To obtain electrospun PLLA fibrous membrane with high filtration efficiency and low filtration resistance in mass production
the rheological behavior and surface tension of PLLA solution prepared by dichloromethane (DCM)
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3-hexafluoro-2-propanol (HFIP) and DCM/DMF mixed solvents with different volume ratios were studied by means of rotary rheometer and optical video contact angle meter. The effects of solvent type and content on the spinnability of PLLA solution and the microstructure
filtration performance of the electrospun fibrous membrane were studied by SEM and filtration efficiency tester. Under the same concentration
the flow behavior of PLLA solution prepared by HFIP was pseudoplastic Bingham body
and the viscosity is higher than that of PLLA solution prepared by DCM
resulting in a better spinnability of PLLA solution
finer fibers. The filtration efficiency and resistance of this fibrous membrane were 9.923% and 534.4Pa higher than those of prepared by PLLA solution with DCM as solvent
respectively
in the same spinning time. When DCM or DCM/DMF was used as solvent
the flow behavior of PLLA solution was pseudoplastic. The stability and spinnability of PLLA solution prepared by the DMF/DCM mixed solvent were obviously improved than the PLLA solution prepared with only DCM as solvent
resulting in the finer fibers and the similar filtration efficiency
224.2Pa lower filtration resistance of fibrous membrane than those of prepared by PLLA solution with HFIP as solvent in the same spinning time.
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Institute of Analysis and Testing (Beijing Center for Physical & Chemical Analysis), Beijing Academy of Science and Technology, Beijing Key Laboratory of Organic Materials Testing Technology & Quality Evaluation
School of Mechanical and Electrical Engineering, Nanchang University
Hefei Genius Advanced Material Co,Ltd.
School of Materials Science and Engineering, Shijiazhuang Tiedao University
College of Ecology and Resources Engineering, Fujian Provincial Bamboo Engineering Technology Research Center, Fujian Key Laboratory of Eco-Industrial Green Technology, Wuyi University