Construction and Assembly of Bottlebrush Polymers Mediated by Supramolecular Interactions

ZHANG Kai-xing; CHEN Sen-bin; ZHU Jin-tao

doi:10.14028/j.cnki.1003-3726.2023.11.002

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Construction and Assembly of Bottlebrush Polymers Mediated by Supramolecular Interactions

Special Issue: Polymer Research at Huazhong University of Science and Technology | 更新时间：2023-10-12

- Construction and Assembly of Bottlebrush Polymers Mediated by Supramolecular Interactions
- Polymer Bulletin Vol. 36, Issue 11, Pages: 1393-1405(2023)
- 作者机构：
  
  华中科技大学化学与化工学院，武汉　430074
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2023.11.002
  CLC：
- Published：20 November 2023，
  
  Received：01 June 2022，
  
  Revised：30 June 2023，
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ZHANG Kai-xing, CHEN Sen-bin, ZHU Jin-tao. Construction and Assembly of Bottlebrush Polymers Mediated by Supramolecular Interactions. [J]. Polymer Bulletin 36(11):1393-1405(2023)
DOI：

ZHANG Kai-xing, CHEN Sen-bin, ZHU Jin-tao. Construction and Assembly of Bottlebrush Polymers Mediated by Supramolecular Interactions. [J]. Polymer Bulletin 36(11):1393-1405(2023) DOI： 10.14028/j.cnki.1003-3726.2023.11.002.

摘要

瓶刷聚合物(BBPs)具有独特的分子结构和富有前景的应用领域，因此受到学者们日益广泛的关注。通过共价键接枝策略来合成瓶刷聚合物费时、合成困难，难以功能化。而通过非共价键作用，则容易将侧链接枝到共聚物主链上，为构建超分子瓶刷共聚物提供有利条件。超分子作用的引入，不仅带来瓶刷聚合物制备方面的灵活性，同时使材料具备更多的响应性、可逆性等功能。本文介绍了氢键、主客体相互作用、金属配位作用、离子相互作用等多种超分子作用介导的瓶刷聚合物的构建及组装，分析讨论了其各自特点、构筑策略，阐明了超分子作用介导的瓶刷聚合物的巨大应用潜能和重要研究意义，最后对其目前仍面临的问题和未来发展进行了分析和展望。

Abstract

Bottlebrush polymers have been widely studied because of their unique molecular structures and broad application scenarios. The synthesis of bottlebrush polymers by covalent bonds grafting is time-consuming

difficult to synthesize and difficult to function. By non-covalent bonding

the side chains are easily attached to the mainchain

which provides favorable conditions for the construction of supramolecular bottlebrush copolymers. The introduction of supramolecular interactions not only brings flexibility in the preparation of bottlebrush polymer

but also makes materials more responsive

reversible and other functions. This paper introduces the construction and assembly of bottlebrush polymers mediated by supramolecular interactions such as hydrogen bond interactions

host-guest interaction

metal coordination and electrostatic interactions

their respective characteristics and construction strategies are analyzed and discussed

the huge application potential and important research significance of bottlebrush polymers mediated by supramolecular interactions are expounded. Finally

the current problems and future development are analyzed and prospected.

关键词

瓶刷聚合物超分子作用自组装纳米结构形貌调控

Keywords

Bottlebrush polymersSupramolecular interactionsSelf-assemblyNanostructureMorphology control

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