Advances in Catalysis for Hydrosilylation Polymerization

LIU Kai-wen; HUANG Zhu-jun; PAN Xiang-cheng

doi:10.14028/j.cnki.1003-3726.2026.25.349

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Advances in Catalysis for Hydrosilylation Polymerization

更新时间：2026-03-21

- Advances in Catalysis for Hydrosilylation Polymerization
- Polymer Bulletin Vol. 39, Issue 4, Pages: 522-544(2026)
- 作者机构：
  
  复旦大学高分子科学系聚合物分子工程全国重点实验室　上海 200438
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.25.349
  CLC：
- Received：26 November 2025，
  
  Accepted：07 January 2026，
  
  Online First：05 March 2026，
  
  Published：20 April 2026
- 稿件说明：
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刘凯文, 黄竹君, 潘翔城. 硅氢化聚合反应催化体系的研究进展. 高分子通报, 2026, 39(4), 522–544.

Liu, K. W.; Huang, Z. J.; Pan, X. C. Advances in catalysis for hydrosilylation polymerization. Polym. Bull. (in Chinese), 2026, 39(4), 522–544.
刘凯文, 黄竹君, 潘翔城. 硅氢化聚合反应催化体系的研究进展. 高分子通报, 2026, 39(4), 522–544. DOI： 10.14028/j.cnki.1003-3726.2026.25.349.

Liu, K. W.; Huang, Z. J.; Pan, X. C. Advances in catalysis for hydrosilylation polymerization. Polym. Bull. (in Chinese), 2026, 39(4), 522–544. DOI： 10.14028/j.cnki.1003-3726.2026.25.349.

摘要

硅氢化聚合反应，是指Si―H键与不饱和键发生加成的聚合反应，作为合成有机硅聚合物的重要途径，在有机硅化学领域中展现出广泛的应用前景。本文综述了近年来硅氢化聚合反应的最新研究进展，依据反应催化剂种类的不同，将其细分为金属催化体系与非金属催化体系两大板块进行深入探讨。研究重点聚焦于催化剂的创新设计、反应条件的精细优化、新型聚合物的合成探索以及应用领域的不断拓展。希望通过对反应催化剂演变与发展的系统总结与深入分析，为硅氢化聚合反应的进一步完善与革新提供新的思路。

Abstract

Hydrosilylation polymerization

referring to the polymerization of the addition reaction between Si―H bonds and unsaturated bonds

serves as a pivotal pathway for synthesizing organosilicon polymers and demonstrates broad application prospects within the field of silicone chemistry. This review provides a comprehensive overview of recent research progress in hydrosilylation polymerization studies. Based on the different types of catalysts employed

the field is categorized into two major segments for exploration: metal and metal-free catalytic systems. The research focus is centered on the innovative design of catalysts

precise optimization of reaction conditions

exploration of novel polymer syntheses

and continuous expansion of application domains. Through a systematic summary and in-depth analysis of the evolution and development of reaction catalysts

this review aims to provide new insights into the further refinement and innovation of hydrosilylation polymerization.

关键词

Keywords

references

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