Xu HUAI, Yang CAO, Hua-jin WANG, Qin ZHANG, Qian DONG, Hao-ran MA, Li LIANG. Construction and Performance Study of Vacuum Visible Light Curing System Based on CQDs. [J]. Polymer Bulletin 33(11):50-55(2020)
DOI:
Xu HUAI, Yang CAO, Hua-jin WANG, Qin ZHANG, Qian DONG, Hao-ran MA, Li LIANG. Construction and Performance Study of Vacuum Visible Light Curing System Based on CQDs. [J]. Polymer Bulletin 33(11):50-55(2020) DOI: 10.14028/j.cnki.1003-3726.2020.11.006.
Construction and Performance Study of Vacuum Visible Light Curing System Based on CQDs
Carbon quantum dots (CQDs) with good blue fluorescence properties were prepared by hydrothermal method and combined with acrylic resin. Then under vacuum conditions
a visible light curing system was constructed to prepare CQDs composite films. Next
the structure and fluorescence properties of CQDs
the morphology
structure
water and solvent resistance of CQDs composite membranes were studied by using Fourier transform infrared spectrometer
dark box three-purpose ultraviolet analyzer
scanning electron microscope
thermogravimetric analyzer
video contact angle measuring instrument and relevant test. The results show that the CQDs with blue fluorescence are prepared. When 0.6g CQDs is added
a dense CQDs composite membrane is obtained. The composite membrane has a water absorption rate of 0.24%
a contact angle of 110.13°
good thermal stability below 150℃
good solvent resistance
and good hydrophobic effect. Finally
the curing mechanism was discussed. It is believed that carbon quantum dots have up-conversion properties
which can convert visible light in the low-energy band into ultraviolet light in the high-energy band
which in turn excites photoinitiators to generate free radicals to initiate polymerization. The curing formula and vacuum visible light curing process in this paper have high application potential and value in industry.