Preparation and Properties of Antibacterial Polymer Structural Color Microspheres

TAO Wei-han; FANG Yin-chun

doi:10.14028/j.cnki.1003-3726.2024.24.234

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Preparation and Properties of Antibacterial Polymer Structural Color Microspheres

更新时间：2025-01-06

- Preparation and Properties of Antibacterial Polymer Structural Color Microspheres
- Polymer Bulletin Vol. 38, Issue 1, Pages: 109-115(2025)
- 作者机构：
  
  安徽工程大学纺织服装学院，芜湖 241000
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.234
  CLC：
- Received：14 August 2024，
  
  Accepted：2024-10-07，
  
  Published Online：07 November 2024，
  
  Published：20 January 2025
- 稿件说明：
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陶伟晗, 方寅春. 抗菌聚合物结构色微球的制备及性能. 高分子通报, 2025, 38(1), 109–115.

Tao, W. H.; Fang, Y. C. Preparation and properties of antiacterial polymer structural color microspheres. Polym. Bull. (in Chinese), 2025, 38(1), 109–115.
陶伟晗, 方寅春. 抗菌聚合物结构色微球的制备及性能. 高分子通报, 2025, 38(1), 109–115. DOI： 10.14028/j.cnki.1003-3726.2024.24.234.

Tao, W. H.; Fang, Y. C. Preparation and properties of antiacterial polymer structural color microspheres. Polym. Bull. (in Chinese), 2025, 38(1), 109–115. DOI： 10.14028/j.cnki.1003-3726.2024.24.234.

摘要

采用无皂乳液聚合方法，以甲基丙烯酸甲酯(MMA)、苯乙烯(St)和丙烯酰氧乙基三甲基氯化铵(DAC)，合成不同粒径的P(St-MMA-DAC)聚合物微球，通过雾化沉积法在涤纶织物上制备结构色。对P(St-MMA-DAC)聚合物微球及结构色织物进行了红外光谱、扫描电镜、粒径、反射光谱和抗菌性能测试。结果表明，通过改变合成过程中单体比例可以得到不同粒径的P(St-MMA-DAC)聚合物微球，可在涤纶织物上形成蓝色、粉红色、绿色、青色和紫色5种不同颜色的结构色。结构色织物对大肠杆菌(

E. coli

)和金黄色葡萄球菌(

S. aureus

)的抑菌率可达到98%以上，表现出优异的抗菌性能。本文为功能性聚合物微球开发及在纺织、医疗卫生等领域的应用提供了研究基础。

Abstract

P(St-MMA-DAC) polymer microspheres with different particle sizes were synthesized by soap free emulsion polymerization using methyl methacrylate (MMA)

styrene (St) and acryloxyethyl trimethylammonium chloride (DAC). The structural colors were formed on polyester fabric by atomization deposition of these P(St-MMA-DAC) polymer microspheres. Infrared spectroscopy

scanning electron microscopy

particle size

reflectance spectroscopy

and antibacterial performance tests were conducted on P(St-MMA-DAC) polymer microspheres and structural color fabrics. The results indicate that P(St-MMA-DAC) polymer microspheres with different particle sizes can be obtained by changing the monomer ratios during the synthesis process

which can form five different structural colors of blue

pink

green

cyan

and purple on polyester fabrics. The antibacterial rates of structural c

olor fabrics against

Escherichia coli

(

E. coli

) and

Staphylococcus aureus

(

S. aureus

) can reach over 98%

showing excellent antibacterial properties. This study provides a research basis for the development of functional polymer microspheres and their application in textile

medical and health fields.

关键词

Keywords

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