<italic style="font-style: italic">α-</italic>Diimine Nickel Catalyst and Olefin Polymerization—Supplementary Suggestions for the “<italic style="font-style: italic">Coordination Polymerization</italic>” Section in the “<italic style="font-style: italic">Polymer Chemistry</italic>” Textbook

WANG Cheng; FENG Tao; FU Zhi-sheng

doi:10.14028/j.cnki.1003-3726.2024.24.222

您当前的位置：

首页 >

文章列表页 >

α-Diimine Nickel Catalyst and Olefin Polymerization—Supplementary Suggestions for the “Coordination Polymerization” Section in the “Polymer Chemistry” Textbook

更新时间：2025-01-06

- α-Diimine Nickel Catalyst and Olefin Polymerization—Supplementary Suggestions for the “Coordination Polymerization” Section in the “Polymer Chemistry” Textbook
- Polymer Bulletin Vol. 38, Issue 1, Pages: 137-145(2025)
- 作者机构：
  
  浙江大学，高分子合成与功能构造教育部重点实验室，高分子科学与工程学系，山西浙大新材料与化工研究院，浙江大学-星庐科技高端聚烯烃联合研发中心，杭州 310058
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.222
  CLC：
- Received：28 July 2024，
  
  Accepted：2024-09-25，
  
  Published Online：11 November 2024，
  
  Published：20 January 2025
- 稿件说明：
移动端阅览
王程, 冯涛, 傅智盛. α-二亚胺镍催化剂与烯烃聚合：《高分子化学》教材中配位聚合部分的增补建议. 高分子通报, 2025, 38(1), 137–145.

Wang, C.; Feng, T.; Fu, Z. S. α-Diimine nickel catalyst and olefin polymerization—subpplementary subggestions for the “coordination polymerization” section in the “Polymer Chemistry” textook. Polym. Bull. (in Chinese), 2025, 38(1), 137–145.
王程, 冯涛, 傅智盛. α-二亚胺镍催化剂与烯烃聚合：《高分子化学》教材中配位聚合部分的增补建议. 高分子通报, 2025, 38(1), 137–145. DOI： 10.14028/j.cnki.1003-3726.2024.24.222.

Wang, C.; Feng, T.; Fu, Z. S. α-Diimine nickel catalyst and olefin polymerization—subpplementary subggestions for the “coordination polymerization” section in the “Polymer Chemistry” textook. Polym. Bull. (in Chinese), 2025, 38(1), 137–145. DOI： 10.14028/j.cnki.1003-3726.2024.24.222.

摘要

烯烃配位聚合是高分子化学教学中的一个重要部分。自20世纪50年代的“镍效应”发现开始，至今已七十余年。目前多数高校选用的潘祖仁教授主编的《高分子化学(第五版)》教材中，只涉及了Ziegler-Natta引发体系和茂金属引发体系，非茂后过渡金属催化剂仅在《高分子化学(增强版)》中有简短介绍，且“链行走”这一重要机理未见提及。从1995年Brookhart等报道的首个能够催化乙烯聚合制备高分子量聚乙烯的后过渡金属催化剂(即

α-

二亚胺镍催化剂)以来，近30年中，后过渡金属催化烯烃聚合，尤其是以镍金属为中心的烯烃聚合催化剂有了长足的发展。本文选取了具有链行走机理、具备催化

α-

烯烃聚合以及烯烃与极性单体共聚能力的

α-

二亚胺镍催化剂进行了详细分析，并对近年来后过渡金属烯烃聚合催化剂进行了简单介绍，提出了该部分需要增补入《高分子化学》教材的建议。

Abstract

Olefin polymerization

is a crucial part in polymer chemistry education. Since the discovery of the “nickel effect” in the 1950s

more than seventy years have passed. The textbook “

Polymer Chemistry

(

Fifth Edition

)” edited by Prof. PAN Zu-ren

widely used in many universities

primarily covers the Ziegler-Natta and metallocene initiation systems

with only a brief introduction to non-metallocene post-transition metal catalysts in the “

Polymer Chemistry

(

Enhanced Edition

)”. Moreover

the important mechanism of “chain walking” was not mentioned. Since Brookhart

et al

. reported the first post-transition metal catalyst could catalyze ethylene polymerization to produce high molecular weight polyethylene (

-diimine nickel catalysts) in 1995

the field of olefin polymerization catalyzed by post-transition metals

especially nickel-based catalysts

has made significant progress over the past 30 years. This paper provides a detailed analysis of

-diimine nickel catalysts

which exhibit the chain walking mechanism and possess the ability to catalyze

-olefin polymerization and the copolymerization of olefins with polar monomers. Additionally

it offers a brief overview of recent advancements in post-transition metal olefin polymerization catalysts and proposes suggestions for incorporating this content into the “

Polymer Chemistry

” textbook.

关键词

Keywords

references

Hustad, P. D . Frontiers in olefin polymerization: reinventing the world’s most common synthetic polymers . Science , 2009 , 325 ( 5941 ), 704 – 707 .

Stürzel, M. ; Mihan, S. ; Mülhaupt, R . From multisite polymerization catalysis to sustainable materials and all-polyolefin composites . Chem. Rev. , 2016 , 116 ( 3 ), 1398 – 1433 .

焦书科 . 烯烃配位聚合理论与实践 . 2版 . 北京 : 化学工业出版社 , 2013 , 20 - 22, 35-39 .

张丹枫 . 烯烃聚合 . 上海 : 华东理工大学出版社 , 2014 , 20 – 21 .

Johnson, L. K. ; Killian, C. M. ; Brookhart, M . New Pd(II)- and Ni(II)-based catalysts for polymerization of ethylene and α- olefins . J. Am. Chem. Soc. , 1995 , 177 , 6414 – 6416 .

Mu, H. L. ; Zhou, G. L. ; Hu, X. Q. ; Jian, Z. B . Recent advances in nickel mediated copolymerization of olefin with polar monomers . Coord. Chem. Rev. , 2021 , 435 , 213802 .

Zanchin, G. ; Leone, G . Polyolefin thermoplastic elastomers from polymerization catalysis: advantages, pitfalls and future challenges . Prog. Polym. Sci. , 2021 , 113 , 101342 .

Wang, Y. ; Gao, R. ; Gou, Q. Q. ; Lai, J. J. ; Zhang, R. D. ; Li, X. Y. ; Guo, Z. F . Developments in late transition metal catalysts with high thermal stability for ethylene polymerization: α crucial aspect from laboratory to industrialization . Eur. Polym. J. , 2022 , 181 , 111693 .

潘祖仁 . 高分子化学(增强版) . 北京 : 化学工业出版社 , 2007 , 213 – 214 .

潘祖仁 . 高分子化学 . 5版 . 北京 : 化学工业出版社 , 2011 , 193 , 207 – 208 .

Wang, F. Z. ; Chen, C. L . A continuing legend: the Brookhart-type α -diimine nickel and palladium catalysts . Polym. Chem. , 2019 , 10 ( 19 ), 2354 – 2369 .

Wu, R. K. ; Wu, W. K. ; Stieglitz, L. ; Gaan, S. ; Rieger, B. ; Heuberger, M . Recent advances on α -diimine Ni and Pd complexes for catalyzed ethylene (Co) polymerization: a comprehensive review . Coord. Chem. Rev. , 2023 , 474 , 214844 .

Liu, J. Y. ; Li, Y. G. ; Li, Y. S. ; Hu, N. H . Ethylene polymerization by ( α -diimine) nickel(II)complexes bear-ing different substituents on para -position of imines activated with MMAO . J. Appl. Polym. Sci. , 2008 , 109 ( 2 ), 700 – 707 .

Zhu, L. ; Zang, D. D. ; Wang, Y. ; Guo, Y. T. ; Jiang, B. Y. ; He, F. ; Fu, Z. S. ; Fan, Z. Q. ; Hickner, M. A. ; Liu, Z. K. ; Chen, L. Q . Insight into the mechanism of thermal stability of α -diimine nickel complex in catalyzing ethylene polymerization . Organometallics , 2017 , 36 ( 6 ), 1196 – 1203 .

Wang, C. ; Wang, D. ; Xu, T. ; Zhang, Q. S. ; Fu, Z. S . Effect of N-aryl para-benzhydryl substituent on the thermal stability of α -diimine nickel catalyst . Macromol. Rapid Commun. , 2023 , 44 ( 18 ), e2300221 .

Wang, C. ; Tang, S. Z. ; He, Y. Y. ; Xu, T. ; Fu, Z. S . Preparation of polyethylene elastomers with increased high molecular weight and nearly perfect strain recovery by steric control of asymmetric α -diimine nickel catalyst . Inorg. Chim. Acta , 2024 , 569 , 122120 .

Killian, C. M. ; Tempel, D. J. ; Johnson, L. K. ; Brookhart, M . Living polymerization of α -olefins using NiII- α -diimine catalysts. Synthesis of new block polymers based on α -olefins . J. Am. Chem. Soc. , 1996 , 118 ( 46 ), 11664 – 11665 .

McCord, E. F. ; McLain, S. J. ; Nelson, L. T. J. ; Ittel, S. D. ; Tempel, D. ; Killian, C. M. ; Johnson, L. K. ; Brookhart, M . 13 C NMR analysis of α -olefin enchainment in poly-( α -olefins) produced with nickel and palladium α -diimine catalysts . Macromolecules , 2007 , 40 ( 3 ), 410 – 420 .

邢震艳 . 不同骨架的不对称( α- 二亚胺)镍催化剂的催化聚合研究 . 硕士学位论文 , 杭州 : 浙江大学 , 2020 .

张昊 . α -二亚胺镍催化剂催化乙烯/甲基丁香酚共聚及其机理研究 . 硕士学位论文 , 杭州 : 浙江大学 , 2020 .

Johnson, L. K. ; Mecking, S. ; Brookhart, M . Copolymerization of ethylene and propylene with functionalized vinyl monomers by palladium(II) cata-lysts . J. Am. Chem. Soc. , 1996 , 118 ( 1 ), 267 – 268 .

Small, B. L. ; Brookhart, M. ; Bennett, A. M. A . Highly active iron and cobalt catalysts for the polymerization of ethylene . J. Am. Chem. Soc. , 1998 , 120 ( 16 ), 4049 – 4050 .

Britovsek, G. J. P. ; Gibson, V. C. ; McTavish, S. J. ; Solan, G. A. ; White, A. J. P. ; Williams, D. J. ; Kimberley, B. S. ; Maddox, P. J . Novel olefin polymerization catalysts based on iron and cobalt . Chem. Commun. , 1998 , ( 7 ), 849 – 850 .

Wang, C. M. ; Friedrich, S. ; Younkin, T. R. ; Li, R. T. ; Grubbs, R. H. ; Bansleben, D. A. ; Day, M. W . Neutral nickel(II)-based catalysts for ethylene polymerization . Organometallics , 1998 , 17 ( 15 ), 3149 – 3151 .

Younkin, T. R. ; Connor, E. F. ; Henderson, J. I. ; Friedrich, S. K. ; Grubbs, R. H. ; Bansleben, D. A . Neutral, single-component nickel(II)polyolefin catalysts that tolerate heteroatoms . Science , 2000 , 287 ( 5452 ), 460 – 462 .

Baur, M. ; Lin, F. ; Morgen, T. O. ; Odenwald, L. ; Mecking, S . Polyethylene materials with in-chain ketones from nonalternating catalytic copolymerization . Science , 2021 , 374 ( 6567 ), 604 – 607 .

傅智盛 , 臧丹丹 , 范志强 , 李杰威 . 一种聚乙烯橡胶及其加工方法 . 中国专利 , CN201410200113.6 , 2016-05–11 .

徐涛 , 傅智盛 , 李寒莹 . 常温下非晶态聚乙烯内聚能密度的测定及其应用 . 高分子通报 , 2024 , 37 ( 2 ), 263 – 269 .

傅智盛 , 朱良 , 范志强 . 亚乙基苊( α- 二亚胺)镍烯烃催化剂及其制备方法与应用 . 中国专利 , CN2012-10276331.9 , 2014-04–09 .

傅智盛 , 何峰 , 范志强 . 亚乙烯基苊( α- 二亚胺)镍烯烃催化剂、制备方法及应用 . 中国专利 , CN2017-10996283.3 , 2018-05–08 .

傅智盛 , 何峰 , 邢震艳 , 朱越洲 , 范志强 . 5,6-二甲基苊( α- 二亚胺)镍烯烃催化剂及其制备与应用 . 中国专利 , CN201710326135.0 , 2018-11–23 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Integrating the Dual Carbon Concept into the Teaching Design and Practice of Polymer Chemistry Course

A New Case of Integrating Research to Promote Teaching in Polymer Chemistry: Using 1,1-Diphenyl-2-trinitrophenylhydrazine to Verify the Free Radical Polymerization Mechanism of Aromatic Nitrile Resins

“Theory-Real-Virtual” Combined Curriculum TeachingReform Based on Project-based-teaching—Our Practice of Polymer Chemistry

The Teaching Exploration and Practice for the Major of Polymer Materials and Engineering with an Interdisciplinary Feature—Taking the Experience for Teaching Polymer Chemistry, the Core Course Set in the Department of Polymer Science and Engineering at Zhejiang University, as an Example

Related Author

WANG Cheng

FENG Tao

FU Zhi-sheng

HOU Gui-xiang

XIE Jian-qiang

SUN Jian-kui

ZENG Ke

RAN Rong

Related Institution

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, ZJU-Hangzhou Xinglu High-end Polyolefin Research & Development Center, Zhejiang University

College of Materials Science and Engineering, North China University of Science and Technology

College of Polymer Science and Engineering, Sichuan University

School of New Materials and Shoes & Clothing Engineering, Liming Vocational University

Department of Polymer Science and Engineering, Zhejiang University

⁰

α-Diimine Nickel Catalyst and Olefin Polymerization—Supplementary Suggestions for the “Coordination Polymerization” Section in the “Polymer Chemistry” Textbook

DOI：10.14028/j.cnki.1003-3726.2024.24.222

摘要

Abstract

关键词

Keywords

references