Polyacrylamide-Carboxymethyl Chitosan-Sodium Ligninsulfonate Self-healing Hydrogels Based on Polyphenol-metal Ion Catalytic System in Triboelectric Nanogenerators

LIU Yu-sen; WANG Meng-chao; ZHOU Xun; YUE Bing-bing

doi:10.14028/j.cnki.1003-3726.2025.25.039

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Polyacrylamide-Carboxymethyl Chitosan-Sodium Ligninsulfonate Self-healing Hydrogels Based on Polyphenol-metal Ion Catalytic System in Triboelectric Nanogenerators

更新时间：2025-07-15

- Polyacrylamide-Carboxymethyl Chitosan-Sodium Ligninsulfonate Self-healing Hydrogels Based on Polyphenol-metal Ion Catalytic System in Triboelectric Nanogenerators
- Polymer Bulletin Vol. 38, Issue 8, Pages: 1267-1279(2025)
- 作者机构：
  
  上海理工大学材料与化学学院，上海 200093
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2025.25.039
  CLC：
- Received：06 February 2025，
  
  Accepted：14 April 2025，
  
  Published Online：05 June 2025，
  
  Published：20 August 2025
- 稿件说明：
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刘玉森, 王孟朝, 周迅, 岳兵兵. 基于多酚-金属离子催化系统的聚丙烯酰胺-羧甲基壳聚糖-木质素磺酸钠自愈合水凝胶摩擦纳米发电机. 高分子通报, 2025, 38(8), 1267–1279.

Liu, Y. S.; Wang, M. C.; Zhou, X.; Yue, B. B. Polyacrylamide-Carboxymethyl Chitosan-Sodium Ligninsulfonate Self-healing Hydrogels Based on Polyphenol-metal Ion Catalytic System in Triboelectric Nanogenerators. Polym. Bull. (in Chinese), 2025, 38(8), 1267–1279.
刘玉森, 王孟朝, 周迅, 岳兵兵. 基于多酚-金属离子催化系统的聚丙烯酰胺-羧甲基壳聚糖-木质素磺酸钠自愈合水凝胶摩擦纳米发电机. 高分子通报, 2025, 38(8), 1267–1279. DOI： 10.14028/j.cnki.1003-3726.2025.25.039.

Liu, Y. S.; Wang, M. C.; Zhou, X.; Yue, B. B. Polyacrylamide-Carboxymethyl Chitosan-Sodium Ligninsulfonate Self-healing Hydrogels Based on Polyphenol-metal Ion Catalytic System in Triboelectric Nanogenerators. Polym. Bull. (in Chinese), 2025, 38(8), 1267–1279. DOI： 10.14028/j.cnki.1003-3726.2025.25.039.

摘要

水凝胶摩擦纳米发电机(H-TENG)因其卓越的机械柔韧性和导电性，成为可穿戴电子产品领域备受人们关注的柔性材料器件。然而，水凝胶在传统聚合过程中存在的高能耗与耗时缺陷，以及极端环境或机械损伤下电学性能衰减与力学失效问题，严重制约了H-TENG的实际应用。针对上述问题，开发了一种基于多酚-金属离子催化系统的自愈合双网络水凝胶，适用于水凝胶传感器和H-TENG。该材料体系通过动态氧化还原反应与Fe

-木质素磺酸钠(SLS)金属配位协同作用，实现了PAM-CMC双网络结构水凝胶的室温快速交联，无需外加热引发。同时，双网络结构及其动态配位键与氢键的协同能量耗散机制赋予了水凝胶优异的机械性能和自愈合特性。作为水凝胶传感器和H-TENG表现出稳健的传感性能和优异的自供电行为。本研究为具有可靠输出性能和传感特性的环境适应性自愈合H-TENG提供了一个应用前景广泛的材料体系。

Abstract

Hydrogel-based triboelectric nanogenerators (H-TENG) have emerged as promising flexible devices for wearable electronics owing to their notable mechanical flexibili

ty and electrical conductivity. However

the high energy consumption and time-intensive nature of conventional hydrogel polymerization processes

combined with the degradation of electrical properties and mechanical failure under extreme mechanical or environmental conditions

have severely limited their practical application. To address these challenges

this study presents a self-healing dual-network hydrogel engineered

via

a polyphenol-metal ion catalytic system for hydrogel sensors and H-TENG. The hydrogel is synthesized through dynamic redox reactions and metal-ligand coordination

utilizing sodium lignin sulfonate (SLS) and Fe

ions

which enable the rapid crosslinking of a polyacrylamide-carboxymethyl cellulose (PAM-CMC) dual-network hydrogel without energy-intensive thermal polymerization. The synergistic integration of dynamic metal coordination and hydrogen bonding confers the hydrogel with enhanced mechanical properties and autonomous self-healing capabilities. As a multifunctional platform

the material demonstrated stable strain-sensing responsiveness and consistent triboelectric output

even after severe mechanical damage. This study establishes an environmentally adaptive hydrogel system for self-healing H-TENG

exhibiting reliable performance across broad applications.

关键词

Keywords

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