HUANG Jing, PENG Sha, SUN Zhi-teng, LIU Xue-qing, LIU Ji-yan. Phase Structure Evolution and Film Properties of PEGDA/PDMS Driven by Electric Field. [J]. Polymer Bulletin 35(12):113-120(2022)
DOI:
HUANG Jing, PENG Sha, SUN Zhi-teng, LIU Xue-qing, LIU Ji-yan. Phase Structure Evolution and Film Properties of PEGDA/PDMS Driven by Electric Field. [J]. Polymer Bulletin 35(12):113-120(2022) DOI: 10.14028/j.cnki.1003-3726.2022.12.013.
Phase Structure Evolution and Film Properties of PEGDA/PDMS Driven by Electric Field
phase separation is realized by electric field. After the hydrophilic light curing resin poly(ethylene glycol diacrylate) (PEGDA) was blended with hydrophobic heat curing dimethylsiloxane acrylate prepolymer (PDMS)
PEGDA was orderly arranged in the direction of film thickness by dielectrophoresis under electric field. The pearl chain structure was fixed by light curing of PEGDA and thermal curing of PDMS. The formation of chain structure was observed online by optical microscope to determine the optimal conditions for phase separation. The structure of the cured PEGDA/ PDMS composite membrane was characterized by scanning electron microscopy (SEM) and Raman spectrometer
which further proved the realization of phase separation. The mechanical properties of the materials were tested. The realization of phase separation judged by the change of contact angle had little effect on the mechanical properties of the films. The results show that the chain structure of PEGDA particles in PDMS matrix under AC electric field is faster and uniform than that under DC electric field. When the AC electric field intensity is 500 V/mm and the frequency is 100 Hz
the pearl chain structure formed by PEGDA in the PDMS matrix is uniform. Compared with the composite film without electric field
the flexibility and surface hydrophilic properties of the obtained PEGDA/PDMS composite film increase
and the optical properties change little.
关键词
电场排列相分离聚乙二醇二丙烯酸酯聚二甲基硅氧烷
Keywords
Electric fieldPhase separationPoly(ethylene glycol diacrylate)Polydimethylsiloxan
Teaching of Phase Separation of Polymer Solution by Number-shape Combination
Discussion on Mixing Free Energy-composition Curve and Phase Diagram in Polymer Physics
Preparation and Control of PC/PLA Composite Microsphere via Phase Separation
Research Progress of Polyamide Microspheres
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