Research Progress on the Preparation, Modification, and Application of Boron Nitride in Rubber

LIU Chi; YUAN Xue-jian; ZHANG Xin; CAO Zhen-sheng; CAO Pan-pan; LI Peng-peng; YUE Jia-ji; WU Qiu-yu; CHANG Xiang-yang; HOU Lian-long

doi:10.14028/j.cnki.1003-3726.2026.25.366

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Research Progress on the Preparation, Modification, and Application of Boron Nitride in Rubber

更新时间：2026-04-30

- Research Progress on the Preparation, Modification, and Application of Boron Nitride in Rubber
- Polymer Bulletin Vol. 39, Issue 5, Pages: 749-763(2026)
- 作者机构：
  
  河北科技大学材料科学与工程学院河北省柔性功能材料重点实验室　石家庄 050018
  河北神龙管业有限公司　衡水 053500
  河北雄发新材料科技发展有限公司　衡水 053000
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.25.366
  CLC：
- Received：18 December 2025，
  
  Accepted：25 February 2026，
  
  Online First：07 April 2026，
  
  Published：20 May 2026
- 稿件说明：
移动端阅览
刘驰, 袁雪建, 张信, 曹振胜, 曹盼盼, 李鹏鹏, 岳嘉继, 吴秋雨, 苌向阳, 侯连龙. 氮化硼的制备改性及其橡胶应用研究进展. 高分子通报, 2026, 39(5), 749–763.

Liu, C.; Yuan, X. J.; Zhang, X.; Cao, Z. S.; Cao, P. P.; Li, P. P.; Yue, J. J.; Wu, Q. Y.; Chang, X. Y.; Hou, L. L. Research progress on the preparation, modification, and application of boron nitride in rubber. Polym. Bull. (in Chinese), 2026, 39(5), 749–763.
刘驰, 袁雪建, 张信, 曹振胜, 曹盼盼, 李鹏鹏, 岳嘉继, 吴秋雨, 苌向阳, 侯连龙. 氮化硼的制备改性及其橡胶应用研究进展. 高分子通报, 2026, 39(5), 749–763. DOI： 10.14028/j.cnki.1003-3726.2026.25.366.

Liu, C.; Yuan, X. J.; Zhang, X.; Cao, Z. S.; Cao, P. P.; Li, P. P.; Yue, J. J.; Wu, Q. Y.; Chang, X. Y.; Hou, L. L. Research progress on the preparation, modification, and application of boron nitride in rubber. Polym. Bull. (in Chinese), 2026, 39(5), 749–763. DOI： 10.14028/j.cnki.1003-3726.2026.25.366.

摘要

氮化硼(BN)因其高导热、电绝缘及优异热稳定性等综合优势，成为一类极具潜力的功能填料，可以突破传统橡胶基体的性能局限。然而BN与橡胶基体之间固有的界面不相容性，是制约复合材料性能优化的关键瓶颈，对BN进行改性至关重要。本文介绍了BN的制备、改性方法及其在橡胶中的应用研究进展。首先概述了BN的结构、性质与主要制备方法，论述了为改善界面结合而采用的共价与非共价改性策略，并系统总结了BN在三元乙丙橡胶、硅橡胶和天然橡胶等不同橡胶基体中，对复合材料导热、热稳定性、阻燃及力学性能的提升效果。本文旨在为高性能BN/橡胶复合材料的开发提供有益参考，并展望其未来发展方向。

Abstract

Boron nitride (BN) has emerged as a highly promising functional filler for overcoming the performance limitations of conventional rubber matrices by leveraging its superior comprehensive properties

including high thermal conductivity

electrical insulation

and excellent thermal stability. However

the inherent interfacial incompatibility between BN and rubber matrices poses a fundamental challenge to optimizing composite performance

making the modification of BN imperative. This review summarizes recent advances in the preparation

modification strategies

and application of BN in rubber composites. It begins with an overview of the structure

properties

and primary synthesis methods of BN. Subsequently

covalent and non-covalent modification strategies employed to enhance interfacial bonding are discussed. This review systematically summarizes the improvements achieved in the thermal conductivity

thermal stability

flame retardancy

and mechanical properties of composites based on various rubber matrices

including EPDM

silicone rubber

and natural rubber. This study aims to provide a valuable reference for the development of high-performance BN/rubber composites and offers perspectives on future research directions.

关键词

Keywords

references

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