Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System

Tian-hao GUO; Shu-zhang QU; Tao-yi ZHANG; Wei WANG

doi:10.14028/j.cnki.1003-3726.2022.10.006

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Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System

更新时间：2022-09-09

- Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System
- Polymer Bulletin Vol. 35, Issue 10, Pages: 41-53(2022)
- 作者机构：
  
  1.中国石化北京化工研究院材料科学研究所,北京 100013
  2.中国石化北京化工研究院医用卫生材料研究所,北京 100013
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2022.10.006
  CLC：
- Published：20 October 2022，
  
  Received：16 August 2021，
  
  Revised：03 April 2022，
扫描看全文
Tian-hao GUO, Shu-zhang QU, Tao-yi ZHANG, Wei WANG. Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System. [J]. Polymer Bulletin 35(10):41-53(2022)
DOI：

Tian-hao GUO, Shu-zhang QU, Tao-yi ZHANG, Wei WANG. Research Progress on the Role of the Third Component in the Single-site Catalyst Polymerization System. [J]. Polymer Bulletin 35(10):41-53(2022) DOI： 10.14028/j.cnki.1003-3726.2022.10.006.

摘要

本文综述了烯烃聚合的单中心催化剂体系中第三组分的影响。作为活性中心形成的非必要组分

第三组分对聚合物结构及聚合行为有重要影响。本文涉及了烷基金属类第三组分对聚合物结构、组成、分子量以及聚合行为的影响

总结了第三组分对单一催化剂体系、复合催化剂体系以及单一单体和多种单体的聚合体系的影响

重点讨论了链转移机理、配位链转移聚合原理以及链穿梭聚合技术。

Abstract

This article reviews the influence of the third component in the single-site catalyst system for olefin polymerization. As an unnecessary component for the formation of active centers

the third component has an important influence on the polymer structure and polymerization behavior. This article deals with the influence of the third component of metal alkyls on the structure

composition

molecular weight and polymerization behavior of the polymer

and summarizes the influence of the third component on the polymerization of a single catalyst system

a composite catalyst system

and a single monomer and multiple monomers. The chain transfer mechanism

coordination chain transfer polymerization principle and chain shuttle polymerization technology are presented.

关键词

单中心催化剂第三组分链转移配位链转移聚合链穿梭聚合

Keywords

Single-site catalystThe third componentChain transferCoordination chain transfer polymerizationChain shuttle polymerization

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College of materials and engineering, Chizhou university

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