Preparation and Properties of Functionalized Silica-based Soil Water Erosion Resistant Materials

LIU Xiao-mei; WANG Wei-qiang; ZHAN Tian-jun; ZHANG Zhen-shi; PENG Huai-wu; LEI Zi-qiang

doi:10.14028/j.cnki.1003-3726.2025.25.293

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Preparation and Properties of Functionalized Silica-based Soil Water Erosion Resistant Materials

更新时间：2026-01-28

- Preparation and Properties of Functionalized Silica-based Soil Water Erosion Resistant Materials
- Polymer Bulletin Vol. 39, Issue 2, Pages: 270-279(2026)
- 作者机构：
  
  西北师范大学生态功能高分子材料教育部重点实验室甘肃省高分子材料重点实验室化学化工学院　兰州 730070
  甘肃民勤连古城国家级自然保护区管护中心　民勤 733300
  中国电建集团西北勘测设计研究院有限公司　西安 710065
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2025.25.293
  CLC：
- Received：09 October 2025，
  
  Accepted：28 November 2025，
  
  Published Online：12 January 2026，
  
  Published：20 February 2026
- 稿件说明：
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刘晓梅, 王伟强, 詹天军, 张振师, 彭怀午, 雷自强. 功能化二氧化硅基土壤抗水蚀材料的制备及性能. 高分子通报, 2026, 39(2), 270–279.

Liu, X. M.; Wang, W. Q.; Zhan, T. J.; Zhang, Z. S.; Peng, H. W.; Lei, Z. Q. Preparation and properties of functionalized silica-based soil water erosion resistant materials. Polym. Bull. (in Chinese), 2026, 39(2), 270–279.
刘晓梅, 王伟强, 詹天军, 张振师, 彭怀午, 雷自强. 功能化二氧化硅基土壤抗水蚀材料的制备及性能. 高分子通报, 2026, 39(2), 270–279. DOI： 10.14028/j.cnki.1003-3726.2025.25.293.

Liu, X. M.; Wang, W. Q.; Zhan, T. J.; Zhang, Z. S.; Peng, H. W.; Lei, Z. Q. Preparation and properties of functionalized silica-based soil water erosion resistant materials. Polym. Bull. (in Chinese), 2026, 39(2), 270–279. DOI： 10.14028/j.cnki.1003-3726.2025.25.293.

摘要

用3-氨基丙基三乙氧基硅烷(APTES)、衣康酸、丙烯酸酐(C

)、1-乙基-(3-二甲基氨基丙基)碳酰二亚胺(EDC)及

-羟基丁二酰亚胺(NHS)对纳米二氧化硅(SiO

)进行改性，再以丙烯酸、丙烯酰胺为单体，过硫酸铵(APS)为引发剂，通过自由基聚合法制备了聚合物材料P(mSiO

-AA-

-AM)。利用傅里叶变换红外光谱仪(FTIR)、扫描电子显微镜(SEM)、激光散射纳米粒度仪对其结构与形貌进行了表征。通过将P(mSiO

-AA-

-AM)添加到黄土以及红土中，分别考察了抗水蚀性能、抗压强度和保水性。结果表明，当添加0.50 wt%的P(mSiO

-AA-

-AM)后，红土的抗冲刷时间提高了24.9倍，水蚀率从400 %/h降低到了16.00 %/h。抗压强度提高了8.7倍。在黄土中添加0.5 wt%该材料，抗冲刷时间为200 h，是黄土抗冲刷时间的2400倍，黄土的抗压强度提高了13倍，保水率提高了3.0倍。室外燕麦种植实验结果表明，P(mSiO

-AA-

-AM)乳液不会对燕麦的发芽生长产生不利影响。

Abstract

Nano-silica (SiO

) was modified using 3-aminopropyltri

ethoxysilane (APTES)

itaconic acid

acrylic anhydride (C

)

1-ethyl-(3-dimethylaminopropyl) carbodiimide (EDC)

and

-hydroxysuccinimide (NHS). Subsequently

a P(mSiO

-AA-

-AM) emulsion was prepared

via

free radical polymerization using acrylic acid and acrylamide as monomers and ammonium persulfate (APS) as the initiator. The structure and morphology of the emulsion were characterized using Fourier transform infrared spectroscopy (FTIR)

scanning electron microscopy (SEM)

and particle size analysis. The anti-water erosion performance

compressive strength

and water retention properties were evaluated by incorporating the P(mSiO

-AA-

-AM) emulsion into loess and red soils. The results indicated that with the addition of 0.50 wt% P(mSiO

-AA-

-AM) emulsion

the anti-scour time of red soil increased by 24.9 times

whereas the water erosion rate decreased from 400 %/h to 16.00 %/h. The compressive strength was enhanced by 8.7 times. For loess treated with 0.5% of the material

the anti-scour time reached 200 h

which is 2400 times longer than that of loess. The compressive strength of the loess increased by 13 times

and the water retention rate improved by 3.0 times. Outdoor oat cultivation experiments demonstrated that the P(mSiO

-AA-

-AM) emulsion did not adversely affect oat germination and growth.

关键词

Keywords

references

李洁 , 刘春芳 . 气候变化下河西走廊生态系统健康时空变化及应对策略 . 应用生态学报 , 2025 , 36 ( 2 ), 537 – 546 .

贾正雷 . 土壤侵蚀机理与水土保持技术研究进展 . 农业灾害研究 , 2024 , 14 ( 8 ), 296 – 298 .

雷自强 . 土基材料及荒漠化防控 . 北京 : 科学出版社 , 2020 .

王埃平 . 黄土高原生态修复与生态环境质量评价研究 . 西安理工大学硕士学位论文 , 2007 .

杨波 , 焦菊英 , 马晓武 , 赵文婷 , 凌麒 , 张昕晗 , 王飞 , 韩剑桥 , 杜鹏飞 , 丛佩娟 , 刘政鸿 , 陈昊 , 戈文艳 . 2022年黄土高原典型暴雨侵蚀及洪水灾害调查分析 . 水土保持通报 , 2022 , 42 ( 6 ), 1 – 13 .

杨斌 , 郭维红 , 谭青媛 , 陈浮 , 刘希朝 , 金贵 . 高标准农田建设对耕地系统韧性的影响及其机制 . 农业工程学报 , 2025 , 41 ( 4 ), 269 – 278 .

刘天山 , 张耀南 , 敏玉芳 , 韩立欣 , 康建芳 , 张彩荷 . 渭河干流甘肃段河岸线空间变化数据集(2008、2015、2022年) . 中国科学数据 , 2024 , 9 ( 1 ), 230 – 242 .

付贵永 , 肖杨 , 史金权 , 周航 , 刘汉龙 . 干湿循环下EICP联合黄原胶加固钙质粉土劣化特性试验研究 . 岩土工程学报 , 2024 , 46 ( 11 ), 2341 – 2351 .

Bagheri, P. ; Gratchev, I. ; Zolghadr, M. ; Son, S. ; Kim, J. M . Mitigation of soil erosion and enhancement of slope stability through the utilization of lignin biopolymer . Polymers , 2024 , 16 ( 9 ), 1300 .

Guo, G. ; Kong, Y. ; Xu, Y. Y. ; Peng, X. Y. ; Niu, M. T. ; Zeng, G. R. ; Ouyang, Z. ; Liu, J. ; Zhang, C. ; Lin, J . Soil organic matter components and sesquioxides integrally regulate aggregate stability and size distribution under erosion and deposition conditions in Southern China . J. Hydrol. , 2024 , 639 , 131588 .

Mittal, H. ; Mishra, S. B. ; Mishra, A. K. ; Kaith, B. S. ; Jindal, R. ; Kalia, S . Preparation of poly(acrylamide- co -acrylic acid)-grafted gum and its flocculation and biodegradation studies . Carbohydr. Polym. , 2013 , 98 ( 1 ), 397 – 404 .

夏修建 , 于永金 , 齐奉忠 , 李长坤 , 徐璞 , 刘慧婷 . 固井用纳米材料及纳米复合材料研究进展 . 油田化学 , 2024 , 41 ( 4 ), 725 – 737 .

魏庆渤 . 纳米二氧化硅改性聚氯乙烯的研究 . 河南大学硕士学位论文 , 2019 .

Irmukhametova, G. S. ; Fraser, B. J. ; Keddie, J. L. ; Mun, G. A. ; Khutoryanskiy, V. V . Hydrogen-bonding-driven self-assembly of PEGylated organosilica nanoparticles with poly(acrylic acid) in aqueous solutions and in layer-by-layer deposition at solid surfaces . Langmuir , 2012 , 28 ( 1 ), 299 – 306 .

Naghavi, F. ; Morsali, A. ; Bozorgmehr, M. R . Molecular mechanism study of surface functionalization of silica nanoparticle as an anticancer drug nanocarrier in aqueous solution . J. Mol. Liq. , 2019 , 282 , 392 – 400 .

Baek, S. S. ; Jang, S. H. ; Hwang, S. H . Sustainable isosorbide-based transparent pressure-sensitive adhesives for optically clear adhesive and their adhesion performance . Polym. Int. , 2017 , 66 ( 12 ), 1834 – 1840 .

杨凤红 . 多功能高分子抗水蚀材料的制备及其性能 . 西北师范大学硕士学位论文 , 2023 .

赵亚奇 , 王佳慧 , 李佳慧 , 苏文聚 . 少水/DMSO反应体系制备聚丙烯腈动力学研究 . 化工新型材料 , 2024 , 52 ( 11 ), 177 – 181 .

郭朝阳 . 紫外光引发水溶液聚合制备超高分子量阴离子聚丙烯酰胺 . 中北大学硕士学位论文 , 2024 .

Khanlari, S. ; Dubé, M. A . Effect of pH on poly(acrylic acid) solution polymerization . J. Macromol. Sci. Part A , 2015 , 52 ( 8 ), 587 – 592 .

李强 . 聚合反应速率的影响因素 . 中国氯碱 , 2023 ( 11 ), 15 – 18 .

邓正东 . 环氧型丙烯酸酯橡胶高温溶液聚合与本体聚合反应特性 . 浙江大学硕士学位论文 , 2023 .

Purcar, V. ; Cinteza, O. ; Donescu, D. ; Bala, D. ; Ghiurea, M. ; Petcu, C. ; Caprarescu, S . Surface modification of silica particles assisted by CO 2 . J. Supercrit. Fluids , 2014 , 87 , 34 – 39 .

Karnati, S. R. ; Oldham, D. ; Fini, E. H. ; Zhang, L. F . Application of surface-modified silica nanoparticles with dual silane coupling agents in bitumen for performance enhancement . Constr. Build. Mater. , 2020 , 244 , 118324 .

Hu, Y. J. ; Zhang, J. ; Huo, H. ; Wang, Z. ; Xu, X. Z. ; Yang, Y. L. ; Lin, K. F. ; Fan, R. Q . One-pot synthesis of bimetallic metal–organic frameworks (MOFs) as acid–base bifunctional catalysts for tandem reaction . Catal. Sci. Technol. , 2020 , 10 ( 2 ), 315 – 322 .

Soto, D. ; Urdaneta, J. ; Pernia, K. ; León, O. ; Muñoz-Bonilla, A. ; Fernández-García, M . Itaconic acid grafted starch hydrogels as metal remover: Capacity, selectivity and adsorption kinetics . J. Polym. Environ. , 2016 , 24 ( 4 ), 343 – 355 .

杨浩 . 纳米SiO 2 聚丙烯酰胺钻井液絮凝剂的制备及性能评价 . 长江大学硕士学位论文 , 2023 .

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