Research Progress in Ether-free Polyaryl Anion Exchange Membranes

MA Zhi-sheng; HAN Chong; GUO Jia; DONG Hai-jian; ZHAI Peng-hui; LONG Zhi; REN Yan-rong; DING Tao

doi:10.14028/j.cnki.1003-3726.2026.26.060

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Research Progress in Ether-free Polyaryl Anion Exchange Membranes

更新时间：2026-07-06

- Research Progress in Ether-free Polyaryl Anion Exchange Membranes
- Polymer Bulletin Vol. 39, Issue 7, Pages: 1045-1062(2026)
- 作者机构：
  
  河南大学化学与分子科学学院　开封 475004
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.26.060
  CLC：
- Received：04 February 2026，
  
  Accepted：09 April 2026，
  
  Online First：22 June 2026，
  
  Published：20 July 2026
- 稿件说明：
移动端阅览
麻智圣, 韩冲, 郭佳, 董海舰, 翟鹏辉, 龙志, 任艳蓉, 丁涛. 无醚聚芳基阴离子交换膜研究进展. 高分子通报, 2026, 39(7), 1045–1062.

Ma, Z. S.; Han, C.; Guo, J.; Dong, H. J.; Zhai, P. H.; Long, Z.; Ren, Y. R.; Ding, T. Research progress in ether-free polyaryl anion exchange membranes. Polym. Bull. (in Chinese), 2026, 39(7), 1045–1062.
麻智圣, 韩冲, 郭佳, 董海舰, 翟鹏辉, 龙志, 任艳蓉, 丁涛. 无醚聚芳基阴离子交换膜研究进展. 高分子通报, 2026, 39(7), 1045–1062. DOI： 10.14028/j.cnki.1003-3726.2026.26.060.

Ma, Z. S.; Han, C.; Guo, J.; Dong, H. J.; Zhai, P. H.; Long, Z.; Ren, Y. R.; Ding, T. Research progress in ether-free polyaryl anion exchange membranes. Polym. Bull. (in Chinese), 2026, 39(7), 1045–1062. DOI： 10.14028/j.cnki.1003-3726.2026.26.060.

摘要

阴离子交换膜水电解技术作为一种新兴的清洁能源转化方式，以其设备成本低、运行效率高等优势，被视为最具发展前景的水电解技术之一。阴离子交换膜(AEM)作为该技术的核心组件，其结构与性能直接影响电解槽的长期运行稳定性与效率。其中无醚聚芳基AEMs因其主链中不含易水解的醚键，在碱性工作环境中展现出优异的化学稳定性与耐久性，成为当前的研究热点。本文系统综述了无醚聚芳基AEMs的研究进展：首先介绍AEMs的基本结构组成与功能机制，其次分析不同聚合物主链类型对其微观结构与性能的影响，重点探讨多种阳离子基团设计策略及其传导机理，并对当前主流的膜制备方法进行归纳总结。此外，文中还对复合型阴离子交换膜的研究现状进行了概述。本文旨在为阴离子交换膜材料的进一步优化设计与性能提升提供参考。

Abstract

Anion exchange membrane water electrolysis

as an emerging clean energy conversion technology

is considered one of the most promising water electrolysis technologies due to its advantages such as low equipment cost and high operational efficiency. As the core component of this technology

the structure and properties of the anion exchange membrane (AEM) directly affect the long-term operational stability and efficiency of the electrolyzer. AEMs among these

ether-free polyaryl AEMs have emerged as a current research hotspot due to their excellent chemical stability and durability in alkaline operating environments

attributed to the absence of hydrolytically susceptible ether linkages in their polymer backbones. This review systematically reviews the research progress on ether-free polyaryl AEMs: first

the basic structural composition and functional mechanisms of AEMs are introduced; second

the influence of different polymer backbone types on their microstructure and properties is analyzed; third

various design strategies for cation groups and their conduction mechanisms are discussed in detail

followed by a summary of current mainstream membrane fabrication methods. Additionally

an overview of the current research status of composite anion exchange membranes is provided. This review aims to serve as a reference for the further optimization and performance enhancement of anion exchange membrane materials.

关键词

Keywords

references

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