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中国科学院大学材料科学与光电技术学院,北京 100049
*史钦钦,E-mail: shiqinqin@ucas.ac.cn;黄辉,E-mail: huihuang@ucas.ac.cn
*史钦钦,E-mail: shiqinqin@ucas.ac.cn;黄辉,E-mail: huihuang@ucas.ac.cn
纸质出版日期:2024-12-20,
网络出版日期:2024-09-02,
收稿日期:2024-06-18,
录用日期:2024-07-23
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梁新宇, 史钦钦, 黄辉. 共轭高分子的精准交替结构与光电性能研究. 高分子通报, 2024, 37(12), 1709–1721
Liang, X. Y.; Shi, Q. Q.; Huang, H. The effect of structural defects of conjugated polymers on the optoelectronic properties. Polym. Bull. (in Chinese), 2024, 37(12), 1709–1721
梁新宇, 史钦钦, 黄辉. 共轭高分子的精准交替结构与光电性能研究. 高分子通报, 2024, 37(12), 1709–1721 DOI: 10.14028/j.cnki.1003-3726.2024.24.183.
Liang, X. Y.; Shi, Q. Q.; Huang, H. The effect of structural defects of conjugated polymers on the optoelectronic properties. Polym. Bull. (in Chinese), 2024, 37(12), 1709–1721 DOI: 10.14028/j.cnki.1003-3726.2024.24.183.
高分子半导体材料具有性能易调控、可溶液加工、柔性可折叠等优点,是柔性电子的最理想材料。然而,传统合成方法造成高分子半导体材料批次差异大、单体自偶联缺陷多,因此限制了高分子半导体材料的大规模商业化应用。本文重点阐述共轭交替高分子中单体自偶联缺陷对材料光电性能的影响,旨在揭示共轭高分子精准合成的重要性,为高性能共轭聚合物材料的精准、宏量制备提供新思路,并推动其产业化应用的进程。
Semiconducting polymers
especially π-conjugated donor-acceptor (D-A) copolymers with defect-free alternating structures
are essential materials for plastic electronics and optoelectronics owing to their tunable chemical structures
tunable bandgaps and optical absorptions
excellent charge transport mobility
mechanical flexibility
and solution processability for printing. However
traditional synthesis methods may cause homocoupling structural defects
resulting in large batch variations
thus hindering the large-scale commercial application of polymer semiconductors. This study reviews the effect of homocoupling structural defects of conjugated polymers on their photoelectric properties
aiming to reveal the importance of precise synthesis on the performance of conjugated polymers. We believe this review will guide the precise and large-scale production of high-performance polymers
potentially catalyzing advancements in their industrial applications.
高分子半导体材料单体自偶联缺陷光电性能
Polymer semiconductor materialHomocoupling structural defectsOptoelectronic property
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