 ), 2412317 .

Zhen, W. C. ; Lu, C. S. ; Li, D. ; Meng, G. F. ; Wang, H. Q. ; Jiang, Y. F. ; Lou, J. ; Han, W. J . Cation-anchoring-induced efficient n-type thermo-electric ionogel with ultra-high thermopower . Adv. Sci ., 2025 , 12 ( 19 ), 2414389 .

Xu, S. J. ; Wu, S. J. ; Zhu, R. T. ; Qiu, Z. M. ; Yan, Y . R. Fully physically crosslinked PNIPAM ionogels with high mechanical properties and temperature-managed adhesion achieved by H 2 O/ionic liquid binary solvents . Adv. Funct. Mater ., 2024 , 34 ( 41 ), 2405965 .

Zhang, H. ; Jia, W. B. ; Sun, M. Z. ; Chen, Y. X. ; Zhang, X. Y. ; Li, H. ; He, X. D. ; Shi, P. ; Xu, L. Z . High-strength and fracture-resistant ionogels via solvent-tailored interphase cohesion in nanofibrous composite networks . Sci. Adv ., 2025 , 11 ( 47 ), eaea6883 .

Du, Z. H. ; Shen, S. T. ; Su, X. Z. ; Zhuang, Y. H. ; Chen, M. X. ; Zhang, X. Y. ; Lin, Z. Q. ; Yu, L. ; Zhou, P. P. ; Wu, M. M. ; Lyu, X. L. ; Zou, Z. G . A robust and tough composite hydrogel electrolyte with anion-locked supramolecular network for zinc ion batteries . Adv. Mater ., 2025 , 37 ( 24 ), 2502328 .

Sun, L. J. ; Huang, H. F. ; Zhang, L. Z. ; Neisiany, R. E. ; Ma, X. P. ; Tan, H. ; You, Z. W . Spider-silk-inspired tough, self-healing, and melt-spinnable ionogels . Adv. Sci ., 2024 , 11 ( 3 ), 2305697 .

Shen, S. T. ; Du, Z. H. ; Zhou, P. P. ; Zou, Z. G. ; Lyu, X. L . A mechanically robust, damping, and high-temperature tolerant ion-conductive elastomer for noise-free flexible electronics . Adv. Funct. Mater ., 2024 , 34 ( 46 ), 2408017 .

Ho, D. H. ; Kim, Y. M. ; Kim, U. J. ; Yu, K. S. ; Kwon, J. H. ; Moon, H. C. ; Cho, J. H . Zwitterionic polymer gel-based fully self-healable ionic thermoelectric generators with pressure-activated electrodes . Adv. Energy Mater ., 2023 , 13 ( 32 ), 2370134 .

Lyu, X. L. ; Zhang, H. Q. ; Yang, S. C. ; Zhan, W. Q. ; Wu, M. M. ; Yu, Y. ; Shen, Z. H. ; Zou, Z. G . Strain-stiffening ionogel with high-temperature tolerance via the synergy of ionic clusters and hydrogen bonds . ACS Appl. Mater. Interfaces , 2023 , 15 ( 26 ), 31888 – 31898 .

Yu, L. ; Huang, C. Z. ; Gong, Y. ; Zheng, S. X. ; Zhou, P. P. ; Zhang, X. ; Zou, Z. G. ; Lyu, X. L . Ultrastretchable and tough poly(ionic liquid) elastomer with strain-stiffening ability enabled by strong/weak ionic interactions . Macromolecules , 2024 , 57 ( 5 ), 2339 – 2350 .

Liu, Z. Y. ; Wang, X. W. ; Duan, M. Z. ; Wu, M. ; Li, Q. N. ; Xiong, J. F. ; Wang, X. L. ; Li, W. Z. ; Yan, F . High-modulus and high-damping ionic polymers enabled by cohesive entanglement . Adv. Mater ., 2026 , 38 ( 13 ), e17751 .

Zhang, C. Y. ; Shi, X. L. ; Chao, X. J. ; Wang, M. X. ; Chen, W. Y. ; Liu, Q. ; Cao, T. Y. ; Hu, B. X. ; Sun, S. ; Chen, Z. G . Ionic coordination and hierarchical architecture enable record n-type thermoelectric efficiency in soft hydrogels . Angew. Chem. Int. Ed ., 2026 , 65 ( 18 ), e4172130 .

Hong, S. H. ; Kim, Y. M. ; Moon, H. C . Dynamic metal-ligand coordination-assisted ionogels for deformable alternating current electroluminescent devices . ACS Appl. Mater. Interfaces , 2023 , 15 ( 23 ), 28516 – 28523 .

Huang, H. F. ; Sun, L. J. ; Zhang, Y. L. ; Zhang, R. H. ; Chen, C. ; Sun, W . Ionogels reinforced by ionophobic coordination . Adv. Mater ., 2025 , 37 ( 34 ), 2506563 .

Wu, J. T. ; Huang, L. ; Wang, S. P. ; Li, X. R. ; Wen, L. ; Li, X. M. ; Feng, T. T. ; Li, P. Y. ; Fang, Z. X. ; Wu, M. Q. ; Lv, W . Ionogel electrolyte with dynamic metal-ligand interactions enabled self-healable supercapacitor with high energy density . Energy Storage Mater ., 2023 , 57 , 549 – 556 .

Xia, Q. M. ; Li, W. Z. ; Zou, X. Y. ; Zheng, S. J. ; Liu, Z. Y. ; Li, L. L. ; Yan, F . Metal-organic framework (MOF) facilitated highly stretchable and fatigue-resistant ionogels for recyclable sensors . Mater. Horiz ., 2022 , 9 ( 11 ), 2881 – 2892 .

Zhang, Y. X. ; Li, K. X. ; Tang, J. ; Bai, Y. Y. ; Chen, Y. M. ; Lv, J. ; Zrínyi, M . Multiscale interfacial designed ionogel/leather ionic skin for multimodal sensing capability . Adv. Funct. Mater ., 2025 , 35 ( 40 ), 2500640 .

Kwon, J. H. ; Hong, S. H. ; Lee, G. R. ; Kim, J. C. ; Moon, H. C . Synergistic dual-cross-linking gelation: exploring the impact of metal-ligand complexation on ionogel performance . ACS Appl. Mater. Interfaces , 2024 , 16 ( 44 ), 61115 – 61122 .

Zhao, W. ; Zheng, Y. W. ; Jiang, M. ; Sun, T. T. ; Huang, A. B. ; Wang, L. J. ; Jiang, W. ; Zhang, Q. H . Exceptional n-type thermoelectric ionogels enabled by metal coordination and ion-selective association . Sci. Adv ., 2023 , 9 ( 43 ), eadk2098 .

Liu, P. ; Pei, D. F. ; Wu, Y. P. ; Li, M. J. ; Zhao, X. H. ; Li, C. X . Dynamic and mechanically robust and ultrafast healable ionogel for nerve fiber-inspired signal transmitter . J. Mater. Chem. A , 2022 , 10 ( 48 ), 25602 – 25610 .

Lv, H. Y. ; Wang, Z. E. ; Gao, Z. Y. ; Song, H. Z . Highly stretchable, self-healable, and environment-adaptable ionogel-based high-output triboelectric nanogenerator for self-powered wearable ionotronics . Chem. Eng. J ., 2025 , 509 , 161247 .

Sun, Y. D. ; Hu, Z. P. ; Tang, A. Y. ; Zhang, S. F. ; Niu, W. B . Bioinspired waterproof and self-healing photonic-ionic skin for underwater interactive sensing . Chem. Eng. J ., 2024 , 497 , 154495 .

Yang, L. ; Sun, L. J. ; Huang, H. F. ; Zhu, W. F. ; Wang, Y. H. ; Wu, Z. K. ; Neisiany, R. E. ; Gu, S. J. ; You, Z. W . Mechanically robust and room temperature self-healing ionogel based on ionic liquid inhibited reversible reaction of disulfide bonds . Adv. Sci ., 2023 , 10 ( 20 ), 2207527 .

Zhang, Z. P. ; Qian, L. ; Zhang, B. ; Ma, C. F. ; Zhang, G. Z . Jellyfish-inspired polyurea ionogel with mechanical robustness, self-healing, and fluorescence enabled by hyperbranched cluster aggregates . Angew. Chem. Int. Ed ., 2024 , 63 ( 40 ), e202410335 .

Zhang, Z. Y. ; Zhao, X. ; Song, X. ; Peng, D. J. ; Ren, S. X. ; Ren, J. X. ; Ma, Y. L. ; Li, S. J . Versatile ionic liquid gels formed by dynamic covalent bonding and microphase separated structures . Mater. Horiz ., 2024 , 11 ( 17 ), 4171 – 4182 .

Fu, Y. H. ; Chen, L. Y. ; Xu, F. C. ; Li, X. ; Li, Y. ; Sun, J. Q . Spontaneous self-healing ionogels for efficient and reliable carbon dioxide separation . J. Mater. Chem. A , 2022 , 10 ( 9 ), 4695 – 4702 .

Tan, H. ; Sun, L. J. ; Huang, H. F. ; Zhang, L. Z. ; Neisiany, R. E. ; Ma, X. P. ; You, Z. W . Continuous melt spinning of adaptable covalently cross-linked self-healing ionogel fibers for multi-functional ionotronics . Adv. Mater ., 2024 , 36 ( 13 ), 2310020 .

Adjaoud, A. ; Puchot, L. ; Shaplov, A. S. ; Verge, P . A flexible and recyclable polybenzoxazine vitrimer ionogel . Chem. Mater ., 2025 , 37 ( 20 ), 8345 – 8355 .

Fan, X. T. ; Luo, Y. F. ; Li, K. ; Wong, Y. J. ; Wang, C. ; Yeo, J. C. C. ; Yang, G. L. ; Li, J. F. ; Loh, X. J. ; Li, Z. B. ; Chen, X. D . A recyclable ionogel with high mechanical robustness based on covalent adaptable networks . Adv. Mater ., 2024 , 36 ( 44 ), 2407398 .

Huang, H. F. ; Sun, W. ; Sun, L. J. ; Zhang, L. Z. ; Wang, Y. ; Zhang, Y. W. ; Gu, S. J. ; You, Z. W. ; Zhu, M. F . Internal catalysis significantly promotes the bond exchange of covalent adaptable polyurethane networks . Proc. Natl. Acad. Sci. U . S . A ., 2024 , 121 ( 34 ), e2404726121 .

Li, Q. N. ; Zheng, S. J. ; Liu, Z. Y. ; Li, W. Z. ; Wang, X. W. ; Cao, Q. ; Yan, F . Strong, spontaneous, and self-healing poly(ionic liquid) elastomer underwater adhesive with borate ester dynamic crosslinking . Adv. Mater ., 2024 , 36 ( 50 ), 2413901 .

Yan, X. R. ; Zhao, R. R. ; Lin, H. J. ; Zhao, Z. D. ; Song, S. S. ; Wang, Y. F . Nucleobase-driven wearable ionogel electronics for long-term human motion detection and electrophysiological signal monitoring . Adv. Funct. Mater ., 2025 , 35 ( 2 ), 2412244 .

Ye, Z. W. ; Yu, H. M. ; Xie, H. X. ; Zhu, W. W. ; Shi, S. T. ; Liu, C. C. ; Wang, Y. Y. ; Liao, J. Q. ; Sun, Q. F. ; Zhao, D. W. ; Shen, X. P . Flame-retardant ionogel enabled by lignin molecular networks for fire rescue . Adv. Sci ., 2025 , 12 ( 35 ), e06901 .

Yu, X. H. ; Teng, C. P. ; Yeo, J. C. C. ; Fan, X. T. ; Fan, X. S. ; Liu, T. X. ; Li, Z. B . Multifunctional recyclable electronic skins enabled by hierarchical dynamic network structures . Adv. Funct. Mater ., 2025 , 35 ( 33 ), 2501677 .

Chen, Z. J. ; Sun, Y. Q. ; Xiao, X. ; Wang, H. Q. ; Zhang, M. H. ; Wang, F. Z. ; Lai, J. C. ; Zhang, D. S. ; Pan, L. J. ; Li, C. H . An ultra-tough and ultra-sensitive ionogel pressure/temperature sensor enabled by hierarchical design of both materials and devices . J. Mater. Chem. A , 2023 , 11 ( 15 ), 8359 – 8367 .

Xiao, J. ; Zhu, T. Y. ; Zhang, H. Y. ; Xie, W. ; Dong, R. H. ; Li, Y. T. ; Wang, X . Healable, recyclable, and upcyclable gel membranes for efficient carbon dioxide separation . Angew. Chem. Int. Ed ., 2024 , 63 ( 43 ), e202411270 .

Xu, Y. Q. ; Jing, X. ; Feng, P. Y. ; Antwi-Afari, M. F. ; Liu, Y. J. ; Liu, F. X. ; Li, S. T. ; Mi, H. Y . Breathable, nanonet-reinforced ultrathin ionogel film via hydrogen bonding-ion dipole synergy for multifunctional wearable sensors . Adv. Funct. Mater ., 2026 , 36 ( 10 ), e17882 .

Kou, Z. M. ; Sha, Y. ; Hu, L. H. ; Liu, M. T. ; Huang, F. C. ; Wang, J. ; Bo, C. Y. ; Zhou, Y. H. ; Zhao, D. W. ; Jia, P. Y . Supramolecular-engineered bamboo lignin polymer with enhanced mechanical and electrical properties for flexible electronics . Adv. Sci ., 2025 , 12 ( 43 ), e12983 .

Padhan, A. K. ; Sharma, D. ; Thomas, T. S. ; Sinha, A. P. ; Mallick, A. N. ; Mandal, D . Rapid self-healing and superior toughness in ionically crosslinked polymer ionogels and strain sensing applications . J. Mater. Chem. A , 2024 , 12 ( 16 ), 9508 – 9517 .

Pi, M. H. ; Wu, H. L. ; Li, W. H. ; Shen, H. W. ; Li, M. ; Cui, W. ; Ran, R . Facile preparation of polymerizable deep eutectic solvents under mild conditions for multisensory ionic skins . Small , 2025 , 21 ( 4 ), 2409754 .

Chen, Q. F. ; Cheng, B. B. ; Wang, Z. Q. ; Sun, X. H. ; Liu, Y. ; Sun, H. D. ; Li, J. W. ; Chen, L. H. ; Zhu, X. H. ; Huang, L. L. ; Ni, Y. H. ; An, M. ; Li, J. G . Rarely negative-thermovoltage cellulose ionogel with simultaneously boosted mechanical strength and ionic conductivity via ion-molecular engineering . J. Mater. Chem. A , 2023 , 11 ( 5 ), 2145 – 2154 .

Huang, J. Q. ; Hu, Y. ; Gao, Q. W. ; She, Y. P. ; Li, J. J. ; Hu, H. M. ; Zheng, H. Y. ; Yan, F. ; Ji, X. Y . Multiple-crosslinking-reinforced ionogel electrolytes for safe and high-performance quasi-solid-state lithium metal batteries . J. Mater. Chem. A , 2025 , 13 ( 47 ), 41019 – 41029 .

Jia, L. Y. ; Xiao, J. ; Tan, Y. ; Zhang, K. Q. ; Liu, Y. Q. ; Wang, X . Supramolecular ionogels for use in locating damage to underwater infrastructure . Small , 2024 , 20 ( 19 ), 2309231 .

Li, L. L. ; Li, W. Z. ; Wang, X. L. ; Zou, X. Y. ; Zheng, S. J. ; Liu, Z. Y. ; Li, Q. N. ; Xia, Q. M. ; Yan, F . Ultra-tough and recyclable ionogels constructed by coordinated supramolecular solvents . Angew. Chem. Int. Ed ., 2022 , 61 ( 50 ), e202212512 .

Wang, Y. C. ; Li, S. ; Han, J. Y. ; Yin, K. Y. ; Chen, W. Z. ; Zhou, W. ; Zhang, T. ; Xiao, P. ; Chen, T . Supramolecular coupling effect enhanced highly transparent, conductive ionic skin for underwater sensory and interactive robotics . Adv. Mater ., 2026 , 38 ( 9 ), e18076 .

Zhou, Q. ; Zhou, S. ; Puglia, D. ; Zhang, X. J. ; Xu, P. W. ; Niu, D. Y. ; Yang, W. J. ; Ma, P. M . Ultrastretchable and recyclable ionogels with hierarchical dynamic bonds for respiratory monitoring . Adv. Funct. Mater ., 2026 , 36 ( 2 ), e12398 .

Chen, H. M. ; Huang, C. Y. ; Lu, K. ; Gao, Y. Z. ; Yan, J. L. ; Wang, Z . Confinement-locking strategy enables ionogels with remarkable mechanical robustness and fatigue resistance . Adv. Mater ., 2026 , 38 ( 10 ), e20126 .

Demarthe, N. ; O’dell, L. A. ; Humbert, B. ; Arrua, R. D. ; Evans, D. ; Brousse, T. ; Le Bideau, J . Enhanced Li + and Mg 2+ diffusion at the polymer-ionic liquid interface within PVDF-based ionogel electrolytes for batteries and metal-ion capacitors . Adv. Energy Mater ., 2024 , 14 ( 18 ), 2304342 .

Hyun, W. J. ; Thomas, C. M. ; Chaney, L. E. ; Mazarin de Moraes, A. C. ; Hersam, M. C . Screen-printable hexagonal boron nitride ionogel electrolytes for mechanically deformable solid-state lithium-ion batteries . Nano Lett ., 2022 , 22 ( 13 ), 5372 – 5378 .

Wang, X. L. ; Jin, Y. F. ; Fu, H. ; Zhang, L. J. ; Lee, P. C. ; An, C. J . Self-healing and stretchable tetrameric PVA-CNF-PVP-IL complex ionogel with high-performance ionic thermoelectric properties . J. Mater. Chem. A , 2025 , 13 ( 22 ), 16948 – 16957 .

Huang, Y. Y. ; Ming, X. Q. ; Tang, Z. ; Chen, G. Q. ; Duan, X. Z. ; Zhu, H. ; Zhu, S. P. ; Zhang, Q . Ultra-strong ionogel adhesives via in situ microphase separation . Adv. Funct. Mater ., 2025 , 35 ( 11 ), 2417011 .

Tie, J. F. ; Mao, Z. P. ; Zhang, L. P. ; Zhong, Y. ; Xu, H . Strong and ultratough ionogel enabled by ingenious combined ionic liquids induced microphase separation . Adv. Funct. Mater ., 2023 , 33 ( 52 ), 2307367 .

Li, F. Y. ; Wu, K. F. ; Zhang, X. ; Fu, Y. M. ; Sun, T. L. ; Guo, H. L. ; Wang, X. L. ; Guo, H. ; Meng, Y. Z . “Frozen” ionogels with high and tunable toughness for soft electronics . Small , 2025 , 21 ( 11 ), 2500477 .

Li, X. ; Yang, X. M. ; Li, S. J. ; Lv, H. Y. ; Wang, Z. E. ; Gao, Z. Y. ; Song, H. Z . 3D printing of thermo-mechano-responsive photoluminescent noncovalent cross-linked ionogels with high-stretchability and ultralow-hysteresis for wearable ionotronics and anti-counterfeiting . Small , 2024 , 20 ( 43 ), 2403252 .

Lv, D. ; Li, X. ; Huang, X. ; Cao, C. Y. ; Ai, L. Q. ; Wang, X. J. ; Ravi, S. K. ; Yao, X . Microphase-separated elastic and ultrastretchable ionogel for reliable ionic skin with multimodal sensation . Adv. Mater ., 2024 , 36 ( 17 ), 2309821 .

Zeng, G. ; Gao, W. S. ; Qiu, W. C. ; Li, G. L. ; Chen, S. S. ; He, X. ; Sun, G. X. ; Yang, W. J. ; Xin, Y . Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape-memory properties for wearable electrical devices . J. Mater. Chem. A , 2024 , 12 ( 44 ), 30618 – 30628 .

He, X. N. ; Zhang, B. ; Liu, Q. J. ; Chen, H. ; Cheng, J. X. ; Jian, B. C. ; Yin, H. L. ; Li, H. G. ; Duan, K. ; Zhang, J. W. ; Ge, Q . Highly conductive and stretchable nanostructured ionogels for 3D printing capacitive sensors with superior performance . Nat. Commun ., 2024 , 15 , 6431 .

Xu, J. ; Wu, B. H. ; Hou, L. ; Wu, P. Y . Hydrogen bonding competition mediated phase separation with abnormal moisture-induced stiffness boosting . Small , 2024 , 20 ( 36 ), 2401164 .

Zhang, J. X. ; Yin, J. J. ; Li, N. ; Liu, H. ; Wu, Z. H. ; Liu, Y. ; Jiao, T. F. ; Qin, Z. H . Simultaneously enhancing the mechanical strength and ionic conductivity of stretchable ionogels enabled by polymerization-induced phase separation . Macromolecules , 2022 , 55 ( 24 ), 10950 – 10959 .

Zhang, M. W. ; Yu, R. ; Tao, X. L. ; He, Y. Y. ; Li, X. P. ; Tian, F. ; Chen, X. Y. ; Huang, W . Mechanically robust and highly conductive ionogels for soft ionotronics . Adv. Funct. Mater ., 2023 , 33 ( 10 ), 2208083 .

Cong, Z. H. ; Cui, Z. Y. ; Liu, C. ; Wang, J. L. ; Huo, X. S. ; Xu, J. B. ; Niu, J . High strength and tough ionogels with bicontinuous phase network structure induced by electrostatic adsorption triggered microphase separation . Adv. Funct. Mater ., 2024 , 34 ( 52 ), 2410588 .

Shi, J. L. ; Xie, S. ; Liu, Z. G. ; Cai, M. K. ; Guo, C. F . Non-hygroscopic ionogel-based humidity-insensitive iontronic sensor arrays for intra-articular pressure sensing . Natl. Sci. Rev ., 2024 , 11 ( 11 ), nwae351 .

Zeng, L. S. ; Liu, F. K. ; Yu, Q. F. ; Jin, C. Y. ; Yang, J. ; Suo, Z. G. ; Tang, J. D . Flaw-insensitive fatigue resistance of chemically fixed collagenous soft tissues . Sci. Adv ., 2023 , 9 ( 9 ), eade7375 .

Lee, L. C. ; Hong, S. H. ; Kim, M. S. ; Jeng, U. S. ; Wang, C. H. ; Tung, S. H. ; Lee, K. H. ; Liu, C. L . Enhanced thermoelectric performance of PVA-based ionogels: tailoring crystallinity via additives for advanced waste heat recovery . ACS Appl. Mater. Interfaces , 2025 , 17 ( 26 ), 38545 – 38557 .

Zhan, W. Q. ; Zhang, H. Q. ; Lyu, X. ; Luo, Z. Z. ; Yu, Y. ; Zou, Z. G . An ultra-tough and super-stretchable ionogel with multi functions towards flexible iontronics . Sci. China Mater ., 2023 , 66 ( 4 ), 1539 – 1550 .

Li, N. ; He, P. ; Qin, Z. H. ; Yan, Y. C. ; Duan, S. D. ; Li, Y. F. ; Shi, X. J. ; Qiao, Y. X. ; Jiang, J. N. ; Jiao, T. F. ; He, X. M . Rapid self-assembly of robust ultrathin ionogel films for high-performance bioelectronics . Sci. Adv ., 2026 , 12 ( 9 ), eaeb4391 .

Li, X. ; Jiang, H. B. ; Zhang, Y. ; Long, Q. ; Jiang, G. Y. ; Zeng, S. Q. ; Zhou, J. F. ; Zhao, D. W . Stimulation-reinforced cellulose-protein ionogels with superior mechanical strength and temperature resistance . Adv. Funct. Mater ., 2024 , 34 ( 48 ), 2408160 .

Wang, J. Y. ; Zhang, S. L. ; Li, L. L. ; Wang, X. L. ; Xiong, J. F. ; Li, Q. N. ; Li, W. Z. ; Yan, F . Glassy ionogels with high compressibility and strength for impact protection . Proc. Natl. Acad. Sci. U . S . A ., 2025 , 122 ( 15 ), e2417978122 .

Li, X. N. ; Tong, Z. H. ; Qiu, Y. X. ; Zheng, Z. H. ; Zeng, S. Q. ; Zhao, D. W. ; Yu, H. P . Balancing mechanical-thermal-electrical properties in cellulose ionogels via crystallization-induced molecular assembly . Nat. Commun ., 2025 , 16 , 9970 .

Zheng, Y. ; Dong, Z. K. ; Luo, S. C. ; Jin, Q. ; Tao, S. L. ; Ding, Y. C. ; Li, T. ; Wang, X. L. ; Zhou, D. S. ; Chen, S. J . Cocrystal effect-driven ultrafast phase-transition ionogel for dynamically switchable adhesion interfaces . Nat. Commun ., 2025 , 16 , 8792 .

Zheng, Y. ; Dong, Z. K. ; Wu, M. ; Duan, M. Z. ; Yin, S. B. ; Jin, Q. ; Chen, S. J. ; Wang, X. L. ; Zhou, D. S . Programmable adhesive ionogels dominated by temperature-triggered reversible side-chain crystallization . Chem. Eng. J ., 2024 , 498 , 155513 .

Wang, S. H. ; Liu, H. Y. ; Yu, Z. Y. ; Ren, X. L. ; Hua, Q. ; Panahi-Sarmad, M. ; Yang, P. ; Liu, C. H. ; Renneckar, S. ; Liu, H. ; Jiang, F . Cellulose-mediated ionic liquid crystallization enables tough-stiff switchable ionogels . Nat. Commun ., 2025 , 16 , 9007 .

Zhu, J. J. ; Gao, H. W. ; Zheng, Z. F. ; Cao, Y. Z. ; Wang, T. Y. ; Kumar Kankala, R. ; Wu, L. X. ; Chen, A. Z. ; Wang, S. B. ; Li, Y. W . Photocuring 3D printable flexible strain sensor enhanced by in situ grown silk fibroin nanoparticles . Chem. Eng. J ., 2024 , 497 , 154762 .

Li, H. L. ; Xu, F. C. ; Guan, T. T. ; Li, Y. ; Sun, J. Q . Mechanically and environmentally stable triboelectric nanogenerator based on high-strength and anti-compression self-healing ionogel . Nano Energy , 2021 , 90 , 106645 .

Luo, X. J. ; Li, J. M. ; Gu, Y. X. ; Du, J. ; Huang, Y. J. ; Baskin, I. ; Ein-Eli, Y. ; Hyun, W. J . Talc nanosheet ionogel electrolytes with high lithium-ion conductivity for solid-state lithium metal batteries . Nano Lett ., 2025 , 25 ( 9 ), 3430 – 3437 .

Sun, S. ; Shi, X. L. ; Lyu, W. ; Hong, M. ; Chen, W. Y. ; Li, M. ; Cao, T. Y. ; Hu, B. X. ; Liu, Q. F. ; Chen, Z. G . Stable, self-adhesive, and high-performance graphene-oxide-modified flexible ionogel thermoelectric films . Adv. Funct. Mater ., 2024 , 34 ( 39 ), 2402823 .

Li, X. ; Lv, D. ; Ai, L. Q. ; Wang, X. J. ; Xu, X. B. ; Qiang, M. Y. ; Huang, G. S. ; Yao, X . Superstrong ionogel enabled by coacervation-induced nanofibril assembly for sustainable moisture energy harvesting . ACS Nano , 2024 , 18 ( 20 ), 12970 – 12980 .

Liu, S. Y. ; Wu, Y. Z. ; Jiang, L. ; Xie, W. R. ; Davis, B. ; Wang, M. X. ; Zhang, L. ; Liu, Y. H. ; Xing, S. C. ; Dickey, M. D. ; Bai, W. B . Highly stretchable, tissue-like Ag nanowire-enhanced ionogel nanocomposites as an ionogel-based wearable sensor for body motion monitoring . ACS Appl. Mater. Interfaces , 2024 , 16 ( 35 ), 46538 – 46547 .

Wang, Y. Q. ; Liu, Z. Q. ; Liu, Y. T. ; Su, W. W. ; Wang, L. ; Huang, X. W. ; Gao, J. F . Anti-fatigue ionogels for high-performance strain sensing . Chem. Eng. J ., 2025 , 522 , 167313 .

Tong, Z. H. ; Liu, S. ; Tang, H. Y. ; Liu, J. N. ; Bi, W. J. ; Liu, Y. ; Zeng, S. Q. ; Xia, Q. Q. ; Zhao, D. W. ; Yu, H. P . Super-robust cellulose rayon filaments engineered via molecular orientation-cross-linking assembly . Nano Lett ., 2025 , 25 ( 39 ), 14489 – 14496 .

Zhang, Z. T. ; Sang, M. ; Li, Z. M. ; Pan, Y. C. ; Wu, J. P. ; Duan, S. L. ; Gong, X. L . In-situ localised alignment assisted salting-out enhanced ionogels with high strength, toughness and impact resistance . Nat. Commun ., 2025 , 16 , 7683 .

Xing, D. D. ; Li, W. Z. ; Yu, H. ; Wang, Z. H. ; Li, L. G. ; Cui, Y. H. ; Zheng, J. M. ; Zhou, Y. J. ; Yan, F . Ionic liquid-inspired highly aligned fibrous ionogel for boosted thermoelectric harvesting . ACS Appl. Mater. Interfaces , 2025 , 17 ( 18 ), 27049 – 27060 .

Ren, Y. Y. ; Liu, Z. Y. ; Jin, G. Q. ; Yang, M. K. ; Shao, Y. Z. ; Li, W. Z. ; Wu, Y. Q. ; Liu, L. L. ; Yan, F . Electric-field-induced gradient ionogels for highly sensitive, broad-range-response, and freeze/heat-resistant ionic fingers . Adv. Mater ., 2021 , 33 ( 12 ), 2008486 .

Zhou, S. ; Li, T. T. ; Li, J. ; Xu, M. D. ; Xu, R. Y. ; Yan, S. Z. ; Quan, Y. ; Ma, T. J. ; Jiang, X. S . Ionogel surface patterns fabricated by photodimerization-induced self-organized spatial reconstruction . J. Mater. Chem. C , 2025 , 13 ( 24 ), 12127 – 12135 .

Xu, M. ; Shen, X. C. ; Li, S. J. ; Zhu, H. N. ; Cheng, Y. ; Lv, H. Y. ; Wang, Z. E. ; Lou, C. G. ; Song, H. Z . Skin-inspired gradient ionogels induced by electric field for ultrasensitive and ultrafast-responsive multifunctional ionotronics . J. Mater. Chem. A , 2024 , 12 ( 2 ), 1036 – 1046 .

Li, X. C. ; Sun, F . An ultrastretchable gradient ionogel induced by a self-floating strategy for strain sensing . ACS Appl. Mater. Interfaces , 2023 , 15 ( 31 ), 37717 – 37727 .

Hao, S. ; Chen, Z. Y. ; Li, H. Z. ; Yuan, J. ; Chen, X. H. ; Sidorenko, A. ; Huang, J. ; Gu, Y. L . Skin-inspired, highly sensitive, broad-range-response and ultra-strong gradient ionogels prepared by electron beam irradiation . Small , 2024 , 20 ( 21 ), 2309931 .

Zhang, T. K. ; Li, Y. ; Dunn, C. B. ; Qian, J. ; Wei, Z. ; Tao, S. J. ; Xie, H. J. ; Zhang, C. ; Qiang, Z. ; Ren, J . Ultrabroad pressure sensing and highly sensitive gradient ionogel-based fluorescent flexible wearable bracelet . ACS Sens ., 2025 , 10 ( 10 ), 7412 – 7426 .

Li, S. M. ; Hong, H. ; Li, D. D. ; Yang, X. R. ; Wang, S. X. ; Zhang, D. C. ; Xiong, Q. ; Huang, Z. D. ; Zhi, C. Y . Designing zwitterionic bottlebrush polymers to enable long-cycling quasi-solid-state lithium metal batteries . Angew. Chem. Int. Ed ., 2025 , 64 ( 5 ), e202409500 .

Lin, Z. Q. ; Hong, J. L. ; Huang, C. Z. ; Zhang, X. Y. ; Shen, S. T. ; Du, Z. H. ; Zhou, P. P. ; Miao, Y. B. ; Lin, Z. H. ; Lyu, X. L. ; Zou, Z. G . A strong, tough, and high-efficiency hydrogel thermocell for thermal energy harvesting . Nano Energy , 2025 , 138 , 110878 .

Cui, X. C. ; Xu, Z. W. ; Xi, C. P. ; Zhang, H. Q. ; Xiao, Y. B. ; Li, L. ; Xu, G. ; Lyu, X. L. ; Lin, Q. L. ; Yu, Y. ; Yang, C. K . Constructing localized-anion gel-electrolyte with poly(ethyl acrylate/acrylic acid lithium) for flame-retardant lithium metal batteries . J. Solid State Electrochem ., 2024 , 28 ( 1 ), 273 – 281 .

Wang, Y. ; Wei, Z. X. ; Ji, T. T. ; Bai, R. B. ; Zhu, H. L . Highly ionic conductive, stretchable, and tough ionogel for flexible solid-state supercapacitor . Small , 2024 , 20 ( 20 ), 2307019 .

Wang, Y. F. ; Liu, Y. ; Plamthottam, R. ; Tebyetekerwa, M. ; Xu, J. S. ; Zhu, J. X. ; Zhang, C. ; Liu, T. X . Highly stretchable and reconfigurable ionogels with unprecedented thermoplasticity and ultrafast self-healability enabled by gradient-responsive networks . Macromolecules , 2021 , 54 ( 8 ), 3832 – 3844 .

Zhuo, S. Y. ; Song, C. ; Rong, Q. F. ; Zhao, T. Y. ; Liu, M. J . Shape and stiffness memory ionogels with programmable pressure-resistance response . Nat. Commun ., 2022 , 13 ( 1 ), 1743 .

Zhang, M. W. ; Zhao, L. Y. ; Tian, F. ; Zhao, X. J. ; Zhang, Y. ; Yang, X. ; Huang, W. ; Yu, R . Bionic artificial skin based on self-healable ionogel composites with tailored mechanics and robust interfaces . Adv. Mater ., 2024 , 36 ( 35 ), 2405776 .

Li, L. L. ; Wang, X. W. ; Gao, S. N. ; Zheng, S. J. ; Zou, X. Y. ; Xiong, J. F. ; Li, W. Z. ; Yan, F . High-toughness and high-strength solvent-free linear poly(ionic liquid) elastomers . Adv. Mater ., 2024 , 36 ( 7 ), 2308547 .

Li, S. J. ; Cheng, Y. ; Zhu, H. N. ; Xu, M. ; Lv, H. Y. ; Wang, Z. E. ; Liu, G. M. ; Song, H. Z . Strain-induced phase separation and mechanomodulation of ionic conduction in anisotropic nanocomposite ionogels . ACS Appl. Mater. Interfaces , 2024 , 16 ( 10 ), 13103 – 13113 .

Lyu, X. L. ; Zhang, H. Q. ; Shen, S. T. ; Gong, Y. ; Zhou, P. P. ; Zou, Z. G . Multi-modal sensing ionogels with tunable mechanical properties and environmental stability for aquatic and atmospheric environments . Adv. Mater ., 2024 , 36 ( 45 ), 2410572 .

Cao, L. Q. ; Sun, T. T. ; Zhao, H. R. ; Shang, M. H. ; Wang, L. J. ; Jiang, W . An actuatable ionogel thermoelectric fiber with aligned mesogens-induced thermopower for four-dimensional dynamically adaptive heat harvesting . Nat. Commun ., 2025 , 16 , 5445 .

Wu, Y. Z. ; Xing, S. C. ; Yang, D. Y. ; Liu, Y. H. ; Ding, C. ; Li, Z. F. ; Jiao, Q. Z. ; Zhang, A. R. ; Guo, Z. H. ; Liu, S. Y. ; Luo, W. ; Yuan, G. K. ; Wang, M. X. ; Wang, Y. ; Dickey, M. D. ; Bai, W. B . Soft giant magnetoimpedance electronics enable contact-free human-machine interactions . Proc. Natl. Acad. Sci. U . S . A ., 2026 , 123 ( 4 ), e2526097123 .

Shen, Z. Q. ; Zhu, X. Y. ; Majidi, C. ; Gu, G. Y . Cutaneous ionogel mechanoreceptors for soft machines, physiological sensing, and amputee prostheses . Adv. Mater ., 2021 , 33 ( 38 ), 2102069 .

Lyu, X. L. ; Yu, K. ; Zhang, H. Q. ; Zhou, P. P. ; Shen, Z. H. ; Zou, Z. G . Tough fiber-reinforced composite ionogels with crack resistance surpassing metals . Nat. Commun ., 2025 , 16 , 4005 .

Sun, L. ; Feng, W. W. ; Liu, Y. C. ; Chen, L. L. ; Chen, T. ; Jin, Z. K. ; Wang, C . Elastic and ultra stable ionic conductors for long-life-time soft robots working at extreme environments . Nat. Commun ., 2025 , 16 , 6004 .

Kang, J. H. ; Su, X. Z. ; Zhou, P. P. ; Yu, K. ; Du, Z. H. ; Shi, D. ; Yu, Y. ; Lyu, X. L. ; Zou, Z. G . Supramolecular interlocking produces mechanically anisotropic, robust, and tough biomimetic ionogels . Adv. Mater ., 2026 , 38 ( 12 ), e11903 .

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