Study on the Release Performance of Polyacrylonitrile/Hexagonal Boron Nitride Derivative Composite Film Constructed Based on Electrospinning and Its Effect on the Self-synthesized Essence

WU Ze-fan; HAO Hong-ling; XIAO Yan; CUI Qing-yun; HU Xue-min; YANG Wen-xiu

doi:10.14028/j.cnki.1003-3726.2025.25.123

您当前的位置：

首页 >

文章列表页 >

Study on the Release Performance of Polyacrylonitrile/Hexagonal Boron Nitride Derivative Composite Film Constructed Based on Electrospinning and Its Effect on the Self-synthesized Essence

更新时间：2025-09-23

- Study on the Release Performance of Polyacrylonitrile/Hexagonal Boron Nitride Derivative Composite Film Constructed Based on Electrospinning and Its Effect on the Self-synthesized Essence
- Polymer Bulletin Vol. 38, Issue 10, Pages: 1536-1545(2025)
- 作者机构：
  
  1.河北科技大学纺织服装学院，石家庄 050018
  2.河北中烟工业有限责任公司技术中心，石家庄 050018
  3.河北省纺织服装技术创新中心，石家庄 050018
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2025.25.123
  CLC：
- Received：23 April 2025，
  
  Accepted：15 July 2025，
  
  Published Online：02 September 2025，
  
  Published：20 October 2025
- 稿件说明：
移动端阅览
吴泽凡, 郝红玲, 肖焱, 崔青云, 胡雪敏, 杨文秀. 基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究. 高分子通报, 2025, 38(10), 1536–1545.

Wu, Z. F.; Hao, H. L.; Xiao, Y.; Cui, Q. Y.; Hu, X. M.; Yang, W. X. Study on the release performance of polyacrylonitrile/hexagonal boron nitride derivative composite film constructed based on electrospinning and its effect on the self-synthesized essence. Polym. Bull. (in Chinese), 2025, 38(10), 1536–1545.
吴泽凡, 郝红玲, 肖焱, 崔青云, 胡雪敏, 杨文秀. 基于静电纺丝构建的聚丙烯腈/六方氮化硼衍生物复合膜及其对自主合成香精的释放性能研究. 高分子通报, 2025, 38(10), 1536–1545. DOI： 10.14028/j.cnki.1003-3726.2025.25.123.

Wu, Z. F.; Hao, H. L.; Xiao, Y.; Cui, Q. Y.; Hu, X. M.; Yang, W. X. Study on the release performance of polyacrylonitrile/hexagonal boron nitride derivative composite film constructed based on electrospinning and its effect on the self-synthesized essence. Polym. Bull. (in Chinese), 2025, 38(10), 1536–1545. DOI： 10.14028/j.cnki.1003-3726.2025.25.123.

摘要

吡嗪类香味化合物因其独特的香气在香烟加香中被广泛应用，但吡嗪类化合物沸点较高，影响消费者抽吸体验感。因此，本研究以聚丙烯腈(PAN)为皮层，2-苯乙烯基吡嗪为芯层，六方氮化硼(h-BN)及其衍生物(HBN、GHBN)为功能填料，采用同轴静电纺丝技术制备了皮芯结构复合纳米纤维膜。研究表明，在复合纳米纤维膜中添加GHBN可明显提升2-苯乙烯基吡嗪的挥发速率，将热响应速度缩短至127 s，提升58%，香气强度值可达484，较单一PAN皮芯结构膜提升85%。同时，复合纤维膜水接触角为115.2°，疏水性明显增强，可降低香烟抽吸过程中湿度对挥发性物质的影响。

Abstract

Pyrazine aroma compounds are widely used in cigarette flavoring due to their unique aroma. But the boiling point of pyrazine compounds is high

which affects consumers’ sense of suction experience. Therefore

in this study

polyacrylonitrile (PAN) was used as the cortex

2-styrylpyrazine as the core layer

and hexagonal boron nitride (h-BN) and its derivatives (HBN

GHBN) as the functional filler. The composite nanofiber membrane with skin core structure was prepared by coaxial electrospinning technology. The results showed that the volatilization rate of 2-styrylpyrazine was significantly improved by adding GHBN to the composite nanofiber membrane

the thermal response rate was shortened to 127 s

and the aroma intensity value was up to 484

which was 85% higher than that of the single pan skin core structure membrane. At the same time

the water contact angle of the composite fiber membrane was 115.2°

and the hydrophobicity was significantly enhanced

which could reduce the effect of humidity on volatile substances during cigarette smoking.

关键词

Keywords

references

Hu, J. Y. ; Wang, L. F. ; Song, Z. G. ; Zhou, M. ; Lai, M. ; Cui, B. ; Xiao, M. L. ; Yang, J. L. ; Wu, C. C. ; Zhao, M. Q . Preparation and properties of thermal responsive 2, 3-diethyl-5-methylpyrazine fragrance microcapsules with β -CD/CS as wall materials . Int. J. Biol. Macromol. , 2024 , 283 , 137853 .

Zhou, M. ; Zhang, Y. J. ; He, A. M. ; Chen, W. H. ; Jiang, L. ; Lai, M. ; Zhao, M. Q. ; Cui, B . Performance characterisation and application of zein microcapsules loaded with pyrazine flavour . Flavour Fragr. J. , 2025 , 40 ( 2 ), 251 – 266 .

郭洪辉 , 张峰 , 谢全灵 , 张廷贵 , 刘雯 , 黄延俊 , 周培琛 , 茅中一 , 洪专 . 肉桂醇微胶囊的制备工艺及其在卷烟中的应用 . 河南农业科学 , 2022 , 51 ( 6 ), 172 – 180 .

Serrano-Garcia, W. ; Ramakrishna, S. ; Thomas, S. W . Electrospinning technique for fabrication of co-axial nanofibers of semiconductive polymers . Polymers , 2022 , 14 ( 23 ), 5073 .

Sukumar, T. ; Kadirvelu, K . Core-shell nanofibers with fire retardant properties prepared by a co-axial electrospinning technique . ChemistrySelect , 2022 , 7 ( 40 ), e202201679 .

Cho, Y. ; Beak, J. W. ; Sagong, M. ; Ahn, S. ; Nam, J. S. ; Kim, I. D . Electrospinning and nanofiber technology: fundamentals, innovations, and applications . Adv. Mater. , 2025 , 37 ( 28 ), 2570190 .

Wu, J. ; Liu, S. Q. ; Zhang, M. ; Wu, G. H. ; Yu, H. D. ; Li, H. M. ; Li, F. ; Jia, L . Coaxial electrospinning preparation and antibacterial property of polylactic acid/tea polyphenol nanofiber membrane . J. Ind. Text. , 2022 , 51 ( 2_suppl ), 1778S – 1792S .

Mounesan, M. ; Akbari, S . Scent encapsulation into the electrospun nanofibers . Engineered Polymeric Fibrous Materials . Amsterdam : Elsevier , 2021 . 233 – 259 .

李志强 , 雷萍 , 艾璞 , 李廷华 , 李寿波 , 朱东来 , 尚善斋 , 李晖 , 孙巧媚 . 静电纺丝技术制备料香包埋材料及其性能研究 . 四川大学学报(自然科学版) , 2024 , 61 ( 4 ), 286 – 292 .

Wu, X. Y. ; Li, P. P. ; Cong, L. Z. ; Yu, H. X. ; Zhang, D. H. ; Yue, Y. ; Xu, H. T. ; Xu, K. L. ; Zheng, X. ; Wang, X . Electrospun poly(vinyl alcohol) nanofiber films containing menthol/ β -cyclodextrin inclusion complexes for smoke filtration and flavor retention . Colloids Surf. A Physicochem. Eng. Aspects , 2020 , 605 , 125378 .

Orhun, Z. ; Doğan, D. ; Erdem, Ü. ; Yıldırım, G. ; Pehlivanlı, Z. O. ; Metin, A. Ü . Design of dual-conductive polyacrylonitrile-based composite nanofiber: synergistic effect of copper nanoparticles decorated-boron nitride and polyaniline . Polym. Compos. , 2024 , 45 ( 3 ), 2685 – 2700 .

Kim, J. ; Park, J. Y. ; Kim, H. J. ; Lee, S. ; Shin, Y. ; Lee, S. W. ; Chae, B . 3D structural analysis of PI blend/BN composite film with FTIR spectro-microtomography . Vib. Spectrosc. , 2020 , 110 , 103144 .

Alarifi, I. M. ; Alharbi, A. ; Khan, W. S. ; Swindle, A. ; Asmatulu, R . Thermal, electrical and surface hydrophobic properties of electrospun polyacrylonitrile nanofibers for structural health monitoring . Materials , 2015 , 8 ( 10 ), 7017 – 7031 .

Zahirifar, J. ; Hadi, A. ; Karimi-Sabet, J. ; Dastbaz, A . Influence of hexagonal boron nitride nanosheets as the additives on the characteristics and performance of PVDF for air gap membrane distillation . Desalination , 2019 , 460 , 81 – 91 .

Bai, C. ; Wang, F. ; Zhao, Z. ; Zhang, B. ; Yu, Y. ; Zhang, J . Mussel-inspired facile fabrication of dense hexagonal boron nitride nanosheet-based coatings for anticorrosion and antifriction applications . Mater. Today Nano , 2021 , 15 , 100129 .

Zou, R. ; Xiao, G. Q. ; Chen, C. L. ; Chen, C. Y. ; Yang, Z. W. ; Zhong, F. ; Wang, M. T. ; Li, Y. Y . High barrier and durable self-healing composite coating: boron nitride combined with cyclodextrin for enhancing the corrosion protection properties of waterborne epoxy coating . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 653 , 129896 .

Liu, J. ; Zhang, Z. Z. ; Qu, M. J. ; Zhao, J. ; Wang, Z. C . Enhanced thermal conductivity of BN/PEK-CN composites by bionic polydopamine modified BN . Polym. Compos. , 2024 , 45 ( 11 ), 9731 – 9740 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation and Properties of Polyacrylonitrile/Graphene Oxide Composite Nanofibers

Progress in the Application of Silicon-Carbon Composite Anode Materials for Lithium-ion Batteries Based on Electrospinning Technology

Research Progress of Nanofiber-based Membrane Materials in Oil-water Separation

Preparation of Sodium Alginate/TiO₂ Nanofiber Membrane and Its Adsorption Capacity for Cu²⁺ Ions

The Development of Electrospinning Technology in Medical Dressings

Related Author

Ping ZHANG

Jin-ning ZHANG

Qing-qing WANG

Qu-fu WEI

WANG Ming

LI Dong-yue

LENG Xin-yang

WANG Jing-wen

Related Institution

Key Laboratory of Eco-Textile of Education, Jiangnan University

School of Materials Science and Engineering, Liaoning Technical University

Key Laboratory of Mineral High Value Conversion and Energy Storage Materials of Liaoning Province

Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University

National Innovation Center of Advanced Dyeing & Finishing Technology

⁰