Research Progress of Gel Polymer Electrolyte in Printed Supercapacitors

WANG Gui-lin; WEN Tao

doi:10.14028/j.cnki.1003-3726.2026.26.002

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Research Progress of Gel Polymer Electrolyte in Printed Supercapacitors

更新时间：2026-04-30

- Research Progress of Gel Polymer Electrolyte in Printed Supercapacitors
- Polymer Bulletin Vol. 39, Issue 5, Pages: 703-719(2026)
- 作者机构：
  
  华南理工大学前沿软物质学院广东省功能与智能杂化材料与器件重点实验室　广州 510640
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.26.002
  CLC：
- Received：04 January 2026，
  
  Accepted：06 February 2026，
  
  Online First：14 April 2026，
  
  Published：20 May 2026
- 稿件说明：
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王桂林, 文韬. 凝胶聚合物电解质及其在印刷超级电容器上的应用. 高分子通报, 2026, 39(5), 703–719.

Wang, G. L.; Wen, T. Research progress of gel polymer electrolyte in printed supercapacitors. Polym. Bull. (in Chinese), 2026, 39(5), 703–719.
王桂林, 文韬. 凝胶聚合物电解质及其在印刷超级电容器上的应用. 高分子通报, 2026, 39(5), 703–719. DOI： 10.14028/j.cnki.1003-3726.2026.26.002.

Wang, G. L.; Wen, T. Research progress of gel polymer electrolyte in printed supercapacitors. Polym. Bull. (in Chinese), 2026, 39(5), 703–719. DOI： 10.14028/j.cnki.1003-3726.2026.26.002.

摘要

印刷超级电容器(PSC)因其可规模化制造和柔性集成特性，在柔性电子与新型储能系统中展现出广阔应用前景。凝胶聚合物电解质(GPE)作为其中关键功能层，对器件的性能与稳定性具有决定性影响。本文系统综述了近年来GPE在PSC中的研究进展，重点围绕聚合物体系类型、溶剂体系以及制备方法进行分类梳理，综合分析其对离子传输行为、电极/电解质界面特性及器件电化学性能的影响机制。在此基础上，进一步总结了不同GPE体系在印刷适配性、循环稳定性及柔性可靠性方面的优势与局限。当前研究表明，GPE在实现高离子电导率、良好机械性能与印刷工艺兼容性之间仍面临挑战，界面阻抗控制、环境适应性及规模化制造一致性仍是制约PSC性能提升和实际应用的关键问题。未来研究需从材料结构设计、作用机制解析及印刷工艺协同优化等方面入手，发展多功能与环境友好型的GPE体系，以推动PSC向高性能化、柔性化和系统集成化方向发展。本文的综述与分析可为GPE的合理设计及其在印刷储能器件中的应用提供实验参考及研究思路。

Abstract

Printed supercapacitors (PSC) have attracted increasing attention in flexible electronics and emerging energy storage systems owing to their scalability and compatibility with flexible integration. As a key functional layer

the gel polymer electrolyte (GPE) plays a decisive role in determining the performance and stability of PSC. This review systematically summarizes the recent research progress on GPE in PSC

with a particular focus on their classification based on polymer systems

solvent systems

and fabrication methods. The influence of the GPE on the ion transport behavior

electrode/electrolyte interfacial characteristics

and electrochemical performance of PSC was comprehensively analyzed. On this basis

the advantages and limitations of different GPE systems in terms of printability

cycling stability and mechanical reliability are further discussed. Current studies indicate that achieving a balance among high ionic conductivity

mechanical integrity and printing compatibility remains challenging

while interfacial resistance control

environmental adaptability and manufacturing consistency continue to limit the performance improvement and practical application of PSC. Future research should focus on material structural design

mechanistic understanding

and synergistic optimization of printing processes

aiming to develop multifunctional and environmentally friendly GPE systems to promote PSC toward high performance

flexibility

and system-level integration. This review provides experimental references and research insights for the rational design of GPE and their application in printed energy storage devices.

关键词

Keywords

references

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