Tannic Acid-modified Polypropylene Melt-blown Nonwoven Fabric: Preparation and Oil-Water Separation Performance

MA Wen-long; YANG Kai-lu; CHEN Qiang; ZHANG Wei

doi:10.14028/j.cnki.1003-3726.2025.25.176

您当前的位置：

首页 >

文章列表页 >

Tannic Acid-modified Polypropylene Melt-blown Nonwoven Fabric: Preparation and Oil-Water Separation Performance

更新时间：2025-09-23

- Tannic Acid-modified Polypropylene Melt-blown Nonwoven Fabric: Preparation and Oil-Water Separation Performance
- Polymer Bulletin Vol. 38, Issue 10, Pages: 1557-1566(2025)
- 作者机构：
  
  1.新疆科技学院化工与纺织工程学院，库尔勒 841000
  2.河北科技大学纺织服装学院，石家庄 050018
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2025.25.176
  CLC：
- Received：28 July 2025，
  
  Accepted：18 August 2025，
  
  Published Online：08 September 2025，
  
  Published：20 October 2025
- 稿件说明：
移动端阅览
马文龙, 杨凯璐, 陈强, 张威. 单宁酸改性聚丙烯熔喷无纺布的制备及其油水分离性能. 高分子通报, 2025, 38(10), 1557–1566.

Ma, W. L.; Yang, K. L.; Chen, Q.; Zhang, W. Tannic acid-modified polypropylene melt-blown nonwoven fabric: preparation and oil-Water separation performance. Polym. Bull. (in Chinese), 2025, 38(10), 1557–1566.
马文龙, 杨凯璐, 陈强, 张威. 单宁酸改性聚丙烯熔喷无纺布的制备及其油水分离性能. 高分子通报, 2025, 38(10), 1557–1566. DOI： 10.14028/j.cnki.1003-3726.2025.25.176.

Ma, W. L.; Yang, K. L.; Chen, Q.; Zhang, W. Tannic acid-modified polypropylene melt-blown nonwoven fabric: preparation and oil-Water separation performance. Polym. Bull. (in Chinese), 2025, 38(10), 1557–1566. DOI： 10.14028/j.cnki.1003-3726.2025.25.176.

摘要

聚丙烯熔喷无纺布(PP MB)因其低成本、可控纤维和优异化学稳定性成为含油废水处理的研究热点，但其固有疏水性限制了在含油废水处理中的应用。为实现PP MB的亲水及水下疏油性能，本研究受贻贝

黏附启发，采用仿生策略在聚丙烯纤维表面构建Cu

/单宁酸(TA)涂层，成功制备了Cu

/TA@PP MB复合材料。通过系统表征改性前后复合材料的微观形貌、化学结构及油水分离性能，并评估其稳定性，结果表明：当单宁酸质量浓度为6 g/L、CuSO

质量浓度为1.2 g/L时，Cu

/TA涂层在纤维表面均匀覆盖；所得复合材料的水接触角降至27.4°，水下油接触角达114.4°，展现出优异的亲水性与水下疏油性；经20次循环油水分离实验，其分离效率仍保持在95%以上；在超声处理及高盐环境下，复合材料油水分离性能保持稳定，显示出优异的循环稳定性与环境耐受性。本研究为开发耐用、可循环使用的PP MB基油水分离材料提供了新思路。

Abstract

Polypropylene meltblown nonwoven fabric (PP MB) has become a research hotspot in oily wastewater treatment owing to its low cost

controllable fiber

and excellent chemical stability. However

its inherent hydrophobicity limits its application in oily wastewater treatment systems. Inspired by the adhesive properties of mussels

this study adopted a biomimetic strategy to construct a Cu

/tannic acid (TA) coating on the surface of polypropylene fibers

successfully preparing Cu

/TA@PP MB composite materials. Through systematic characterization of the microstructure

chemical structure

and oil-water separation performance of the composite material before and after modification

and evaluation of its stability

the results showed that when the tannic acid mass concentration was 6 g/L and the CuSO

mass concentration was 1.2 g/L

the Cu

/TA coating uniformly covered the fiber surface; the water contact angle of the composite material decreased to 27.4°

and the underwater oil contact angle reached 114.4°

demonstrating excellent hydrophilicity and underwater oleophobicity. After 20 rounds of oil-water separation experiments

the separation efficiency remained above 95%. Under ultrasonic treatment and high-salt environments

the oil-water separation performance of the composite material remained stable

exhibiting excellent cyclic stability and environmental tolerance. This study provides new insights into the development of durable and reusable PP MB-based oil-water separation materials.

关键词

Keywords

references

Tan, S. L. ; El Meragawi, S. ; Majumder, M. ; von Lau, E . Superhydrophilic and underwater superoleophobic Graphene oxide-Phytic acid membranes for efficient separation of oil-in-water emulsions . Sep. Purif. Technol. , 2023 , 314 , 123544 .

Manikandan, S. ; Subbaiya, R. ; Saravanan, M. ; Ponraj, M. ; Selvam, M. ; Pugazhendhi, A . A critical review of advanced nanotechnology and hybrid membrane based water recycling, reuse, and wastewater treatment processes . Chemosphere , 2022 , 289 , 132867 .

Ahmadi, F. ; Faizi, M. ; Tabatabai, S. A. ; Beiki, D. ; Shahhosseini, S . Comparison [3H]-flumazenil binding parameters in rat cortical membrane using different separation methods, filtration and centrifugation . Nucl. Med. Biol. , 2013 , 40 ( 7 ), 896 – 900 .

Wang, J. X. ; Guo, Y. ; Luo, C. X. ; Chen, H. Y. ; Pi, W. J. ; Liu, B. G. ; Yao, N. Y. ; Qiu, J. T. ; Zeng, Z. ; Li, L. Q . Theory-guided preparation of pore size tunable porous carbon for efficient adsorption and separation of the light hydrocarbons . Appl. Surf. Sci. , 2023 , 623 , 156941 .

古其林 , 李军佑 , 仲兆祥 , 邢卫红 . 油水高效分离用碳化硅膜的研究进展 . 膜科学与技术 , 2024 , 44 ( 6 ), 145 – 157 .

张跃忠 , 沈静 , 张少华 , 武鹏鹏 , 刘宝胜 . 超亲水-水下超疏油ZnCo 2 O 4 -不锈钢的制备及油水分离性能研究 . 表面技术 , 2024 , 53 ( 16 ), 198 – 207 .

Shen, X. ; Liu, P. ; He, C. X. ; Xia, S. B. ; Liu, J. J. ; Cheng, F. X. ; Suo, H. B. ; Zhao, Y. P. ; Chen, L . Surface PEGylation of polyacrylonitrile membrane via thiol-ene click chemistry for efficient separation of oil-in-water emulsions . Sep. Purif. Technol. , 2021 , 255 , 117418 .

Zhang, N. ; Yang, N. ; Zhang, L. H. ; Jiang, B. ; Sun, Y. L. ; Ma, J. W. ; Cheng, K. ; Peng, F. F . Facile hydrophilic modification of PVDF membrane with Ag/EGCG decorated micro/nanostructural surface for efficient oil-in-water emulsion separation . Chem. Eng. J. , 2020 , 402 , 126200 .

李思诺 , 刘静 , 孙凯 , 李胜海 . 贻贝仿生矿化超亲水表面膜的制备及其油-水分离性能 . 膜科学与技术 , 2024 , 44 ( 4 ), 65 – 74 .

Kong, W. G. ; Zhang, L. F. ; Yang, N. ; Jiang, B. ; Zhang, L. H. ; Liu, Y . Polyphenol-assisted construction of hierarchical microstructure on membrane surface with self-cleaning properties for highly efficient oil/water separation . J. Membr. Sci. , 2024 , 712 , 123222 .

Fang, S. K. ; Li, H. R. ; Feng, S. D. ; Wang, P. X. ; Yu, Y. ; Zhang, H. ; Guo, J . TA modified PAN/PU nanofiber membrane with excellent strength for oil/water separation . Fibres. Polym. , 2024 , 25 ( 1 ), 47 – 58 .

马文龙 , 郝天煦 , 张威 , 王新亚 , 李永贵 , 陈明星 . 聚丙烯熔喷空气过滤材料表面仿生改性及性能 . 高分子材料科学与工程 , 2024 , 40 ( 2 ), 141 – 150 .

陈微微 , 陈妍 , 夏孟胜 , 曹雪 , 李疆懿 , 高军凯 . 超亲水天然多酚改性膜的制备及其油水分离性能 . 精细化工 , 2023 , 40 ( 4 ), 829 – 837 .

Zhang, Y. X. ; Duan, X. F. ; Tan, B. R. ; Jiang, Y. C. ; Wang, Y. ; Qi, T . PVDF microfiltration membranes modified with AgNPs/tannic acid for efficient separation of oil and water emulsions . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 644 , 128844 .

Zhao, X. T. ; Wang, R. X. ; Lan, Y. Y. ; Wang, T. Y. ; Pan, J. F. ; Liu, L. F . Engineering superwetting membranes through polyphenol-polycation-metal complexation for high-efficient oil/water separation: From polyphenol to tailored nanostructures . J. Membr. Sci. , 2021 , 630 , 119310 .

Tian, S. W. ; Zhang, Y. Q. ; Sha, Q. K. ; Zhang, X. X. ; Yang, T. ; Yan, X. H. ; Han, N . PPS/TA-PEI/β-FeOOH membranes with powerful photo-Fenton self-cleaning capability for efficient oil–water emulsion separation . Chem. Eng. J. , 2024 , 485 , 150069 .

Liu, C. ; Yan, M. J. ; Guo, K. Y. ; Gao, Y. ; Liu, F. ; Gao, B. Y . Ta-Fe in situ coating PES membrane and its application in oily wastewater treatment: Insight into modification and anti-fouling mechanisms . Sep. Purif. Technol. , 2024 , 346 , 127506 .

Xie, H. L. ; Shen, L. G. ; Xu, Y. C. ; Hong, H. C. ; Yang, L. N. ; Li, R. J. ; Lin, H. J . Tannic acid (Ta)-based coating modified membrane enhanced by successive inkjet printing of Fe 3+ and sodium periodate (sp) for efficient oil-water separation . SSRN Electron. J. , 2022 , 660 : 120873 .

Wei, C. ; Wang, C. L. ; Hao, Y. J. ; Zhang, X. ; Long, J. S. ; Lang, W. Z . Nature-inspired construction of poly(vinylidene fluoride) membranes through the coordination coating of tannic acid with copper ions for oil-in-water emulsions separation . J. Membr. Sci. , 2023 , 671 , 121367 .

张诗雨 , 姚依婷 , 董晨珊 , 张如全 , 杨红军 , 顾绍金 , 黄菁菁 , 杜杰毫 . 金属有机框架/聚丙烯纤维基复合材料对化学战剂模拟物的快速降解 . 纺织学报 , 2024 , 45 ( 6 ), 134 – 141 .

Zhang, R. X. ; Ren, X. X. ; Cai, P. X. ; Zhong, L. ; Lu, Y. Y. ; Zhou, Z. G . Designing integrated Janus membrane based on a double-cross-linked polyphenol hydrophilic layer for complex emulsion separation . Sep. Purif. Technol. , 2024 , 330 , 125417 .

张彩云 , 范志颖 , 杜培波 , 文艳 , 王娟 , 葛凤燕 . 基于金属酚网络设计的耐久抗菌织物及其性能 . 印染 , 2023 , 49 ( 9 ), 52 – 55 .

郑雅心 , 孙菲 , 刘高峰 , 刘国金 . 纳米纤维基膜材料在油水分离中的研究进展 . 高分子通报 , 2024 , ( 6 ), 757 – 765 .

Kim, J. ; Moon, M. W. ; Kim, H. Y . Capillary rise in superhydrophilic rough channels . Phys. Fluids , 2020 , 32 ( 3 ), 032105 .

Ao, C. H. ; Hu, R. ; Zhao, J. Q. ; Zhang, X. F. ; Li, Q. Y. ; Xia, T. ; Zhang, W. ; Lu, C. H . Reusable, salt-tolerant and superhydrophilic cellulose hydrogel-coated mesh for efficient gravity-driven oil/water separation . Chem. Eng. J. , 2018 , 338 , 271 – 277 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation of Superhydrophobic Nonwoven Fabric Based on Titanium Dioxide Particles and Its Oil-water Separation Performance

Applications and Research Progress of Living/Controlled Free Radical Polymerization in Tribology

Research Progress of Nanofiber-based Membrane Materials in Oil-water Separation

Research Progress of Oil-Water Separation Membranes with Adaptable Wettability

Related Author

HAO Yun-ge

ZHOU Yuan

LI Jie-fang

LI Rong

ZHOU Chang-e

LI Zhi-guang

LIU Han-feng

YANG Lin-jie

Related Institution

Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing & Finishing, Wuhan Textile University

Key Laboratory of Eco-textiles of Ministry of Education, College of Textile Science and Engineering, Jiangnan University

School of Petrochemical Technology, Lanzhou University of Technology

Key Laboratory of Science and Technology on Wear and Protection of Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences

Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University

⁰