Research Progress of Cyclo-olefins Copolymer

Qiang XU; Yu-li GAO; Ke-feng WANG; Jian-jun YI

doi:10.14028/j.cnki.1003-3726.2019.01.008

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Research Progress of Cyclo-olefins Copolymer

The 30th Anniversary Issue I | 更新时间：2022-09-02

- Research Progress of Cyclo-olefins Copolymer
- Polymer Bulletin Vol. 32, Issue 1, Pages: 64-74(2019)
- 作者机构：
  
  中国石油石油化工研究院，北京 102206
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2019.01.008
  CLC：
- Published：20 January 2019，
  
  Received：27 September 2018，
  
  Revised：05 November 2018，
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Qiang XU, Yu-li GAO, Ke-feng WANG, Jian-jun YI. Research Progress of Cyclo-olefins Copolymer. [J]. Polymer Bulletin 32(1):64-74(2019)
DOI：

Qiang XU, Yu-li GAO, Ke-feng WANG, Jian-jun YI. Research Progress of Cyclo-olefins Copolymer. [J]. Polymer Bulletin 32(1):64-74(2019) DOI： 10.14028/j.cnki.1003-3726.2019.01.008.

摘要

本文总结了近十年来环烯烃共聚物的研究进展，着重介绍了乙烯/降冰片烯（E/NB）共聚物、丙烯／降冰片烯（P/NB）共聚物和环烯烃官能化共聚物的研究进展，比较了用于合成E/NB共聚物、P/NB共聚物的催化剂特点，包括茂金属催化剂、非茂金属催化剂、后过渡金属催化剂。通过设计催化剂结构、控制聚合条件，可以实现对共聚合活性、共聚物微观结构调控，并实现环烯烃官能化聚合物的合成。

Abstract

In this paper

the research progress of cyclo-olefins copolymer during the last decade were overviewed. Ethylene/Norbornene(E/NB) copolymers

Propylene/Norbornene (P/NB) copolymers and functionalization cyclo-olefins copolymer were highlighted. The characteristic of catalyst

included metallocene

non-metallocene and late-transition catalysts

being used in synthesis of E/NB copolymers and P/NB copolymers

were all summarized. Through the design of catalyst structure and the control of polymerization conditions

both the copolymerization activity and microstructure of the copolymers could be regulated

also

the synthesis of functionalization cyclo-olefins copolymer could be achieved.

关键词

环烯烃乙烯丙烯官能化共聚物研究进展

Keywords

Cyclo-olefinsEthylenePropyleneFunctionalizationCopolymersResearch progress

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