The Synthesis of Functionalized Polyolefin Materials and Research on Material Properties

Min CHEN; Chang-le CHEN

doi:10.14028/j.cnki.1003-3726.2021.06.003

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The Synthesis of Functionalized Polyolefin Materials and Research on Material Properties

Special Issue: In Celebration of the 80th Birthday of Professor HU You-liang | 更新时间：2022-08-30

- The Synthesis of Functionalized Polyolefin Materials and Research on Material Properties
- Polymer Bulletin Vol. 34, Issue 6, Pages: 26-34(2021)
- 作者机构：
  
  中国科学技术大学高分子科学与工程系,合肥 230026
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2021.06.003
  CLC：
- Published：20 June 2021，
  
  Received：15 January 2021，
  
  Revised：18 February 2021，
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Min CHEN, Chang-le CHEN. The Synthesis of Functionalized Polyolefin Materials and Research on Material Properties. [J]. Polymer Bulletin 34(6):26-34(2021)
DOI：

Min CHEN, Chang-le CHEN. The Synthesis of Functionalized Polyolefin Materials and Research on Material Properties. [J]. Polymer Bulletin 34(6):26-34(2021) DOI： 10.14028/j.cnki.1003-3726.2021.06.003.

摘要

聚烯烃年产量巨大、用途广泛

但是其最大的缺点之一是其非极性。向非极性聚烯烃中引入少量的极性官能团可以极大地改善其性质、拓宽其用途、提高其商业价值。因此

功能化聚烯烃材料受到了学术界和工业界一致的关注。本文将主要基于作者课题组的相关工作

介绍其在催化剂结构创新、极性单体的选择、聚合新技术等方面的研究进展。在此基础之上

制备了一系列带有极性基团的聚烯烃材料

并系统地研究了这些功能化聚烯烃材料的性质。

Abstract

Polyolefins have huge annual production and wide applications. However

one of their biggest limitations is their nonpolar nature. The introduction of small amounts of polar functional groups into non-functionalized polyolefins can greatly improve many properties

broaden their applications and increase their business values. Therefore

functionalized polyolefins are of growing interest scientifically and industrially. This account focuses on the research works from our research group and describes the following topics: the development of new catalyst systems

the selection of polar monomers and the new polymerization techniques. Subsequently

we describe the synthesis of a series of polyolefins with incorporation of some polar groups

as well as the studies of the properties of polar functionalized polyolefins materials.

关键词

催化剂极性单体聚合技术功能化聚烯烃材料材料性质

Keywords

CatalystsPolar monomerPolymerization techniquesFunctionalized polyolefinsMaterials properties

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Recent Advances in Phosphine-Phenolate Neutral Nickel Catalyzed Olefin Polymerization and Copolymerization with Polar Monomers

Research in Olefin Polymerization with Catalysts Immobilized onto Molecular Sieves

Advances in Polymerization Using Ionic Liquid as Reaction Media

Progress in Silicon-Based Dendrimers

Research Progress of Functional Polyolefins by Direction Copolymerization of Olefin and Polar Monomer

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School of Chemistry and Environmental Engineering, Changchun University of Science and Technology

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

Key Laboratory of Engineering Plastics, Joint Laboratory of Polymer Science and Materials, Institute of Chemistry, Chinese Academy of Sciences

Graduate University of the Chinese Academy of Sciences

State Key Laboratory of Metastable Materials Science & Technology, College of Materials, Yanshan University

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